首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2405篇
  免费   77篇
  国内免费   65篇
化学   1522篇
晶体学   18篇
力学   109篇
综合类   1篇
数学   326篇
物理学   571篇
  2023年   23篇
  2022年   43篇
  2021年   44篇
  2020年   28篇
  2019年   39篇
  2018年   18篇
  2017年   20篇
  2016年   47篇
  2015年   38篇
  2014年   84篇
  2013年   120篇
  2012年   171篇
  2011年   183篇
  2010年   115篇
  2009年   117篇
  2008年   119篇
  2007年   131篇
  2006年   134篇
  2005年   116篇
  2004年   99篇
  2003年   64篇
  2002年   71篇
  2001年   56篇
  2000年   42篇
  1999年   34篇
  1998年   33篇
  1997年   27篇
  1996年   19篇
  1995年   28篇
  1994年   30篇
  1993年   29篇
  1992年   26篇
  1991年   21篇
  1990年   25篇
  1989年   21篇
  1988年   17篇
  1987年   21篇
  1985年   31篇
  1984年   35篇
  1983年   22篇
  1982年   22篇
  1981年   21篇
  1980年   13篇
  1979年   12篇
  1978年   17篇
  1977年   16篇
  1976年   18篇
  1975年   17篇
  1974年   16篇
  1973年   11篇
排序方式: 共有2547条查询结果,搜索用时 82 毫秒
891.
The photophysical properties and the organic synthesis using effective palladium‐catalyzed Suzuki coupling reactions from a series of carbazole derivatives are described and the relationships of the donor and acceptor groups are also investigated. The purification of the materials and its applications along with the corresponding photo‐physical characterizations were presented. With the advantages gained from 2D‐COSY spectra, which provide more correlated information between immediate atoms than 1H‐NMR spectra and a series of further investigations were undertaken including powder X‐ray diffraction analysis, Infrared and Raman spectroscopy, constructing the composition conformation and chemical structure of the materials is more easily to achieve. Additionally, the optimized structure of the minimized energy geometries and spatial distributions of carbazole derivatives was calculated using density functional theory (DFT), new materials can be developed and designed selectively based on the method proposed in this work.  相似文献   
892.
In this article, we study mixed equilibrium problems, and present algorithms and convergence theorems for the proposed algorithms, like proximal gradient method, Tikhonov regularization method, Mann’s type method, conjugate gradient method. As application, we study minimization problems.  相似文献   
893.
Intraguild predation is added to a mathematical model of competition between two species for a single nutrient with internal storage in the unstirred chemostat. At first, we established the sharp a priori estimates for nonnegative solutions of the system, which assure that all of nonnegative solutions belong to a special cone. The selection of this special cone enables us to apply the topological fixed point theorems in cones to establish the existence of positive solutions. Secondly, existence for positive steady state solutions of intraguild prey and intraguild predator is established in terms of the principal eigenvalues of associated nonlinear eigenvalue problems by means of the degree theory in the special cone. It turns out that positive steady state solutions exist when the associated principal eigenvalues are both negative or both positive.  相似文献   
894.
本文借助于非标准组合论中的星型有限结构,定义了星型关联代数,从而建立了局部星型有限集上的M?bius反演.由此在一个超结构扩大中,在非标准意义下,将M?bius反演推广到局部标准无限半序集上.文中几例显示,在非标准领域里,本文结果为探索离散数学与连续数学的某些反演的统一性提供了一种可能途径.  相似文献   
895.
Four analogous compounds, cyclohexylmethyl 4-(4'-octoxybiphenyl-4-carbonyloxy)benzoate (2), cyclopentylmethyl 4-(4'-octoxybiphenyl-4-carbonyloxy)benzoate (3), cyclobutylmethyl 4-(4'-octoxylbiphenyl-4-carbonyloxy)benzoate (4) and cyclopropylmethyl 4-(4'-octoxylbiphenyl-4-carbonyloxy)benzoate (5) were prepared. They all exhibit SmA, SmC and SmX phases.  相似文献   
896.
Level-resolved lifetimes of the first excited state (Ã1A″) of hydrogen cyanide (HCN and DCN). obtained using the technique of vacuum ultraviole  相似文献   
897.
The structure and local environment of ZnO:CoFe were investigated. An epitaxial structure of ZnO thin film doped with CoFe on Al2O3 substrate was confirmed by XRD. By fitting the Zn EXAFS spectra, the bond distances and coordination numbers of Zn atoms in the ZnO:CoFe show that Co and Fe ions replace some positions of zinc atoms. The XANES study of Zn and O also show that CoFe cluster formation in this system can be excluded.  相似文献   
898.
899.
The Holly-Preissmann two-point finite difference scheme (HP method) has been popularly used for solving the advection equation. The key idea of this scheme is to solve the dependent variable (i.e. the concentration for the pollutant transport problem) by the method of characteristics with the use of cubic interpolation on the spatial axis. The interpolating polynomials of higher order are constructed by use of the dependent variable and its derivatives at two adjacent grid points. In this paper a new interpolating technique is introduced for incorporation with the Holly-Preissmann two-point method. The new method is denoted herein as the Holly-Preissmann reach-back method (HPRB) and allows the characteristics to project back several time steps beyond the present time level. Through stability analyses it has been observed that the increase of the reach-back time step numbers for the characteristics indeed reduces the numerical damping and dispersive phenomena. A schematic model has been constructed to demonstrate the merits of this new technique for the calculation of the pure advection and dispersion equations. Numerical experiments and comparisons with analytical solutions which support and demonstrate this new technique are presented.  相似文献   
900.
The Hamiltonian problem is to determine whether a graph contains a spanning (Hamiltonian) path or cycle. Here we study the Hamiltonian problem for the generalized Fibonacci cubes, which are a new family of graphs that have applications in interconnection topologies [J. Liuand W.-J. Hsu, ?Distributed Algorithms for Shortest-Path, Deadlock-Free Routing and Broadcasting in a Class of Interconnection Topologies,”? International Parallel Processing Symposium (1992)]. We show that each member of this family contains a Hamiltonian path. Furthermore, we also characterize the members of this family that contain a Hamiltonian cycle.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号