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81.
Christina H. Chen Ashil K. Higgins Reinhold M. Strnat 《Journal of magnetism and magnetic materials》2008
The effect of specimen geometry on magnetization distortion in closed-circuit measurements is reported in this letter. The degree of the distortion increases as the ratio of length to diameter (L/D) of specimen decreases, and the distortion can reduce the magnetization values as much as 42% when the applied magnetic field is 24 kOe and the L/D is 0.28. The type of magnetic material also affects the distortion. Although the phenomenon seems to be similar to the “image effect” that occurs in open-circuit measurements, reports of this effect in closed-circuit measurements have not been found in the literature. Further research effort, including 3D computer modeling, for understanding this magnetic phenomenon is underway and will be reported later. 相似文献
82.
Iovka Dragieva Christina Deleva Mladen Mladenov Ivania Markova-Deneva 《Monatshefte für Chemie / Chemical Monthly》2002,82(1):807-814
Different structures of the interglobular space or voids between self-organized nanoparticles lead to differences in the measurable magnetic properties of single-domain particle chains of similar composition, grain size, and amorphous structure of the single globules. The volumes and radii of nanoparticles obtained by application of a magnetic field (3 to 15 nm) are larger than those determined without application of a magnetic field during the borohydride reduction process. Two types of hydrogen containing nanotubes with diameters of up to 2 (small-size containers) and 5 nm (large-size containers) are produced using as a driving force the domain wall formation energy between ferromagnetic nanoparticles with quantum size effected dimensions prepared by this reduction method at room temperature and ambient atmosphere. Nanoscale hydrogen containers can be used instead of MeH nanoparticle electrodes as perfect energy charge transfer media of high efficiency (close to 100%) using Li ion electrolytes. No influence on the electrode temperature and no participation of OH− and H2O in the main charge/discharge transfer reactions were observed. 相似文献
83.
Penna Thereza Christina Vessoni Moraes Dante Augusto 《Applied biochemistry and biotechnology》2002,98(1-9):775-789
Applied Biochemistry and Biotechnology - The production of nisin by batch culture of Lactococcus lactis ATCC 11454 in MRS broth (pH 6.5), as treated in 30 assays, that were set up by a fractional... 相似文献
84.
Asawin Likhitsup Anbanandam Parthiban Christina L. L. Chai 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):102-116
A simple, one‐step procedure has been developed for the preparation of bifunctional initiators capable of polymerizing monomers suitable for atom‐transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP). These bifunctional initiators were employed for making narrow disperse poly(styrene) macroinitiators, which were subsequently used for the ROP of various lactides to yield poly(styrene‐block‐lactide) copolymers. Thermogravimetric analysis (TGA) of these block copolymers are interesting in that it shows a two‐step degradation curve with the first step corresponding to the degradation of poly(lactide) segment and the second step associated with the poly(styrene) segment of the block copolymer. This nature of the block copolymer makes it possible to estimate the block copolymer content by TGA in addition to the 1H NMR spectroscopic analysis. Thus, this study for the first time highlights the possibility of making porous materials by thermal means which are otherwise obtained by base hydrolysis. The bifunctional initiators were prepared by the esterification of 3‐hydroxy, 4‐hydroxy, and 3,5‐dihydroxy benzyl alcohols with α‐bromoisobutyryl bromide and 2‐bromobutyryl bromide. A mixture of products was obtained, which were purified by column chromatography. The esterified benzyl alcohols were employed in the polymerization of styrene under copper (Cu)‐catalyzed ATRP conditions to yield macroinitiators with low polydispersity. These macroinitiators were subsequently used in the ROP of L ‐, DL ‐, and mixture of lactides. The formation of block copolymers was confirmed by gel permeation chromatography (GPC), spectroscopic and thermal characterizations. The molecular weight of the block copolymers was always higher than the macroinitiator, and the GPC chromatogram was symmetrical indicating the uniform initiation of ROP by the macroinitiators. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 102–116, 2008 相似文献
85.
86.
Tsvetan Tsolov Christina Pravtcheva Russy Milenkov Jordan Pirov 《Fresenius' Journal of Analytical Chemistry》1986,323(3):228-231
Summary The applicability of a series of synthetic standards for laser local analysis of refractories has been determined on the basis of 4 criteria: homogeneity, equality of the form and size of the craters formed by the laser beam, densities and plasma clouds. The validity of these criteria has been checked by comparison of the results received by electrone microprobe area scanning and by shooting the same places with a laser beam and reading the results with the help of synthetic standards.
