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41.
In the framework of ARMA models, we consider testing the reliability of the standard asymptotic covariance matrix (ACM) of the least-squares estimator. The standard formula for this ACM is derived under the assumption that the errors are independent and identically distributed, and is in general invalid when the errors are only uncorrelated. The test statistic is based on the difference between a conventional estimator of the ACM of the least-squares estimator of the ARMA coefficients and its robust HAC-type version. The asymptotic distribution of the HAC estimator is established under the null hypothesis of independence, and under a large class of alternatives. The asymptotic distribution of the proposed statistic is shown to be a standard χ2 under the null, and a noncentral χ2 under the alternatives. The choice of the HAC estimator is discussed through asymptotic power comparisons. The finite sample properties of the test are analyzed via Monte Carlo simulation. 相似文献
42.
Pulsed laser deposition with a Nd:YAG laser was used to grow thin films from a pre-synthesized Ti3SiC2 MAX-phase formulated ablation target on oxidized Si(1 0 0) and MgO(1 0 0) substrates. The depositions were carried out in a substrate temperature range from 300 to 900 K, and the pressure in the deposition chamber ranged from vacuum (10−5 Pa) to 0.05 Pa Argon background pressure. The properties of the films have been investigated by Rutherford backscattering spectrometry for film thickness and stoichiometric composition and X-ray diffraction for the crystallinity of the films. The silicon content of the films varied with the energy density of the laser beam. To suppress especially the silicon re-sputtering from the substrate, the energy of the incoming particles must be below a threshold of 20 eV. Therefore, the energy density of the laser beam must not be too high. At constant deposition energy density the film thickness depends strongly on the background pressure. The X-ray diffraction measurements show patterns that are typical of amorphous films, i.e. no Ti3SiC2 related reflections were found. Only a very weak TiC(2 0 0) reflection was seen, indicating the presence of a small amount of crystalline TiC. 相似文献
43.
Christian Richter 《Elemente der Mathematik》1998,53(4):149-158
44.
45.
Christian Steglich 《Results in Mathematics》1995,27(1-2):188-193
While in Euclidean, equiaffine or centroaffine differential geometry there exists a unique, distinguished normalization of a regular hypersurface immersion x: M n → An+1, in the geometry of the general affine transformation group, there only exists a distinguished class of such normalizations, the class of relative normalizations. Thus, the appropriate invariants for speaking about affine hypersurfaces are invariants of the induced classes, e.g. the conformai class of induced metrics and the projective class of induced conormal connections. The aim of this paper is to study such invariants. As an application, we reformulate the fundamental theorem of affine differential geometry. 相似文献
46.
47.
Christian Bär 《Communications in Mathematical Physics》1997,188(3):709-721
We prove that the nodal set (zero set) of a solution of a generalized Dirac equation on a Riemannian manifold has codimension
2 at least. If the underlying manifold is a surface, then the nodal set is discrete. We obtain a quick proof of the fact that
the nodal set of an eigenfunction for the Laplace-Beltrami operator on a Riemannian manifold consists of a smooth hypersurface
and a singular set of lower dimension. We also see that the nodal set of a Δ-harmonic differential form on a closed manifold
has codimension 2 at least; a fact which is not true if the manifold is not closed. Examples show that all bounds are optimal.
Received: 28 October 1996 / Accepted: 3 March 1997 相似文献
48.
The separation of the toxicologically important aldehyde acrolein from other carbonyl compounds by high performance liquid chromatography after derivatization to 2,4-dinitrophenylhydrazones is critically discussed on the basis of a selection of published methods. A method is proposed whereby the compounds acrolein, acetone, and propanal may be reproducibly separated to baseline by a reversed phase HPLC procedure employing a ternary mixture of methanol, water, and acetonitrile as mobile phase. 相似文献
49.
Christian Hill 《Journal of Molecular Spectroscopy》2007,241(1):15-17
Recently-formulated centrifugal distortion corrections to the spin-spin Hamiltonian have been used to analyse the first excited triplet state (ã3A2) of deuterated selenoformaldehyde. By including six spin-spin centrifugal distortion parameters, it is possible to account for the energy levels of this state using a single set of three rotational constants, A, B, and C, where previously nine spin-dependent parameters were required. 相似文献
50.