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21.
Guey‐Sheng Liou Sheng‐Huei Hsiao 《Journal of polymer science. Part A, Polymer chemistry》2002,40(15):2564-2574
A new N‐phenylated amide (N‐phenylamide) unit containing aromatic diamine, N,N′‐bis(3‐aminobenzoyl)‐N,N′‐diphenyl‐1,4‐phenylenediamine, was prepared by the condensation of N,N′‐diphenyl‐1,4‐phenylenediamine with 3‐nitrobenzoyl chloride, followed by catalytic reduction. Two series of organosoluble aromatic poly(N‐phenylamide‐imide)s and poly(N‐phenylamide‐amide)s with inherent viscosities of 0.58–0.82 and 0.56–1.21 dL/g were prepared by a conventional two‐stage method and the direct phosphorylation polycondensation, respectively, from the diamine with various aromatic dianhydrides and aromatic dicarboxylic acids. All polyimides and polyamides are amorphous and readily soluble in many organic solvents such as N,N‐dimethylacetamide and N‐methyl‐2‐pyrrolidone. These polymers could be solution cast into transparent, tough, and flexible films with high tensile strengths. These polyimides and polyamides had glass‐transition temperatures in the ranges of 230–258 and 196–229 °C, respectively. Decomposition temperatures of the polyimides for 10% weight loss all occurred above 500 °C in both nitrogen and air atmospheres. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2564–2574, 2002 相似文献
22.
Guey‐Sheng Liou Sheng‐Huei Hsiao 《Journal of polymer science. Part A, Polymer chemistry》2002,40(4):459-470
Two series of phosphorus‐containing aromatic poly(ester amide)s with inherent viscosities of 0.46–3.20 dL/g were prepared by low‐temperature solution polycondensation from 1,4‐bis(3‐aminobenzoyloxy)‐2‐(6‐oxido‐6H‐dibenz〈c,e〉〈1,2〉oxaphosphorin‐6‐yl)naphthalene and 1,4‐bis(4‐aminobenzoyloxy)‐2‐(6‐oxido‐6H‐dibenz〈c,e〉〈1,2〉oxaphosphorin‐6‐yl)naphthalene with various aromatic diacid chlorides. All the poly(ester amide)s were amorphous and readily soluble in many organic solvents, such as N,N‐dimethylformamide, N,N‐dimethylacetamide (DMAc), and N‐methyl‐2‐pyrrolidone (NMP). Transparent, tough, and flexible films of these polymers were cast from DMAc and NMP solutions. Their casting films had tensile strengths of 71–214 MPa, elongations to break of 5–10%, and initial moduli of 2.3–6.0 GPa. These poly(ester amide)s had glass‐transition temperatures of 209–239 °C (m‐series) and 222–267 °C (p‐series). The degradation temperatures at 10% weight loss in nitrogen for these polymers ranged from 462 to 489 °C, and the char yields at 800 °C were 55–63%. Most of the poly(ester amide)s also showed a high char yield of 35–45%, even at 800 °C under a flow of air. The limited oxygen indices of these poly(ester amide)s were 35–46. © 2002 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 40: 459–470, 2002; DOI 10.1002/pola.10129 相似文献
23.
Guey‐Sheng Liou Sheng‐Huei Hsiao 《Journal of polymer science. Part A, Polymer chemistry》2002,40(11):1781-1789
A series of new aromatic polyamides having pendent naphthoxy groups were synthesized by the triphenyl phosphite‐activated polycondensation of (2‐naphthoxy)terephthalic acid (NOTPA) with various aromatic diamines in a medium consisting of N‐methyl‐2‐pyrrolidone (NMP), pyridine, and calcium chloride. The diacid monomer NOTPA was prepared from the nitro displacement of dimethyl 2‐nitroterephthalate with the potassium naphthoxide of β‐naphthol, followed by base‐induced ester hydrolysis. All the resulting polymers were noncrystalline and readily soluble in aprotic polar solvents such as NMP and N,N‐dimethylacetamide. Almost all the polymers could be solution‐cast to tough, creasable amorphous films with good mechanical properties, the values of tensile strengths ranging from 90 to 124 MPa with initial moduli ranging from 1.72 to 2.51 GPa. Except for two examples, all the other polyamides displayed discernible glass transitions between 189 and 248 °C in the differential scanning calorimetric traces. These polyamides showed insignificant decomposition below 400 °C in nitrogen or air. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1781–1789, 2002 相似文献
24.