Kriterien zur Anwendbarkeit synthetischer Standards für die Laser-Spektralanalyse von feuerfesten Materialien
Zusammenfassung Die Anwendbarkeit von synthetischen Standards für die Laser-Lokalanalyse von feuerfesten Materialien wurde auf Grund von 4 Kriterien beurteilt: Homogenität, Gleichheit von Form und Größe der vom Laserstrahl verursachten Krater, Dichten und Plasmawolken. Die Gültigkeit dieser Kriterien wurde durch Vergleich der erhaltenen Ergebnisse mit den mit Hilfe der Elektronenmikrosonde erzielten Resultaten geprüft.相似文献
87.
Christina Strassacker Viatcheslav Bykov Ulrich Maas 《Proceedings of the Combustion Institute》2021,38(1):1025-1032
In this study, multi-dimensional molecular transport phenomena during Flame-Wall-Interactions (FWI) and their effects on model reduction strategies are investigated. In order to access the problem, the standard configurations of a two-dimensional Side-Wall Quenching (SWQ) flame and a one-dimensional Head-On Quenching (HOQ) flame are used and compared. In the case of the SWQ configuration it is shown that the gradients of the species scatter significantly both in the physical space and in the state space. Moreover, the gradient vector of the specific enthalpy describing energy losses towards the wall is not aligned with the gradient vectors of the species, which can be considered as a typical case while a flame in application might approach to the wall at any arbitrary transversal direction. This observation motivates to take the gradients’ scattering and multi-dimensional transport phenomena into account during model reduction to describe reliably the quenching process.The Reaction-Diffusion Manifold (REDIM) method is applied in this work. The method allows to take into account multi-dimensional transport in a very generic way. In order to generate the REDIM, gradient estimates are approximated by using a Singular-Value Decomposition (SVD) of SWQ detailed gradients fields. Two-dimensional REDIMs for both cases are constructed and compared to each other. Different transport (diffusion) models are implemented to compare quantitatively the manifolds with HOQ and SOQ gradients estimates. The comparison shows that the differences between reduced models with varying transport models is significantly larger than the differences for varying configurations (multidimensional gradient estimates). This justifies the use of a relatively simple REDIM for more complicated geometries and configurations. This simplifies the treatment and model reduction procedure significantly for such complicated transient phenomena. 相似文献
88.
Christina Petschnigg Markus Spitzner Lucas Weitzendorf Jürgen Pilz 《Entropy (Basel, Switzerland)》2021,23(3)
The 3D modelling of indoor environments and the generation of process simulations play an important role in factory and assembly planning. In brownfield planning cases, existing data are often outdated and incomplete especially for older plants, which were mostly planned in 2D. Thus, current environment models cannot be generated directly on the basis of existing data and a holistic approach on how to build such a factory model in a highly automated fashion is mostly non-existent. Major steps in generating an environment model of a production plant include data collection, data pre-processing and object identification as well as pose estimation. In this work, we elaborate on a methodical modelling approach, which starts with the digitalization of large-scale indoor environments and ends with the generation of a static environment or simulation model. The object identification step is realized using a Bayesian neural network capable of point cloud segmentation. We elaborate on the impact of the uncertainty information estimated by a Bayesian segmentation framework on the accuracy of the generated environment model. The steps of data collection and point cloud segmentation as well as the resulting model accuracy are evaluated on a real-world data set collected at the assembly line of a large-scale automotive production plant. The Bayesian segmentation network clearly surpasses the performance of the frequentist baseline and allows us to considerably increase the accuracy of the model placement in a simulation scene. 相似文献
89.
This report describes the use of Pd(II)/bis-sulfoxide 1 catalyzed intra- and intermolecular allylic C-H amination reactions to rapidly diversify structures containing a sensitive β-lactam core similar to that found in the monobactam antibiotic Aztreonam. Pharmacologically interesting oxazolidinone, oxazinanone, and linear amine motifs are rapidly installed with predictable and high selectivities under conditions that use limiting amounts of substrate. Additionally, we demonstrate for the first time that intramolecular C-H amination processes may be accelerated using catalytic amounts of a Lewis acid co-catalyst [Cr(III)(salen)Cl 2]. 相似文献
90.
Clio Dessinioti Christina Antoniou Andreas Katsambas Alexander J. Stratigos 《Photochemistry and photobiology》2010,86(3):481-491
Basal cell carcinoma (BCC) is the most common skin cancer in white populations with an increasing incidence worldwide, thereby imposing an important public health problem. Its etiology is still unclear, but existing data indicate that the risk for BCC development is of multifactorial origin and results from the interplay of both constitutional and environmental factors. Yet, UV radiation (UVR) is believed to be the predominant causative risk factor in the pathogenesis of BCC. For years, BCC and squamous cell carcinoma (SCC) have been grouped together as “nonmelanoma skin cancer.” However, it seems that there are considerable biologic differences between BCC and SCC, and thus each type of epithelial cancer should be addressed separately. The present review provides an overview of the intriguing etiologic link of BCC with UVR and attempts a comprehensive review of recent epidemiologic and molecular evidence that supports this association. 相似文献