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151.
152.
A polyacrylonitrile (PAN) fiber was adopted for the backbone of a chelate polymer and poly(acrylo‐amidino ethylene amine) (PAEA) was prepared through a one‐step reaction between the PAN fiber and ethylenediamine (EDA). The maximum removal capacity and degree of substitution were 7.8 meq per gram of dried PAEA and 98%, respectively. The PAEA was tested as an adsorbent in single and two‐component metal aqueous solutions under changing pH. The Cu2+ ion accomplished maximum adsorption amount at pH 3 and the order of maximum adsorbed amounts on PAEA is Cu2+ > Ag+ > Zn2+ > Ni2+ > Pb2+ in molar basis. FT‐IR spectroscopy was employed to characterize the chemical bonding in metal aqueous solutions and surface morphology was examined using atomic force microscopy (AFM) and scanning electron microscopy (SEM). Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
153.
[reaction: see text] A conformationally locked carbocyclic version of puromycin amino nucleoside was synthesized via Mitsunobu coupling of a 3-azido-substituted carbocyclic moiety with 6-chloropurine without interference from the azido group reacting with triphenylphosphine. The requisite 3-azido-substituted carbocyclic pseudosugar was prepared by a double inversion of configuration at C3' (nucleoside numbering) involving a nucleophilic displacement with azide. 相似文献
154.
155.
A spectrofluorimetric method has been developed for the determination of trace Cu(II) in real samples with 4,5-dihydroxy-l,3-benzenedisulfonic acid (Tiron) as a fluorimetric reporter. Tiron is very soluble in water and is a good fluorimetric reagent. However, as Tiron was complexed with Cu(II), the fluorescence intensity decreased proportionally to the concentration of Cu(II) by a static quenching effect. The excitation wavelength and the fluorescence wavelength of Tiron were 294 and 350 nm, respectively, as it was caused by a quenching effect from Cu(II) at pH 8.0. The highest sensitivity was shown at Tiron concentration of 5.0x10(-5) M. To enhance the quenching effect, the Cu(II)-Tiron complex solution was heated up to 80 degrees C for 90 min. As for Cu(II), the interference by Co(II) was very serious, which was eliminated by oxalate ion. The linear response to Cu(II) was shown at the concentration range between 5.0x10(-7) and 1.0x10(-5) M. With this proposed method, the detection limit of Cu(II) was 3.83(+/-0.09)x10(-7) M. Recoveries of Cu(II) in the diluted brass samples and the stream water samples were almost 100%. Based on results from the experiment, this proposed technique could be applied to the practical determination of Cu(II) in real samples. 相似文献
156.
Kim Y Choi YH Chin YW Jang YP Kim YC Kim J Kim JY Joung SN Noh MJ Yoo KP 《Journal of chromatographic science》1999,37(12):457-461
An investigation of the effect of plant matrix on the supercritical fluid extraction efficiency of five schisandrin derivatives is reported, exhibiting a great difference with respect to extraction efficiency depending on the matrix. Pure supercritical CO2 at 60 degrees C and 34.0 MPa cannot fully recover schisandrin derivatives from the leaves as much as from the other matrices. Only 36.9% of these compounds are extracted from leaves of Schisandra chinensis by supercritical CO2 in comparison with organic solvent extraction. However, more than 80% of schisandrin derivatives are obtained from both stem and fruit parts. Ethanol addition also shows a different effect depending on plant matrix; that is, CO2 modified with 10% ethanol could enhance the yield of schisandrin derivatives from leaves by four times when compared with that of pure CO2, but it has little effect on both stems and fruits. 相似文献
157.
A theoretical investigation of the gas-phase oxidation reaction of the saturated tert-butyl radical.
The radical-radical reaction mechanisms and dynamics of ground-state atomic oxygen [O(3P)] with the saturated tert-butyl radical (t-C4H9) are investigated using the density functional method and the complete basis set model. Two distinctive reaction pathways are predicted to be in competition: addition and abstraction. The barrierless addition of O(3P) to t-C4H9 leads to the formation of an energy-rich intermediate (OC4H9) on the lowest doublet potential energy surface, which undergoes subsequent direct elimination or isomerization-elimination leading to various products: C3H6O + CH3, iso-C4H8O + H, C3H7O + CH2, and iso-C4H8 + OH. The respective microscopic reaction processes examined with the aid of statistical calculations, predict that the major addition pathway is the formation of acetone (C3H6O) + CH3 through a low-barrier, single-step cleavage. For the direct, barrierless H-atom abstraction mechanism producing iso-C4H8 (isobutene) + OH, which was recently reported in gas-phase crossed-beam investigations, the reaction is described in terms of both an abstraction process (major) and a short-lived addition dynamic complex (minor). 相似文献
158.
H. Bruchertseifer Choi Valsek K. A. Gavrilov M. Schwarzenberg 《Journal of Radioanalytical and Nuclear Chemistry》1983,77(1):97-104
The electrolytic deposition of the hydroxides of rare earth and transplutonium elements on nickel holders from α-hydroxyisobutyrate
solutions of 10−5 M to 5·10−1 M concentrations has been investigated in the presence of ammonium chloride. It is shown that at total concentrations of
≥10−12 M of rare earth and transplutonium elements, their electrodeposition proceeds with a 90% yield. 相似文献
159.
Lee K Song H Kim B Park JT Park S Choi MG 《Journal of the American Chemical Society》2002,124(12):2872-2873
Reaction of Rh(6)(CO)(9)(dppm)(2)(mu(3)-eta(2),eta(2),eta(2)-C(60)) (1) with C(60) in refluxing chlorobenzene followed by treatment with CNR (R = CH(2)C(6)H(5)) at room temperature affords the first fullerene-metal sandwich complex Rh(6)(CO)(5)(dppm)(2)(CNR)(mu(3)-eta(2),eta(2),eta(2)-C(60))(2) (2). Compound 2 has been characterized by an X-ray diffraction study. Electrochemical study of 2 reveals six well-separated reversible redox couples localized at C(60) cages due to a strong electronic communication between the two C(60) centers via the Rh(6) cluster spacer. 相似文献
160.
Injection-molded, short-glass-fiber-reinforced high-impact polystyrene was investigated under uniaxial tension with special attention to the effects of fiber and rubber concentration on fracture behavior. According to a fracture morphology study performed by polarized optical and scanning electron microscopy, crazes were consecutively initiated from rubber-styrene composite particles and from fiber ends. The rubber particles exhibited an intra-particle failure mode which resulted from the failure manner of the matrix becoming of a more brittle character with increasing fiber fraction. Fibers were surrounded by neigh boring growing crazes. Failure at the fiber-matrix interfaces proceeded with an increase in the number of crazes. With increasing concentration of the fibers, crazing at rubber particles appeared to be suppressed and crazing occurred more preferentially at the fiber ends, which accelerated a macroscopic fracture.Dedicated to Prof. H. H. Kausch on the occasion of his 60th birthday. 相似文献