全文获取类型
收费全文 | 208篇 |
免费 | 3篇 |
专业分类
化学 | 129篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 16篇 |
物理学 | 62篇 |
出版年
2021年 | 2篇 |
2019年 | 2篇 |
2016年 | 3篇 |
2014年 | 5篇 |
2013年 | 3篇 |
2012年 | 8篇 |
2011年 | 5篇 |
2010年 | 4篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 18篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1976年 | 3篇 |
1974年 | 4篇 |
1973年 | 11篇 |
1972年 | 2篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 7篇 |
1967年 | 2篇 |
1962年 | 1篇 |
1961年 | 3篇 |
1960年 | 2篇 |
1957年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有211条查询结果,搜索用时 15 毫秒
41.
Hiroshi Mitsui Fumio Hosoi Tsutomu Kagiya 《Journal of polymer science. Part A, Polymer chemistry》1970,8(2):451-461
The effects of hydrogen on the γ-radiation-induced polymerization of ethylene were studied from the viewpoint of polymer structure and kineties. All experiments were carried out at 30°C. In the polymerization of ethylene containing 21.6% hydrogen, the solid polymer was obtained as a main product, while no liquid product was found. There was no difference in hydrogen contents before and after the irradiation; and acetylene, ethane, butane, and butene-1 were found as gaseous products. The polymer yield increased almost proportionally with dose rate in the presence of 8.0% hydrogen; on the other hand the molecular weight was independent of dose rate. At hydrogen contents of 0–8%, the polymerization rate increased with reaction time and decreased with hydrogen content. The molecular weight also increased with the time, and the extent of the increment decreased with the time and hydrogen content. The number of moles of polymer chain increased proportionally with the reaction time and increased linearly with hydrgen concentration. These results were analyzed by using a graphical evaluation method for kinetics, and the effects of hydrogen on the each elementary step in the polymerization were discussed. 相似文献
42.
The direct application of electrokinetic phenomena to detergency was investigated. Experiments were carried out to remove particles from substrate by electro-osmosis. A model system which consisted of spherical nylon particles of 5m in mean diameter, a quartz plate, and wash liquid were used in analyzing the kinetic process of particle removal from substrate. When an electric field was applied to the system, electro-osmotic flow took place, and hence the particles were removed from the quartz surface. The -potentials of nylon particles and quartz plate were measured by electrophoresis. The rate constants of removal,, were obtained from the changes with time in the ratio of particle residue by applying the first-order reaction scheme. The value of increased with increasing electric field and with increasing concentration of surfactant. The total force of interaction between particle and plate was calculated on the basis of heterocoagulation theory of colloid stability.It was found from results thus obtained that the hydrodynamic force due to the electro-osmotic flow worked effectively as a mechanical force on the removal process and the adhesion force of particle to substrate reduced by adding surfactant. 相似文献
43.
44.
Akutsu M Koyasu K Atobe J Hosoya N Miyajima K Mitsui M Nakajima A 《The journal of physical chemistry. A》2006,110(44):12073-12076
The geometric and electronic structures of aluminum binary clusters, AlnX (X = Si and P), have been investigated, using mass spectrometry, anion photoelectron spectroscopy, photoionization spectroscopy, and theoretical calculations. Both experimental and theoretical results show that Al12Si has a high ionization energy and low electron affinity and Al12P has a low ionization energy, both with the icosahedral structure having a central Si or P atom, revealing that Al12Si and Al12P exhibit rare-gas-like and alkali superatoms, respectively. Experiments confirmed the possibility that the change in the total number of valence electrons on substitution could produce ionically bound binary superatom complexes, the binary cluster salts Al12P+ F- and Al12B- Cs+. 相似文献
45.
Ultrafast photosynthetic reduction of elemental sulfur by Au nanoparticle-loaded TiO2 总被引:1,自引:0,他引:1
Kiyonaga T Mitsui T Torikoshi M Takekawa M Soejima T Tada H 《The journal of physical chemistry. B》2006,110(22):10771-10778
Nanometer-sized gold particles with varying mean size from 3.2 to 12.2 nm were loaded on the surfaces of TiO2 particles in a highly dispersed state with the loading amount maintained constant (0.46 +/- 0.02 mass %) using the deposition-precipitation method. Light irradiation (lambda(ex) > 300 nm) to a deaerated ethanol TiO2 particle suspension containing elemental sulfur (S8) led to the energetically uphill reduction of S8 to H2S. It has been found that this reaction is dramatically enhanced with such a low level of Au loading on TiO2 and that the zero-order rate constant of reaction increases with decreasing mean size of Au nanoparticles (d). The effects of reaction parameters (substrate concentration, light intensity, temperature) on the rate of reaction were studied to infer the essential reaction mechanism. Further, a kinetic analysis has led to a conclusion that the increase in the rate of reaction with decreasing d results from the improvement of the charge separation efficiency. 相似文献
46.
