全文获取类型
收费全文 | 69882篇 |
免费 | 10252篇 |
国内免费 | 6629篇 |
专业分类
化学 | 46886篇 |
晶体学 | 659篇 |
力学 | 4661篇 |
综合类 | 515篇 |
数学 | 8449篇 |
物理学 | 25593篇 |
出版年
2024年 | 228篇 |
2023年 | 1399篇 |
2022年 | 2281篇 |
2021年 | 2353篇 |
2020年 | 2521篇 |
2019年 | 2422篇 |
2018年 | 2188篇 |
2017年 | 1939篇 |
2016年 | 2964篇 |
2015年 | 3078篇 |
2014年 | 3650篇 |
2013年 | 4843篇 |
2012年 | 5889篇 |
2011年 | 6014篇 |
2010年 | 4079篇 |
2009年 | 4018篇 |
2008年 | 4187篇 |
2007年 | 3788篇 |
2006年 | 3567篇 |
2005年 | 3093篇 |
2004年 | 2478篇 |
2003年 | 1895篇 |
2002年 | 1682篇 |
2001年 | 1520篇 |
2000年 | 1418篇 |
1999年 | 1563篇 |
1998年 | 1330篇 |
1997年 | 1169篇 |
1996年 | 1227篇 |
1995年 | 1071篇 |
1994年 | 1007篇 |
1993年 | 865篇 |
1992年 | 768篇 |
1991年 | 664篇 |
1990年 | 555篇 |
1989年 | 481篇 |
1988年 | 366篇 |
1987年 | 349篇 |
1986年 | 297篇 |
1985年 | 300篇 |
1984年 | 202篇 |
1983年 | 176篇 |
1982年 | 145篇 |
1981年 | 112篇 |
1980年 | 82篇 |
1978年 | 56篇 |
1977年 | 52篇 |
1976年 | 50篇 |
1975年 | 57篇 |
1973年 | 57篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
961.
Characterization and electrochemical investigation of boron-doped mesocarbon microbead anode materials for lithium ion batteries 总被引:1,自引:0,他引:1
Mao-Hui Chen Guo-Tao Wu Guang-Ming Zhu Jin-Kua You Zu-Geng Lin 《Journal of Solid State Electrochemistry》2002,6(6):420-427
The structure and anodic performance of boron-doped and undoped mesocarbon microbeads (MCMBs) have been comparatively studied
and the results obtained by XPS, XRD, SEM, Raman spectroscopy and electrochemical measurements are discussed. It is found
that boron doping introduces a depressed d
002 spacing and the larger amount of "unorganized carbon", which induces vacancy formation in the graphite planes and leads to
a quite different morphology from that of the undoped material. Electrochemical charge/discharge cycle tests indicated that
after boron doping the lithium intercalation was carried through at a somewhat higher potential, being attended by greater
irreversible capacity loss.
Electronic Publication 相似文献
962.
963.
在自制的硅基纤维素-三(3,5-二甲基苯基氨基甲酸酯)高效液相色谱手性固定相上(HPLC-CSP),优化了1-(6'-甲氧基萘)乙醇氢酯基化反应产物-萘普生甲酯手性分离的条件,测定了相应的一系列不对称氢酯基化反应产物的对映体过剩值(e.e.值)。结果表明,在CDMPC-CSP手性柱上用HPLC测定此类不对称催化反应的光学产率,评价催化剂体系的手性选择是一种非常理想的方法。 相似文献
964.
纳米级金膜微电极的制作,表征及异相催化反应 总被引:1,自引:0,他引:1
报道了纳米级金膜微电极的制作方法,用XPS及SEM对电极表面进行了表征,考察了该电极的循环伏安及计时电流特性,在聚吡咯修饰微带金电极上成功地实现了葡萄糖氧化酶和电子传递媒体Fe(CN)6^3-的同时固定,并研究了GOD/Fe(CN)6^3-/PPy微酶电极对葡萄糖的响应,稳态响应电流与葡萄糖浓度之间存在Michealis-Menten动力学特征。 相似文献
965.
James K. Chen Stuart L. Schreiber 《Angewandte Chemie (International ed. in English)》1995,34(9):953-969
Combinatorial chemistry is a laboratory emulation of natural recombination and selection processes. Strategies in this developing discipline involve the generation of diverse, molecular libraries through combinatorial synthesis and the selection of compounds that possess a desired property. Such approaches can facilitate the identification of ligands that bind to biological receptors, promoting our chemical understanding of cellular processes. This article illustrates that the coupling of combinatorial synthesis, multidimensional NMR spectroscopy, and biochemical methods has enhanced our understanding of a protein receptor used commonly in signal transduction, the Src Homology 3 (SH3) domain. This novel approach to studying molecular recognition has revealed a set of rules that govern SH3–ligand interactions, allowing models of receptor–ligand complexes to be constructed with only a knowledge of the polypeptide sequences. Combining combinatorial synthesis with structural methods provides a powerful new approach to understanding how proteins bind their ligands in general. 相似文献
966.
聚双环戊二烯反应注射成型 总被引:3,自引:0,他引:3
本文介绍了国外有关聚双环戊二烯反应注射成型的研究进展,讨论了国内进行聚双环戊二烯反应注射成型开发研究的现实意义,并对这一领域的发展进行了展望 相似文献
967.
968.
A biological organism (chitosan) was utilized to preconcentrate lead ions from tap water. This preconcentration was achieved by mixing 0.8 ml of chitosan slurry with 10-50 ml of lead-containing solution and subsequently separating by centrifugation. The chitosan paste was then dissolved in 1 ml of 0.2% nitric acid and analysed by graphite furnace atomic absorption spectrometry. The extraction efficiency can approach 100% in the pH range 4-10. The amount of chitosan used was not critical. The effect of some impurities was also investigated. If six samples were prepared simultaneously, the time needed to preconcentrate each sample was less than 3 min. Two different modes of standard addition (the standard lead solutions being added before and after preconcentration) were used for analysis of tap water samples, and the results obtained by the two modes were found to be quite consistent. 相似文献
969.
作者调查了珠海市568名0~6岁健康儿童的发锌含量,结果表明,集体儿童的低锌发生率为59.1%,门诊儿童为72.04%,在珠海市儿童中低锌有较高的发生率。 相似文献
970.
Synthesis and characterization of segmented liquid crystal poly(azoxy polyester-co-polyoxypropylene)
Jaine-Ming Huang Jen-Feng Kuo Chuh-Yung Chen 《Journal of polymer science. Part A, Polymer chemistry》1995,33(1):165-173
In this study a series of a segmented copolyester, poly(4,4′-dioxy-2,2′-dimethyl-azoxybenzene dodecanedioyl) (PMABD)-co-polyoxypropylene 400 (POP), was prepared. The chain length of PMABD studied (n) was varied from 7.8-18.2, and that of POP was unchanged. The intrinsic viscosity of the segmented copolyesters was 1.04-1.30, and the number average molecular weight obtained was 2.53 × 104?3.49 × 104 g/mol. The mesophase texture and thermal properties of the segmented copolyesters were measured as functions of n. It was found that the insert of flexible POP between those liquid crystalline domains of PMABD did affect thermotropic properties of PMABD. As the n value was 9.0 and 7.8 (or 7.4 and 8.6% by weight POP) the texture appeared as cholesteric-like oily streaks. The effect could not be attained by simply copolymerizing a mesogenic moiety with a pair of spacers of different lengths. The fluidity and domain structure of the flexible dodecanedioyl-POP-dodcanedioyl segments are taken into account for the obtained results. © 1995 John Wiley & Sons, Inc. 相似文献