The spin states of iron (II) in FeL2(NCS)2 produced from the thermal decomposition of FeL8(NCS)2 (L=2-py-CR1=NR2, R1 or R2=H, Me(CH3), Ph) under nitrogen atmosphere are investigated by means of Mössbauer spectroscopy and magnetic measurements. It was found that the spin states of iron (II) in substitutited bis (2-pyridylimine) iron (II) thiocyanate are included: intermediate-spin (3T1, S=1), mixed-spin of 5T2(S=2)+3T1 and spin incomplete transition of 5T2?3T1. 相似文献
25.
A simple, rapid, and eco-friendly analytical method for simultaneous determination of uric acid and creatinine in urine applying high performance liquid chromatography (HPLC) is described. After dilution, de-protein, and filtration, the sample solution was injected to separate the species with C-18 column by an eluent containing 0.05 M ammonium phosphate buffer at pH 7.4. An UV detector was used to monitor the separation of species at 235 nm. Optimum conditions for separation and detection were investigated. Results indicated that under optimized condition measurements were achieved within 13 min. The detection limits were 0.127 and 0.156 mug ml(-1) for uric acid and creatinine respectively. The recovery was 95% (0.57% RSD) for uric acid and 99.2% (0.98% RSD) for creatinine, from five measurements. Real urine specimens were tested. 相似文献
26.
Synthesis and properties of novel poly(amide-imide)s containing pendent diphenylamino groups 总被引:1,自引:0,他引:1
A new dicarboxylic acid, 2,4-bis(N-trimellitoyl)triphenylamine, bearing two preformed imide rings was synthesized from the condensation of 2,4-diaminotriphenylamine and trimellitic anhydride at 1:2 molar ratio. A series of poly(amide-imide)s (PAIs) with inherent viscosities of 0.38-0.66 dl/g were prepared by triphenyl phosphite-activated polycondensation from the diimide-dicarboxylic acid with various aromatic diamines. All the resulting PAIs were readily soluble in a variety of organic solvents and formed strong and tough films via solution casting. These PAIs have useful levels of thermal stability associated with moderately high glass-transition temperatures (259-314 °C) and 10% weight loss temperatures in excess of 530 °C in nitrogen or in air. 相似文献
27.
Temperature dependent behavior of the responsivity of InAs/GaAs quantum dot infrared photodetectors was investigated with detailed measurement of the current gain. The current gain varied about two orders of magnitude with 100 K temperature change. Meanwhile, the change in quantum efficiency is within a factor of 10. The dramatic change of the current gain is explained by the repulsive coulomb potential of the extra carriers in the QDs. With the measured current gain, the extra carrier number in QDs was calculated. More than one electron per QD could be captured as the dark current increases at 150 K. The extra electrons in the QDs elevated the Fermi level and changed the quantum efficiency of the QDIPs. The temperature dependence of the responsivity was qualitatively explained with the extra electrons. 相似文献
28.
Wen-Tsung Ho Jason Chao-Hsien Pan Yu-Cheng Hsiao 《Journal of Optimization Theory and Applications》2012,153(2):513-531
This paper studies the multi-stage logistics and inventory problem in an?assembly-type supply chain where a uniform lot size is produced uninterruptedly with a single setup at each stage. Partial lots, or sub-batches, can be transported to next stage upon completion. Unequal sub-batch sizes at each stage follow geometric series and the numbers of sub-batches across stages are allowed to be different. Since the mainline and each branch line of an assembly-type supply chain are series-type supply chains, a model of the series-type supply chain is first established and a model of the assembly-type supply chain is subsequently developed. Optimization algorithms that determine the economic lot sizes, the optimal sub-batch sizes and the number of sub-batches for each stage are developed. The polynomial-time algorithms incorporate the optimality properties derived in the paper to find the lower and upper bounds of the solutions by constructing the solution ranges and then the optimal solutions accordingly. 相似文献
29.
In this paper we show that the quasi-symmetric coupling of finite and boundary elements of Bielak and MacCamy can be freed
of two very restricting hypotheses that appeared in the original paper: the coupling boundary can be taken polygonal/polyhedral
and coupling can be done using the normal stress instead of the pseudostress. We will do this by first considering a model
problem associated to the Yukawa equation, where we prove how compactness arguments can be avoided to show stability of Galerkin
discretizations of a coupled system in the style of Bielak–MacCamy’s. We also show how discretization properties are robust
in the continuation parameter that appears in the formulation. This analysis is carried out using a new and very simplified
proof of the ellipticity of the Johnson–Nédélec BEM–FEM coupling operator. Finally, we show how to apply the techniques that
we have fully developed in the model problem to the linear elasticity system. 相似文献
30.