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161.
ZnO‐Coated Carbon Nanotubes: Inter‐Diffusion of Carboxyl Groups and Enhanced Photocurrent Generation 下载免费PDF全文
Chia‐I Hung Dr. Hua‐Chiang Wen Yao‐Cheng Lai Dr. Shih‐Hsin Chang Prof. Dr. Wu‐Ching Chou Prof. Dr. Wen‐Kuang Hsu 《Chemphyschem》2015,16(4):812-816
ZnO is a defect‐governed oxide and emits light at both visible and UV regimes. This work employs atomic layer deposition to produce oxide particles on oxygenated carbon nanotubes, and the composites only show emission profiles at short wavelengths. The quenching of defect‐related emissions at long wavelengths is verified, owing to carboxyl diffusion into oxygen vacancies, and doping is supported by ZnCO3 formation in oxide lattice. Fully coated tubes display an increased photocurrent and the quantum efficiency increases by 22 % relative to the bare nanotubes. 相似文献
162.
Chih-Ming Chou Shunpei Nobusue Shohei Saito Daishi Inoue Daisuke Hashizume Shigehiro Yamaguchi 《Chemical science》2015,6(4):2354-2359
A reproducible formation of strongly bent crystals was accomplished by structurally restraining macrocyclic π-conjugated molecules. The model π-units consist of two 9,10-bis(2-thienylethynyl)anthracenes with a strong propensity for stacking, which are connected in a macrocyclic fashion via two alkylene linkers. The correlation between the crystalline morphology and the macrocyclic structures restrained by a variety of flexible alkylene linker combinations was systematically studied. Bent crystals were obtained only with specific alkylene linkers of appropriate chain length. The alkylene linkers can adopt different conformations in the crystal packing, so as to fill voids within the macrocycle. The ability to form several similar molecular structures with different alkylene conformations gives rise to contaminations of different crystalline phases within a single crystal, and it is these phase contaminations which are responsible for the bending of the crystals. 相似文献
163.
Dale McMorrow Michon Irons Wyche Pi Tai Chou Michael Kasha 《Photochemistry and photobiology》2015,91(3):576-585
Trace quantities of hydrogen‐bonding impurities in otherwise highly purified and dried glassy hydrocarbon matrices at 77 K can modify the relative triplet state energy levels, and hence the photophysical properties of two aromatic ketones, xanthone and chromone, to the extent that the intrinsic spectroscopic properties are obscured. The intrinsic spectroscopic properties of each are revealed in multicrystalline n‐alkane Shpol'skii matrices, and also can be observed in rigorously purified and dried hydrocarbon glasses at 77 K. The extreme sensitivity to stoichiometric, and even substoichiometric quantities of hydrogen‐bonding impurities arises from the near‐degeneracy of the two lowest‐lying triplet states, and the sensitive nature of the n→π* blueshift phenomena to specific hydrogen‐bonding interactions. 相似文献
164.
Chia‐Chun Chou 《International journal of quantum chemistry》2015,115(7):419-425
A simple and easy‐to‐implement method is presented for the study of time‐dependent reaction dynamics by propagating an ensemble of transmitted quantum trajectories. During the trajectory evolution, reflected trajectories are gradually removed and all the remaining trajectories represent the transmitted subensemble. The removal process of reflected trajectories avoids numerical instabilities arising from node formation in the reactant region, and allows stable long‐time propagation of transmitted trajectories. This method is applied to a two‐dimensional model chemical reaction. Excellent computational results are obtained for the time‐dependent reaction probabilities evaluated by the time integration of the probability flux. © 2014 Wiley Periodicals, Inc. 相似文献
165.
In this paper, experiments involving interior impacts on soft, lead targets are described. The term “interior impact” refers to the impact of a projectile at the bottom of a predrilled hole in the target. It is known that impact of low-velocity projectiles into such soft targets results in plastic flow and cavities similar to those obtained in high-velocity impact of hard targets. Therefore, comparatively simple rifle-propelled projectile impacts on soft targets may yield useful information for high-speed hard-target impacts. Double impacts with a short-time interval, on the order of microseconds, between projectile arrivals were conducted. The leading projectile creates a plastic flow in the target which partially seals the entrance hole. The trailing projectile must first force open the passage hole before achieving additional penetration. The total penetration was measured for different time intervals between the projectiles. A method was developed to obtain double impacts at the same point. The method utilizes a duplex round, which is made up of two separate projectiles fired from the same cartridge. With this round, a series of impact experiments was conducted. It was learned that occlusion, or the close up of the hole, is negligible for nearly simultaneous projectiles (less than 10 μs between impacts), and greatest with about 80 to 100 μs between impacts. The projectile velocity was measured by the use of properly placed photodiodes. 相似文献
166.
