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31.
Christian Buchgraber Alexander Pogantsch Stefan Kappaun Julia Spanring Wolfgang Kern 《Journal of polymer science. Part A, Polymer chemistry》2006,44(14):4317-4327
Light‐emitting diodes based on organic materials [organic light‐emitting diodes (OLEDs)] have attracted much interest over the past decade. Several different attempts have been made to realize multicolor OLEDs. This article describes a new approach based on energy transfer in a donor/acceptor system. A copolymer containing both donor and acceptor compounds as comonomer units is prepared. The polymer consists of a derivative of a luminescent dye [4‐dicyanmethylene‐2‐methyl‐6‐4H‐pyran (DCM); acceptor compound], which is copolymerized with fluorene (donor compound) to combine the properties of an electroactive polymer with a highly luminescent dye. Photochemical processing is achieved by UV irradiation of this copolymer in the presence of gaseous trialkylsilanes. This reagent selectively saturates the C?C bonds in the DCM comonomer units while leaving the fluorene units essentially unaffected. As a result of the photochemical process, the red electroluminescence of the acceptor compound vanishes, and the blue‐green electroluminescence from the polyfluorene units is recovered. Compared with previous approaches based on polymer blends, this copolymer approach avoids problems associated with phase‐separation phenomena in the active layer of OLEDs. © 2006Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4317–4327, 2006 相似文献
32.
Christian Constanda 《Proceedings of the American Mathematical Society》1998,126(3):827-834
Sommerfeld-type radiation conditions are indicated for the solutions of the system governing the small stationary oscillations in plates with transverse shear deformation, and a uniqueness theorem is proved in the case of the corresponding exterior Dirichlet and Neumann problems.
33.
34.
Joel L. Lebowitz Christian Maes Eugene R. Speer 《Journal of statistical physics》1990,59(1-2):117-170
We investigate the behavior of discrete-time probabilistic cellular automata (PCA), which are Markov processes on spin configurations on ad-dimensional lattice, from a rigorous statistical mechanics point of view. In particular, we exploit, whenever possible, the correspondence between stationary measures on the space-time histories of PCAs on
d
and translation-invariant Gibbs states for a related Hamiltonian on (
d+1). This leads to a simple large-deviation formula for the space-time histories of the PCA and a proof that in a high-temperature regime the stationary states of the PCA are Gibbsian. We also obtain results about entropy, fluctuations, and correlation inequalities, and demonstrate uniqueness of the invariant state and exponential decay of correlations in a high-noise regime. We discuss phase transitions in the low-noise (or low-temperature) regime and review Toom's proof of nonergodicity of a certain class of PCAs. 相似文献
35.
36.
The reaction of 2-chlorooxiranes 1 with thioamides and thioureas provides access to thiazoles, 4-hydroxy-4,5-dihydrothiazoles and 2-imino-2,3-dihydrothiazoles under mild conditions and with excellent yields. With 1 and selenourea, near quantitative yields of selenazoles are obtained. 相似文献
37.
Christian Buchta 《Monatshefte für Mathematik》1986,102(2):91-102
Denoty byp
d+i
(B
d
,d+m) the probability that the convex hull ofd+m points chosen independently and uniformly from ad-dimensional ballB
d
possessesd+i(i=1,...,m) vertices. We prove Mile's conjecture that, given any integerm, p
d+m
(B
d
,d+m)»1 asd». This is obvious form=1 and was shown by Kingman form=2 and by Miles form=3. Further, a related result by Miles is generalized, and several consequences are deduced.Dedicated to Professor E. Halwaka on the occasion of his seventieth 相似文献
38.
Hydroxylamine-O-sulfonic acid: a convenient reagent for the conversion of aldehydes into nitriles . Hydroxylamine-O-sulfonic acid (HAS) proved to be an excellent reagent for the conversion of aliphatic, aromatic and heteroatomic aldehydes into nitriles. There, aldehydes in the form of suspension in HAS water solution, react rapidely to give the corresponding nitriles in high yield. Only with formylpyridines could the intermediate oxime-O-sulfonic acids be isolated. 相似文献
39.
Maurice Prost Marcel Urbain Andr Schumer Christian Houben Clment Van Meerbeeck 《Helvetica chimica acta》1975,58(1):40-49
The authors describe the synthesis of decahydro-4-quinolinones and N-substituted 4-alkynyl-, 4-allyl- and 4-alkyldecahydro-4-quinolinols and discuss the stereochemical problems of this compounds. 相似文献
40.
Cross-linked block copolymers are used as adhesives in fiber-reinforced composite material manufactures for automotive applications. Good adhesion between the polymer matrix and fibers in the interphase region is required for the structural integrity of these materials. Experimental evidence indicates that superior adhesion is obtained when phase segregation occurs between the two matrix phase block copolymers. It is therefore desirable to predict the conditions under which phase segregation is expected to occur. Configurational bias Monte Carlo simulations of two-component, trifunctional block copolymer networks were carried out to investigate phase segregation in these materials. The effects of four principal parameters on phase segregation were examined: the weight fractions of the two components, the cross-link length, the connectivity of the network, and the ratio of the square-well interactions. The molecular simulation results confirmed trends observed in laboratory measurements. 相似文献