Practical synthesis of new functionalized tetraphenylenes

The practical synthesis procedure of substituted tetraphenylene derivatives involving the synthesis of a precursor for 4, 7-dunethoxyisobenzofuran and Diets-Alder addition of 4, 7-dimethoxyisobenzofuran generated in situ to 5, 6, 11,12-te-tradehydrodibenzo[a,e]cyclooctene, followed by a low valent titanium mediated deoxygenation to give 1,4, 11, 14-tetra-methoxy-dibenzo[b, n] tetraphenylene, which can be further demethyiated to the corresponding phenolic compound, which was acetylated to afford 1,4,11,14-tetraacetoxy-dibenzo-[ b, n] tetraphenylene.     

A New ent-Kaurane Diterpenoid from Isodon enanderianus

Isodon enanderianus (Hand. -Mazz.) H. W. Li, has been used in folk medicine as anti-inflammatory and detoxified agent1. The Isodon genus is known to be rich in ent-kaurane diterpenoids, a series of new ent-kaurane diterpenoids have been isolated from the dried leaves of I. enanderianus2-4. In order to find more biologically active substances, we have carefully investigated the chemical constituents of I. enanderianus collected in Shiping county of Yunnan province, and as a result, enanderi…     

Red Electroluminescence and Photoluminescence from Novel Binuclear Europium Complex with Squaric Acid Ligand

Organic electroluminescent devices (OELDs) have attracted much attention for several years because of their potential application in large area, multi-colored flat panel displays1-5. The green organic EL display using Alq3 as emitter was commercialized in 19976. However, red-emitting OELD with excellent properties has not been well developed. In order to realize practical full-color OELDs, it is considered very important to develop red and blue emitting materials with excellent propert…     

STUDY ON THE BLOOD FAT REGULATION OF THE FUCOIDA-GALACTOSAN SULFATE (FGS) FROM LAMINARIA JAPONICA

1. INTRODUCTION Blood fat primarily contains cholesterol, cholesterol ester, phosphatide, triglyceride and free fatty acid in serum of human being and mammalian. Under physiological conditions, the lipids transport in the form of lipoproteins linked with the proteins. Except for the free fatty acid linked with albumin, the other lipids are linked with the globular proteins into high-density lipoproteins (HDL), low density lipoproteins (LDL), very low density lipoproteins (VLDL) and so…     

Instrumentation of coherent X-ray imaging and the primary experimental results

Coherent X-ray microscopy has advanced towards higher-energy, more brilliant sources over the past decade since its demonstrations, and many advancements have been made towards optimizing this imaging technique. Here we present both the experimental instrument for obtaining diffraction patterns and the primary reconstruction of yeast cell 2D projection. In addition, the characteristics of the existing optics at BL29XUL of SPring-8 Facility and the method of image reconstruction are discussed.     

高碘酸钾法测钢铁及合金中锰的改进建议

试样经酸溶解后,以磷酸-高氯酸混合酸(4 1)或(9 1)氧化至冒烟.在硫酸、磷酸介质中,用高碘酸钾将锰氧化到七价,测其吸光度.     

Off-diagonal long-range order of the wave function in terms of the alternate molecular bonding geminals

It is shown that in the quantum structural approach to high-Tc superconductivity, the wave function in terms of the alternate molecular bonding geminals possesses off-diagonal long-range order (ODLRO).     

La_(0.5)M_(0.5)MnO_3(M=Sr,Ba)的水热合成与表征

我们用水热法合成了钙钛矿锰氧化物La0.5M0.5MnO3(M=Sr,Ba)系列样品,研究了制备条件对结构、形貌和磁性的影响.     

A note on the crossed product R(A, α) associated with PSL_2(R)

Given the hyperbolic measure dxdy/y2 on the upper half plane H, the rational actions of PSL2(R) on H induces a continuous unitary representation α of this group on the Hilbert space L2(H, dxdy/y2). Supposing that A = {Mf : f ∈ L∞(H, dxdy/y2)}, we show that the crossed product R(A,α) is of type I. In fact, the crossed product R(A,α) is *-isomorphic to the von Neumann algebra B(L2(P,ν))■LK, where LK is the abelian group von Neumann algebra generated by the left regular representation of K.     

GLOBAL CONVERGENCE OF NONMONOTONIC TRUST REGION ALGORITHM FOR NONLINEAR OPTIMIZATION

§ 1　 IntroductionIn this paper we study the following nonlinear equality constrained optimization prob-lem:minimize f(x) ,subjectto h(x) =0 ,(P)where h(x) =(h1 (x) ,h2 (x) ,...,hm(x) ) T,f and hi(i=1 ,2 ,...,m) are Rn→R twice conti-nously differentiable(m≤n) .Many authors have studied the problem(P) with trustregion method(see,references[1～ 3 ] ) .These methods have the same property:to enforce strict monotonicity for meritfunction at every iteration.Paper[4 ] shows thatstrictmonotonic …