Synthesis,structure and electrochemical properties of a dioxomolybdenum(VI) complex with a ferrocene-containing ligand

Summary Bis[ferrocene aldehyde benzoylhydrazonato(1-)-N ¹,O]- dioxomolybdenum(VI) has been synthesized and characterized by x-ray diffraction and i.r.,¹H n.m.r. and electronic spectroscopies. The CH₂Cl₂/hexane solvate crystallizes in space group P2₁/n witha=11.149(6),b=20.463(8),c= 15.541(5) Å, =90.40(3)° andZ=4. The structure has been refined to R_w=0.049 based on 2886 independent reflections. The complex has distorted octahedral geometry with the two bidentate ligands coordinated through the oxygen and the azomethine nitrogen atoms. The MoO ₂ ²⁺ unit has the expectedcis geometry and the Mo-N bonds aretrans to the oxo-groups. The chelate rings are nearly planar but the cyclopentadienyl and phenyl rings are twisted out of the chelate rings. The electrochemical behaviour of the compound is also discussed: the two ferrocenyl groups appear to be independent with respect to oxidation and the molybdenum centre displays a nearly reversible one-electron reduction.     

Hindered rotation and electronic distribution in thiocarbamates

We wish to report here the isolation of methyl N-(p-methoxybenzyl)thiocarbamate, a natural product extracted from Pentadiplandra brazzena Bailli, and the synthesis of its homologue, benzyl N-(2-phenylethyl)thiocarbamate. The barrier to internal rotation calculated from a complete lineshape analysis of the temperature dependent ¹H n.m.r. spectra is discussed. The extent of delocalization on the three N, S and O substituents on the central trigonal carbon atom is gauged from a double labelling experiment.     

A study of the reactions KN→Σ(1385)π between 0.6 and 1.2 GeV/c

An energy-dependent partial-wave analysis of the reaction $\text{K}\text{N}\text{→Σ(1385)π}$ has been performed in the energy region lying between 1.65 and 1.85 GeV. The resonant amplitudes of seven well known Y¹ resonances have been determined, and used to compute the corresponding (8) ? (10) SU (3) coupling constants.     

Stereochimie de la reaction de rupture par le brome de la liaision siliciumaryle du dimethyl-1,2 phenyl-1 silacyclopentane

Stereospecific synthesis of geometric isomers of 1,2-dimethyl-1-phenylsilacyclopentane is described. We demonstrate that brominolysis of the arylsilicon bond occurs with predominant inversion of configuration at the silicon atom of the silacyclopentane ring.     

Etudes stereochimiques dans la serie du silacyclopentane: synthese de dimethyl-1,2 alcoxy-1 silacyclopentanes a stereoisomere preferentiel

The stereoselective alcoholysis of 1,2-dimethyl-1-chlorosilacyclopentane and the catalytic alcoholysis of 1,2-dimethylsilacyclopentane are described.