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991.
Johann Steiner Hans-Gert Bernstein Hendrik Bielau Annika Berndt Ralf Brisch Christian Mawrin Gerburg Keilhoff Bernhard Bogerts 《BMC neuroscience》2007,8(1):2
Background
S100B is considered an astrocytic in-situ marker and protein levels in cerebrospinal fluid (CSF) or serum are often used as biomarker for astrocytic damage or dysfunction. However, studies on S100B in the human brain are rare. Thus, the distribution of S100B was studied by immunohistochemistry in adult human brains to evaluate its cell-type specificity. 相似文献992.
993.
The incorporation of energy elastic effects in the modeling of flowing polymeric liquids is discussed. Since conformational
energetic effects are determined by structural features much smaller than the end-to-end vector of the polymer chains, commonly
employed single conformation tensor models are insufficient to describe energy elastic effects. The need for a local structural
variable is substantiated by studying a microscopic toy model with energetic effects in the setting of a generalized canonical
ensemble. In order to examine the dynamics of flowing polymeric liquids with energy elastic effects, a thermodynamically admissible
set of evolution equations is presented that accounts for the evolution of the microstructure in terms of a slow tensor, as
well as a fast, local scalar variable. It is demonstrated that the temperature used in the definition of the heat flux is
directly related to the Lagrange multiplier of the microscopic energy in the generalized canonical partition function. The
temperature equation is discussed with respect to, first, the dependence of the heat capacity on the polymer conformation
and, second, the possibility to measure experimentally the effects of the conformational energy.
相似文献
Markus HütterEmail: |
994.
Florian J. Stadler Christian Piel Joachim Kaschta Sascha Rulhoff Walter Kaminsky Helmut Münstedt 《Rheologica Acta》2006,45(5):755-764
Linear high-density polyethylenes with molar masses M
w between 240 and 1,000,000 g/mol, obtained by metallocene catalysts, were characterized in shear using oscillatory and creep tests. The polydispersities of the molar mass distributions (MMDs) lay between 1 and 16. The resulting zero shear-rate viscosities η0 covered a range from 2.5×10−3 to around 108 Pas. Above a critical molar mass of M
c≈2,900 g/mol, the experimental results can be described by the relation η0 ∼ M
w3.6, independently of the MMD. The oscillatory data were fitted with a Carreau–Yasuda equation. The resulting parameters were correlated to molecular structure. The parameter a, being a quantity for the width of the transition between the Newtonian and the non-Newtonian regime, showed a dependence on the molar mass M
w but not on M
w/M
n. The parameter λ of the Carreau-Yasuda equation was found to be the reciprocal crossover frequency for all samples with a log-Gaussian MMD. λ depends on the molar mass M
w and also on M
w/M
n.
相似文献
Helmut MünstedtEmail: Phone: +49-9131-8527604Fax: +49-9131-8528321 |
995.
The Layered Structure of Cu2(H2O)4[C4H4N2][C6H2(COO)4]·2H2O Triclinic single crystals of Cu2(H2O)4[C4H4N2][C6H2(COO)4]·2H2O have been grown in an aqueous silica gel. Space group (Nr. 2), a = 723.94(7) pm, b = 813.38(14) pm, c = 931.0(2) pm, α = 74.24(2)°, β = 79.24(2)°, γ = 65.451(10)°, V = 0.47819(14) nm3, Z = 1. Cu2+ is coordinated in a distorted, octahedral manner by two water molecules, three oxygen atoms of the pyromellitate anions and one nitrogen atom of pyrazine (Cu—O 194.1(2)–229.3(3) pm; Cu–N 202.0(2) pm). The connection of Cu2+ and [C6H2(COO)4)]4? yields infinite strands, which are linked by pyrazine molecules to form a two‐dimensional coordination polymer. Thermogravimetric analysis in air showed that the dehydrated compound was stable between 175 and 248 °C. Further heating yielded CuO. 相似文献
996.
Fischer C Kohrt C Drexler HJ Baumann W Heller D 《Dalton transactions (Cambridge, England : 2003)》2011,40(16):4162-4166
Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H](3)(μ(2)-H)(3)(μ(3)-H)}[BF(4)](2) containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution. 相似文献
997.
