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61.
使用质谱、热分析手段研究了PMMA热解反应 .结果表明 ,在氮气中 ,PMMA -CH =CH2 有两个失重阶段 ,分别对应于主链末端双键引发的断链和主链无规则断链反应 ,转折点的失重率约为 2 6 % .其中 ,第一阶段的失重速率受扩散过程控制 ,平均表观活化能E为 15 8.5kJ/mol,lnA为 2 7.6 9;第二失重阶段为 1.5级化学反应 ,平均表观活化能E为 2 14 .79kJ/mol,lnA为 4 0 .4 6 .在空气中 ,PMMA也有两个失重阶段 ,反应机理为 1级化学反应 ,转折点处的失重率约为 70 % .其中在第一失重阶段平均表观活化能E为 130 .32kJ/mol,lnA为 2 4 .81,在此阶段中 ,过氧化基团的分解反应对PMMA的失重速率有重要影响 ;在空气中第二失重阶段平均表观活化能E为 78.2 5kJ/mol,lnA为 13.97. 相似文献
62.
This paper describes the application of a novel broadband acoustic sensor to evaluating the acoustic emissions from cavitation produced by a typical commercial 20 kHz sonochemical horn processor. Investigations of the reproducibility of the processor, and of the variation in cavitation emissions as a function of output setting and sensor location are described, and resulting trends discussed in terms of the broadband integrated power in the megahertz frequency range. Companion studies with a conventional membrane hydrophone have illustrated for the first time that cavitation emissions produced by a sonochemical horn processor can extend to frequencies beyond 20 MHz, and the sensor shows that significant nonlinearity can be seen in measured cavitation activity with increasing nominal output power. 相似文献
63.
64.
[reaction: see text] The type 2 intramolecular N-acylnitroso Diels-Alder reaction has been employed for the synthesis of substituted bridged bicyclic oxazinolactams. Upon oxidation of hydroxamic acid 6, a 3-benzylated oxazinolactam (7) was synthesized with complete diastereoselectivity. Elaboration of cycloadduct 7 liberated a cis-3,7-disubstituted azocin-2-one (9). 相似文献
65.
Liao JH Chen CT Chou HC Cheng CC Chou PT Fang JM Slanina Z Chow TJ 《Organic letters》2002,4(18):3107-3110
[structure: see text] A push-pull conjugated molecule, 2,7-bis(1H-pyrrol-2-yl)ethynyl-1,8-naphthyridine (BPN), has been designed to bind selectively with octyl glucopyranoside (OGU). The BPN/OGU quadruple hydrogen-bonding complex adopts a rigid BPN conformation in which the proton donor (d) and acceptor (a) relays (daad) are resonantly conjugated through the ethynyl bridge, inducing pi-electron delocalization, i.e., a charge transfer effect. The excellent photophysical properties make BPN a highly sensitive probe for monitoring glucopyranoside to a detection limit of approximately 100 pM. 相似文献
66.
Silviu Polosan Tahsin J. Chow Taiju Tsuboi 《Journal of Physical Organic Chemistry》2008,21(4):315-320
Electronic states and their energies are calculated for a mixed‐ligand Ir(III) compound, (5‐chloro‐8‐hydroxyquinoline) bis(2‐phenylpyridyl) iridium (called IrQ(ppy)2‐5Cl) using time‐dependent density functional theory (TDDFT) calculations and are compared with the experimental result. A good agreement is obtained between the calculated and measured absorption spectra. The d‐πQ* molecular orbital transition gives the lowest‐energy triplet state absorption band. Its energy is estimated as 1.84 eV (671 nm), which is close to the absorption band position of 1.86 eV (666 nm) observed for IrQ(ppy)2‐5Cl doped in 4,4′‐N,N′‐dicarbazole‐biphenyl (CBP) host and of 1.88 eV (660 nm) observed for IrQ(ppy)2‐5Cl doped in polystyrene (PS). The second triplet state absorption band is caused by d‐πppy transition. Its position is calculated as 2.51 eV (494 nm). The dipole moment is estimated as 3.45 D, which is lower than the dipole moment of fac‐Ir(ppy)3. This is understood by a reduced charge transfer between Ir(III) and quinoline ligand. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
67.
In this paper we introduce a concept of exponential dichotomy for linear skew-product semiflows (LSPS) in infinite dimensional Banach spaces, which is an extension of the classical concept of exponential dichotomy for time dependent linear differential equations in Banach spaces. We prove that the concept of exponential dichotomy used by Sacker-Sell and Magalhães in recent years is stronger than this one, but they are equivalent under suitable conditions. Using this concept we where able to find a formula for all the bounded negative continuations. After that, we characterize the stable and unstable subbundles in terms of the boundedness of the corresponding projector along (forward/backward) the LSPS and in terms of the exponential decay of the semiflow. The linear theory presented here provides a foundation for studying the nonlinear theory. Also, this concept can be used to study the existence of exponential dichotomy and the roughness property for LSPS.
68.
A detailed investigation of the conditions for formation and extraction of the thiocyanate complex of osmium by polyether-type polyurethane foam is reported. The complex which formed in solution was extracted through the “cation-chelation” mechanism and distribution coefficients of more than 104 were obtained. By using conditions which inhibit the formation of the osmium-thiocyanate complex, it was possible to leave 95% of osmium in the aqueous phase while extracting more than 95% of ruthenium into polyurethane foam. 相似文献
69.
70.
B.S.K. Chow 《Optics Communications》1974,11(3):235-237
A hologram of an object with field depth greatly exceeding the coherence length has been made with an ordinary gas laser, taking account of the reoccurence of the temporal coherence and its stability dependence on operating time. Only one object beam is used for a number of seperate exposures, so that the full output power is used. 相似文献