This paper presents the design of a unique materials-testing system capable of medium strain rates of from 10?4 to 102/s. The design incorporates both closed-loop hydraulic operation with that of open-loop pneumatic operation. A novel design permits accurate specimen alignment and a stiff frame which exceeds 17×106 lb/in. (11.7×104 MPa). The mechanine is able to perform conventional tension/compression tests, fatigue tests and, with slight modification, biaxial-stress-tube tests and triaxial-stress tests. The accurate alignment capability coupled with high frame stiffness and the pneumatic operation enables the testing of brittle materials with rigid grips. Titanium 6-6-2 was tested in both tension and compression at strain rates from 10?4 to about 10/s at four selected temperatures. The material showed a slight strain-rate sensitivity. Yield stress was shown to increase with strain rate while ductility decreased at each test temperature. 相似文献
167.
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169.
The amorphous and crystalline phase behavior, spherulite morphology, and interactions between amorphous poly(vinyl acetate)
(PVAc) and poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid) (PHBV) were examined using differential scanning calorimetry,
polarized-light optical and scanning electron, atomic-force microscopy (DSC, POM, SEM, AFM), and small-angle X-ray scattering
(SAXS). The PHBV/PVAc blend was found to be miscible with an almost linear T
g-composition relationship, indicating perfect homogeneity. Interaction parameter by melting point depression is a negative
value of χ = −0.32, suggesting quite favorable interaction strength. With the intimate interaction between the amorphous PVAc and crystalline
PHBV polymers, effects of PVAc on the spherulitic morphology of PHBV are quite significant. Owing to the higher T
g of PVAc (than that of PHBV), the spherulite growth rate of PHBV was depressed by increasing PVAc content in blends. Neat
PHBV exhibits ring-banded spherulites when crystallized at Tc = 60 ~ 110° C {T_{\rm{c}}} = {6}0\sim {11}0^\circ {\hbox{C}} ; however, with increasing PVAc content in the blends, the temperature range at which the PHBV/PVAc blends exhibit ring-banded
spherulites remains similar but the regularity increases, and the inter-ring spacing significantly decreases. In addition,
the spherulite size and ring-band patterns therein are strongly dependent on T
max (190 vs. 220 °C, respectively, for erasing prior nuclei), from which the blends were quenched to a T
c (60–110 °C) for crystallization. For PHBV/PVAc blends crystallized at the same T
c from different T
max, higher T
max tends to erase nuclei, leading to larger spherulites. However, such larger spherulites owing to higher T
max are not necessarily packed with thicker lamellae. 相似文献
170.
Chou TH Hong SJ Liang YE Tsao HK Sheng YJ 《Langmuir : the ACS journal of surfaces and colloids》2011,27(7):3685-3692
Drop-on-fiber is commonly observed in daily life and is closely related to digital microfluidics. The wetting behavior of droplet-on-fiber is different from that of droplet-on-plane due to the global cylindrical shape. It is generally believed that the equilibrium geometric shape of a droplet on a fiber takes either asymmetric clam-shell or axisymmetric barrel conformation in the absence of gravity. The barrel-to-clam-shell transition is determined by the stability condition. Nonetheless, experimental observations showed that both barrel and clam-shell conformations can coexist in some situations and thus indicated the existence of the multiple stable states. In this Article, the phase diagrams of droplet-on-fiber, that is, the plots of droplet volume against contact angle, are established on the basis of the finite-element simulation (Surface Evolver). When the gravity effect is absent, there are three regimes including barrel, clam-shell, and coexistence of barrel and clam-shell. As the gravity effect is considered, there exist three regimes, including (I) downward clam-shell, (II) coexistence of barrel and clam-shell, and (III) falling-off. 相似文献