Spacer‐Modulated Differentiation Between Self‐Assembly and Folding Pathways for Bichromophoric Merocyanine Dyes 下载免费PDF全文
Dr. André Zitzler‐Kunkel Eva Kirchner David Bialas Christian Simon Prof. Dr. Frank Würthner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(42):14851-14861
We have synthesized a large series of bis(merocyanine) dyes with varying spacer unit and investigated in detail their self‐organization behavior by concentration‐ as well as solvent‐dependent UV/Vis spectroscopy. Our in‐depth studies have shown that the self‐organization of the present bis(merocyanine) dyes is subtly influenced by the nature of the spacer unit. The utilization of rigid spacers results in the formation of self‐associated bimolecular complexes with high binding strength, while flexible spacers drive the respective bichromophoric dyes to intramolecular folding. Our thorough investigations on the impact of alkyl spacer chain length on the folding tendency of the present series of bis(merocyanine) dyes revealed a biphasic behavior, that is, a steep increase of the folding tendency for the dyes containing C4 to C7 chains and then a gentle decrease for dyes with longer alkyl spacer chains as evidenced by free energy (ΔG) values for the folding of these dyes. Furthermore, analyses of aggregates’ optical properties based on exciton theory as well as quantum chemical calculations suggest a bimolecular aggregate structure for the dye possessing a rigid spacer and a rotationally twisted pleated structure for the bis(merocyanine) dyes having spacer units with less than seven carbon atoms, while the application of longer alkyl chain linkers (≥C7) provides enough flexibility to orient the chromophores in electrostatically most favored antiparallel fashion. 相似文献
998.
999.
Functionalization of Intramolecular Frustrated Lewis Pairs by 1,1‐Carboboration with Conjugated Enynes 下载免费PDF全文
Dr. Andreas Feldmann Dr. Gerald Kehr Dr. Constantin G. Daniliuc Dr. Christian Mück‐Lichtenfeld Prof. Dr. Gerhard Erker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(35):12456-12464
The vicinal P/B frustrated Lewis pair (FLP) Mes2PCH2CH2B(C6F5)2 undergoes 1,1‐carboboration reactions with the Me3Si‐substituted enynes to give ring‐enlarged functionalized C3‐bridged P/B FLPs. These serve as active FLPs in the activation of dihydrogen to give the respective zwitterionic [P]H+/[B]H? products. One such product shows activity as a metal‐free catalyst for the hydrogenation of enamines or a bulky imine. The ring‐enlarged FLPs contain dienylborane functionalities that undergo “bora‐Nazarov”‐type ring‐closing rearrangements upon photolysis. A DFT study had shown that the dienylborane cyclization of such systems itself is endothermic, but a subsequent C6F5 migration is very favorable. Furthermore, substituted 2,5‐dihydroborole products are derived from cyclization and C6F5 migration from the photolysis reaction. In the case of the six‐membered annulation product, a subsequent stereoisomerization reaction takes place and the resultant compound undergoes a P/B FLP 1,2‐addition reaction with a terminal alkyne with rearrangement. 相似文献
1000.
Dr. Tobias Blockhaus MSc. Fabian L. Zott Dr. Peter M. Zehetmaier Dr. Christian Klein-Heßling Prof. Dr. Karlheinz Sünkel 《无机化学与普通化学杂志》2023,649(1):e202200277
1,2,3- Tricyanoferrocene and 1,3-dibromo-2,4,5-tricyanoferrocene have been synthesized via metallation and usage of dimethylmalononitrile (DMMN) as cyanating agent. They are the first compounds where three nitrile functions could be introduced into the ferrocene sceleton. Further studies on the electrophilic cyanation of lithiated haloferrocenes [Fe(C5HmX4-mLi)(C5H5)] (X=Cl, Br; m=0–3) show the formation of complex mixtures of cyano-halo-ferrocenes [Fe{C5HmX5-m-n(CN)n}(C5H5)] (m=0–3, n=0–3) most likely induced by “halogen-dance” reactions. The molecular and crystal structures of [Fe{C5H2(CN)3}(C5H5)] and [Fe(C5Cl4CN)(C5H5)] are discussed. Cyclic voltametric studies of both tricyanoferrocenes show irreversible oxidations at very high potentials (Eonset≈845 mV and 945 mV, respectively, vs FcH/FcH+). 相似文献