Tanatani A Yokoyama A Azumaya I Takakura Y Mitsui C Shiro M Uchiyama M Muranaka A Kobayashi N Yokozawa T 《Journal of the American Chemical Society》2005,127(23):8553-8561
Poly(p-benzamide)s 1 bearing a chiral side chain on the nitrogen atom were synthesized by chain-growth polycondensation methodology. The polyamides exhibited well-defined molecular weights with narrow polydispersities. Solutions of the polyamides in several organic solvents (CH(3)CN, CHCl(3), and CH(3)OH) showed dispersion type CD signals characteristic of coupled-oscillator and much larger as compared with the corresponding monomer. The CD signals were dependent on the temperature and molecular weight of the polyamides but independent of the solvent, as far as examined. An exciton model analysis of the absorption and CD spectra provided a clear-cut picture for the secondary structure of these polyamides in solution that the N-alkylated poly(p-benzamide)s possess a right-handed helical conformation ((P)-helix). In the solid states, the results of X-ray crystallographic analysis of 4-(methylamino)benzoic acid oligomers substantiated that they have a helical conformation with three monomer units per turn. 相似文献
47.
48.
1,3-Butadiene-2-carboxylates were treated with a titanium(II) alkoxide reagent, Ti(O-i-Pr)4/2i-PrMgCl, to generate diene-titanium alkoxide complexes, the presence of which was verified by hydrolysis and deuteriolysis to give the corresponding monoolefins or their bis-deuterated counterpart. These diene complexes underwent successive addition to an aldehyde (as the first electrophile) and iodine (as the second one) in a highly regio- and stereoselective manner to give the corresponding iodo alcohol. Optically active 1,3-butadiene-2-carboxylates afforded the same adducts of high asymmetric induction. Besides these electron-deficient dienes, electron-rich 2-siloxy-1,3-butadienes also participated in the formation of the titanium complex, which led to the preparation of functionalized enol silyl ethers through regio- and stereoselective coupling with carbonyl compounds and hydrolytic workup. 相似文献
49.
Kazuhiro Maruyama Tetsuo Otsuki Kiichiro Mitsui Masahiro Tojo 《Journal of heterocyclic chemistry》1980,17(4):695-700
Anthra[2,1-b]furan, anthra[2,1-b]benzo[d]furan, anthra[2,1-b]thiophene, anthra[1,2-b]thiophene, anthra[2,1-b]benzo[d]thiophene, anthra[2,1-b]pyrrole and naphtho[2,3-c]carbazole derivatives were synthesized in fairly good yields by a one-pot photocycloaddition reaction of 2,3-disubstituted 1,4-naphthoquinone with 1,1-diarylethylene. This is the first reported synthesis of these aromatic compounds. 相似文献
50.
Hiroshi Mitsui Fumio Hosoi Miyuki Hagiwara Tsutomu Kagiya 《Journal of polymer science. Part A, Polymer chemistry》1968,6(10):2881-2888
The effects of acetylene on the γ-radiation-induced polymerization of ethylene were studied from the viewpoint of the gaseous products and polymer structure. The experiments were carried out under a pressure of 400 kg/cm2; the temperature was 30°C; the does rate was 1.1 × 105 rad/hr; and the acetylene content was 0–20%. The solid polymer was obtained in the polymerization of ethylene containing 2.2% acetylene, while the monomer containing 19.7% acetylene gave a yellowish viscous oil. The polymer yield and molecular weight decreased remarkably with acetylene content. The main gaseous product was hydrogen, and trace amounts of butane, butene-1, butadiene-1,3, and benzene and its derivatives were also observed. The rate of formation of hydrogen was almost independent of acetylene content and there was no difference in acetylene contents before and after the irradiation was found. The infrared spectra of the polymers showed the presence of vinylidene, trans-vinylene, and terminal vinyl unsaturations, 1,4-disubstituted benzene, and carbonyl groups. The contents of trans-vinylene, terminal vinyl, and methyl groups increased with acetylene content, and that of vinylidene was independent of acetylene content. The monomer reactivity ratios of ethylene and acetylene were evaluated as 45.5 and 66.0, respectively. On the basis of the results, the effects of acetylene on the γ-radiation-induced polymerization of ethylene were discussed. 相似文献