Biogenic synthesis from <Emphasis Type="Italic">Prunus</Emphasis> × <Emphasis Type="Italic">yedoensis</Emphasis> leaf extract,characterization, and photocatalytic and antibacterial activity of TiO<Subscript>2</Subscript> nanoparticles

Green synthesis of TiO₂ nanoparticles (NPs) from Prunus × yedoensis leaf extract (PYLE), and their application for removal of phosphate and their antibacterial activity, were studied for the first time. NPs were obtained using a green chemistry approach from 0.1 M TiO₂ and PYLE at ratio of 1:1 (v/w). Initial confirmation of production of TiO₂ NPs was provided by a color change from white to light yellow, then calcination was performed at 500 °C for 1 h. The TiO₂ NPs were characterized using various analytical techniques such as ultraviolet–visible (UV–Vis) spectroscopy, X-ray diffraction analysis, Fourier-transform infrared spectroscopy, Raman spectroscopy, UV–Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy. The results indicated that the optimal amount of TiO₂ NPs for removal of phosphate was 10 mg/l (10 ppm) with duration of 25 min. Furthermore, the antibacterial activity of TiO₂ NPs was also investigated using two different bacteria (Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli) in aqueous medium. The results revealed highly efficient sunlight-driven photocatalytic and antibacterial activity of TiO₂ NPs.     

Synthesis of water soluble metalloporphyrin-cored amphiphilic star block copolymer photocatalysts for an environmental application

Two series of water-soluble metalloporphyrin-cored amphiphilic star block copolymers were synthesized by controlled radical polymerizations such as atom transfer radical polymerization (ATRP) and reversible addition fragmentation chain transfer (RAFT), which gave eight amphiphilic block copolymer arm chains consisting of poly(n-butyl acrylate-b-poly(ethylene glycol) methyl ether methacylate) (PnBA-b-PEGMEMA, M_n,GPC = 78,000, M_w/M_n = 1.2, 70 wt% of PPEGMEMA) and poly(styrene-b-2-dimethylamino ethyl acrylate) (PS-b-PDMAEA, M_n,GPC = 83,000, M_w/M_n = 1.2, 67 wt% of PDMAEA), yielding porphyrin(Pd)-(PnBA-b-PPEGMEMA)₈ and porphyrin(Pd)-(PS-b-PDMAEA)₈, respectively. Obtained metalloporphyrin polymer photocatalysts were homogeneously solubilized in water to apply to the removal of chlorophenols in water, and was distinguished from conventional water-insoluble small molecular metalloporphyrin photocatalysts. Notably, we found that the water-soluble star block copolymers with hydrophobic–hydrophilic core–shell structures more effectively decomposed the chlorophenol, 2,4,6-trichlorophenol (2,4,6-TCP), in water under visible light irradiation (k = 1.39 h^?1, t_1/2 = 0.5 h) in comparison to the corresponding water-soluble star homopolymer, because the hydrophobic core near the metalloporphyrin effectively captured and decomposed the hydrophobic chlorophenols in water.     

Full automatic synthesis of [<Superscript>18</Superscript>F]THK-5351 for tau protein PET imaging in Alzheimer’s disease patients: 1 year experience

[¹⁸F]THK-5351, a new candidate for tau protein imaging, is based on an aryl quinoline structure. We report the full automatic synthesis using disposable cassettes under pH controlled [¹⁸F]fluorination. After the trapping of 88.5 ± 21.9 GBq of [¹⁸F]fluoride, it was eluted with potassium methansulfonate (KOMs) (pH 7.8)/K₂₂₂. After drying, 3 mg of the precursor was added to 1 mL DMSO and subjected to [¹⁸F]fluorination at 110 °C for 10 min. After hydrolysis, the final product was purified by HPLC. The overall radiochemical yield was 31.9 ± 11.1% (n = 22), satisfying all quality control criteria. It was stable for up to 6 h with high radiochemical purity as 99.8 ± 0.5%.     

