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691.
A quadratic spinor Lagrangian for general relativity 总被引:1,自引:0,他引:1
We present a newfinite action for Einstein gravity in which the Lagrangian is quadratic in the covariant derivative of a spinor field. Via a new spinor-curvature identity, it is related to the standard Einstein-Hilbert Lagrangian by a total differential term. The corresponding Hamiltonian, like the one associated with the Witten positive energy proof, is fully 4-covariant. It defines quasi-local energy-momentum and can be reduced to the one in our recent positive energy proof.This essay received the fourth award from the Gravity Research Foundation, 1994—Ed. 相似文献
692.
A statistical model for the calculation of inelastic mean free paths and energy losses of electrons in solids is described. Results for the application of the model to the six solid media Al, Au, Ag, Cu, Ni, and Si are presented. Agreement between calculated mean free paths and experimental attenuation lengths indicates that the statistical model provides a useful method in the little-studied electron energy range from a few tens of electron volts to 10 keV. 相似文献
693.
Lue Zu-Fong Tung Yuen-Yu Chao Rhan-Mei Ou Qing-Yu Yang Pei-Yi Dong Kun-Nian Yu Wei-Lu 《Journal of separation science》1979,2(7):429-435
A technique for adhesion of fine particles (ca. 5 μ) of the 405 white diatomaceous support on the inner wall of glass tube with organic glue [poly (diethylaminoethyl methacrylate) acetate] is described. The coated tube was drawn to capillary column by using a machine designed according to Desty's. The capillary column was then coated with stationary phase (such as squaiane, QF-1, Dexsil 300, PEG 20 M, OV-1, SE 30 and etc.) by the conventional dynamic or static method. This preparation method has proved easy to duplicate and is simple. The coating efficiency (UTE %) is within 60–90. The theoretical plate number per meter of an SE 30 column is about 4000, and per meter of a PEG 20 M column is about 2500. The columns thus prepared have been successfully used to analyze petroleum hydrocarbons, essential oils, petrochemicals, pheromone, steroid metabolites and others. 相似文献
694.
Wang YH Zhang HM Liu L Liang ZX Guo QX Tung CH Inoue Y Liu YC 《The Journal of organic chemistry》2002,67(8):2429-2434
Photoinduced electron transfer was observed in the supramolecular complexes of p-nitrobenzoyl-beta-cyclodextrin (NBCD) with a number of naphthalene derivatives, which were stabilized clearly via hydrophobic interactions in aqueous solution. Both steady-state and time-resolved fluorescence measurements were conducted, which revealed that there were two routes of electron transfer, i.e., electron transfer between the free donor and free acceptor in solution and electron transfer between the donor and acceptor bound in a supramolecular assembly. The evidence collected demonstrates that the latter route was very efficient. As a result, the rate and quantum yield of the fluorescence quenching in the present supramolecular system were appreciably large. 相似文献
695.
Wu FI Shih PI Tseng YH Chen GY Chien CH Shu CF Tung YL Chi Y Jen AK 《The journal of physical chemistry. B》2005,109(29):14000-14005
We have systematically examined the photoluminescence (PL) and electroluminescence (EL) behavior of blends comprising two efficient red phosphors doped, respectively, into the blue-emitting polyfluorene derivatives PF-TPA-OXD and PF-OXD. The host polymers, which contain both hole- and electron-transporting or merely electron-transporting side chains, are capable of facilitating charge injection and transport. After determining the HOMO and LUMO energy levels of these materials, we were able to match the dopant with its most suitable host to achieve the direct formation and confinement of an exciton at the dopant. This configuration also leads to a reduction in the electrical excitation of the host polymer, which in turn decreases the degree of exciton loss arising from nonradiative decay of the host triplet. Using this approach, we were able to realize the production of high-performance red-electrophosphorescent devices. For Os(fppz)-doped devices, we obtain a balanced charge recombination in conjunction with higher current and luminance when using PF-TPA-OXD as the host matrix; this device reached a maximum external quantum efficiency of 8.37% with a peak brightness of 16 720 cd/m2. The absence of charge-transporting pendant units, i.e., the device fabricated from poly[9,9-dioctylfluorene-2,7-diyl] (POF), led, however, to relatively poor electroluminescence characteristics (5.81% and 2144 cd/m2). 相似文献
696.
697.
Tung JW 《Annali di chimica》2004,94(11):837-846
A rapid energy-dispersive X-ray fluorescence (ED-XRF) spectrometric method for the analysis of metal components of marine sediments has been presented. Calibrations were made using synthetic matrix. The agreement of the results for sediment standard reference materials with reference values is satisfactory. Major advantages of the non-destructive ED-XRF technique over conventional chemical digestion methods include the applicability to analyzing the major oxide components, as well as to trace metals, and the avoidance of hazardous chemicals. The method has been applied to the routine analysis of Hong Kong marine sediment. 相似文献
698.
O. V. Kovalchukova K. K. Palkina Tran Thanh Tung S. B. Strashnova B. E. Zaitsev N. V. Polyakova A. N. Levov 《Russian Journal of Inorganic Chemistry》2007,52(5):733-741
Complexes of copper(II) halides (chlorides and bromides) with some 4-azafluorene derivatives have been synthesized and studied by X-ray crystallography and IR and UV spectroscopy. In neutral media, Cu(L)2X2 (X = Cl, Br) complexes are formed in which the ligands are coordinated to the metal atoms though the lone pair of the endocyclic nitrogen atom and through the oxygen atoms of substituents. In acid media at pH 2, (HL2)2CuX4 complexes are formed in which the 4-azafluorene molecules protonated at the endocyclic nitrogen atom act as an outer-sphere cation. The molecule and crystal structure of 4-aza-9-oxofluorenium tetrabromocuprate hydrate (HL4)2CuBr4·H2O has been determined. 相似文献
699.
ChungShinLU ChiingChangCHEN YaPingSU KungTungCHEN 《中国化学快报》2005,16(5):701-704
Safranine, a cationic dye, was removed from synthetic wastewater by ion flotation. Over 98% of safranine was removed from the solution in 10 min. A stoichiometric amount of surfactant (1 mol of surfactant to 1 mol of dye) was found to be most effective for safranine removal. The separation efficiency of safranine decreased with increasing concentration of NaNO3. Safranine was also removed by adsorbing colloid flotation technique using Fe(OH)3 as the coagulant. Sodium lauryl sulfate was used as the collector, and over 97% of safranine was removed in 5 min. The separation efficiency decreased with increasing ionic strength of the solution. The deleterious effect of neutral salt was compensated somewhat with the aid of Al^3 as the activator. Both ion flotation and adsorbing colloid flotation may be applicable in the removal of safranine from wastewater. 相似文献
700.