Cyclic Group Actions on 4-Manifolds

Let X be a closed, oriented Riemannian 4-manifold. Suppose that a cyclic group Z( _p (p is prime) acts on X by an orientation preserving isometry with an embedded Riemann surface as fixed point set. We study the representation of Z _p on the Spin^c-bundles and the Z _p-invariant moduli space of the solutions of the Seiberg–Witten equations for a Spin^c-structure X. When the Z _p action on the determinant bundle det L acts non-trivially on the restriction L| over the fixed point set , we consider -twisted solutions of the Seiberg-Witten equations over a Spin^c-structure ' on the quotient manifold X/Z _p X', (0,1). We relate the Z _p -invariant moduli space for the Spin^c-structure on X and the -twisted moduli space for the Spin^c-structure on X'. From this we induce a one-to-one correspondence between these moduli spaces and calculate the dimension of the -twisted moduli space. When Z _p acts trivially on L|, we prove that there is a one-to-one correspondence between the Z _p -invariant moduli space M( ^Zp and the moduli space M (") where ' is a Spin^c-structure on X' associated to the quotient bundle L/Z _p X'. vskip0pt When p = 2, we apply the above constructions to a Kahler surface X with b ₂ ⁺ (X) > 3 and H ₂(X;Z) has no 2-torsion on which an anti-holomorphic involution acts with fixed point set , a Lagrangian surface with genus greater than 0 and []2H ₂(H ;Z). If _K ^X 2 > 0 or K _X ² = 0 and the genus g()> 1, we have a vanishing theorem for Seiberg–Witten invariant of the quotient manifold X'. When K _X ² = 0 and the genus g()= 1, if there is a Z ²-equivariant Spin^c-structure on X whose virtual dimension of the Seiberg–Witten moduli space is zero then there is a Spin^c-structure " on X' such that the Seiberg-Witten invariant is ±1.     

Anti-symplectic involutions with lagrangian fixed loci and their quotients

We study the lagrangian embedding as a fixed point set of anti-symplectic involution on a symplectic 4-manifold . Suppose the fixed loci of are the disjoint union of smooth Riemann surfaces ; then each component becomes a lagrangian submanifold. Furthermore, if one of the components is a Riemann surface of genus , then its quotient has vanishing Seiberg-Witten invariants. We will discuss some examples which allow an anti-symplectic involution with lagrangian fixed loci.

     

Catalytic and highly regiospecific carbon-carbon bond formation at alpha-position of Michael acceptor by palladium complex

Activated olefins react with allyl acetates and Bu3SnH in the presence of a catalytic amount of a palladium catalyst to afford the corresponding products which construct a new C-C bond selectively at the alpha-position of Michael acceptors.     

Nickel-catalyzed asymmetric grignard cross-coupling of dinaphthothiophene giving axially chiral 1,1'-binaphthyls

Asymmetric cross-coupling of dinaphtho[2,1-b:1',2'-d]thiophene with ArMgBr (Ar = Ph, 4-MeC6H4, 4-MeOC6H4) proceeded with high enantioselectivity in THF at 20 degrees C in the presence of 3 mol % of a nickel catalyst generated from Ni(cod)2 and a chiral oxazoline-phosphine ligand to give high yields of axially chiral 2-mercapto-2'-aryl-1,1'-binaphthyls, whose enantiomeric excesses are over 93%. The mercapto group in the chiral binaphthyl was converted into iodo, boryl, and phosphino groups without racemization.     

Photoassociation of sodium in a Bose-Einstein condensate

We form ultracold Na2 molecules by single-photon photoassociation of a Bose-Einstein condensate, measuring the photoassociation rate, linewidth, and light shift of the J = 1, v = 135 vibrational level of the A1 Sigma (+)(u) molecular state. The photoassociation rate constant increases linearly with intensity, even where it is predicted that many-body effects might limit the rate. Our observations are in good agreement with a two-body theory having no free parameters.     

Intensities of resonant brillouin scatterings from multicomponent exciton-polaritons

To reduce the arbitrariness in the current analysis of resonant Brillouin scattering (RBS) from multicomponent polaritons, the intensities of scattering peaks are theoretically studied. The interaction among the multicomponent excitons may contain linear and quadratic terms in translational wave vector, electron-hole exchange interaction, and any other terms that retain translational symmetry. As the scattering mechanisms due to TA and LA phonons, we consider various deformation and piezoelectric potentials. In certain cases, this theory leads to a “selection rule”, which can solve the controversy between the two different dispersion curves for CuBr obtained from RBS and two photon resonant Raman scattering, in favor of the latter. The theory also provides a basis to discuss the problem of additional boundary conditions for multicomponent polaritons in terms of the relative intensities of scattering peaks.