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71.
Choudhury A Neeraj S Natarajan S Rao CN 《Angewandte Chemie (International ed. in English)》2000,39(17):3091-3093
72.
The structure of the aminoacid, Ls-threonine [NH 3 + CH(CHOHCH3)COO?], space groupP212121,a=13.630(5),b=7.753(1),c=5.162(2) Å,z=4, has been determined from neutron diffraction data using direct methods. The intensities of 1148 neutron Bragg reflections were measured from a single crystal. The structural parameters were refined by the method of least squares using anisotropic temperature factors. The finalR(F 2) is 0.068. The structure was also refined from the x-ray data of Shoemakeret al (1950J. Am. Chem. Soc. 72 2328); there is good agreement between the two sets of heavy atom parameters. The parameters of hydrogen atoms are of course more precisely determined in our neutron study. The molecular conformation and the hydrogen bonding scheme are discussed. Weighted average values of bond distances and angles from 14 aminoacid structures with ionized carboxylic groups studied by neutron diffraction at Brookheven and Trombay are also presented. 相似文献
73.
Contrary to the general assumption that photoreactions in crystals may not proceed with large molecular motions, a pedal-like motion prompted by electronic excitation is believed to be involved during the beta-dimer formation from the crystals of the diamine double salt of trans-2,4-dichlorocinnamic acid and trans-1,2-diaminocyclohexane. 相似文献
74.
In Knowledge Discovery in Databases (KDD)/Data Mining literature, interestingness measures are used to rank rules according to the interest a particular rule is expected to evoke. In this paper, we introduce an aspect of subjective interestingness called item-relatedness. Relatedness is a consequence of relationships that exist between items in a domain. Association rules containing unrelated or weakly related items are interesting since the co-occurrence of such items is unexpected. Item-Relatedness helps in ranking association rules on the basis of one kind of subjective unexpectedness. We identify three types of item-relatedness – captured in the structure of a fuzzy taxonomy (an extension of the classical concept hierarchy tree). An item-relatedness measure for describing relatedness between two items is developed by combining these three types. Efficacy of this measure is illustrated with the help of a sample taxonomy. We discuss three mechanisms for extending this measure from a two-item set to an association rule consisting of a set of more than two items. These mechanisms utilize the relatedness of item-pairs and other aspects of an association rule, namely its structure, distribution of items and item-pairs. We compare our approach with another method from recent literature. 相似文献
75.
We demonstrate a new technique for saturated-absorption spectroscopy by use of copropagating beams that does not have the problem of crossover resonances. The pump beam is locked to a transition, and its absorption signal is monitored while the probe beam is scanned. As the probe comes into resonance with another transition, the pump absorption is reduced and the signal shows a Doppler-free dip. We use this technique to measure hyperfine intervals in the D2 line of 85Rb with a precision of 70 kHz and to resolve hyperfine levels in the D2 line of 39K that are less than 10 MHz apart. 相似文献
76.
B. Natarajan 《Journal of Physics and Chemistry of Solids》2007,68(10):1995-2002
EPR spectroscopic investigations on single crystals of diaquabis[malonato(1-)-κ2O,O′] zinc(II) doped with VO(II) ion have been carried out at X-band frequencies and at 300 K. The single crystal, rotated along the three mutually orthogonally axes, has yielded spin-Hamiltonian parameters g and A as: gxx=1.980, gyy=1.972, gzz=1.937 and Axx=8.4, Ayy=6.1, Azz=18.1 mT, respectively. These spin-Hamiltonian parameters reflect a slight deviation from axial symmetry to rhombic, which is elucidated by the interstitial occupation of vanadyl ions. The isofrequency plots and powder EPR spectrum have been simulated. The percentage of metal-oxygen bond has been estimated. The optical absorption spectrum exhibits four bands at 257, 592, 720 and 764 nm suggesting a C4v symmetry. The admixture coefficients and bonding parameters have also been calculated by collaborating EPR data with optical data. 相似文献
77.
X-ray diffraction experiments onp-dichlorobenzene at high pressures show a transition at ~ 0.3 GPa, to a new phase, the diffraction pattern of which cannot be indexed on the anticipated low temperature monoclinic crystal structure. We have instead found an orthorhombic cell, very closely related to the low temperature monoclinic cell, for this new phase. This structure, which also occurs inp-diiodobenzene at ambient conditions, has cell constantsa =14.02,b = 6.06,c = 7.41Å andZ = 4. The space group is Pbca. This new phase has a non-β herring-bone structure, in contrast with the initialα phase which has aβ-structure with ribbon-like arrangement of molecules, with Cl-Cl contacts of ~ 4A between adjacent molecules. This implies that with pressure the halogen-halogen interaction in this compound plays a less dominant role in crystal engineering. 相似文献
78.
R Srinivasan V Sankaranarayanan N P Raju S Natarajan U V Varadaraju G V Subba Rao 《Pramana》1987,29(2):L225-L230
The absolute thermopower of single phase YBa2Cu3O7 and Y0.8Er0.2Ba2Cu3O7 has been measured in the range 250 K to the superconducting transition temperature. It is found that these compounds show
a large enhancement of thermopower in the range 150 K down toT
c. This enhancement shows a steep exponential drop as the temperature increases from the transition temperature. The temperature
variation of the enhancement is too steep to be accounted for by electron-phonon or electron-local structural excitation mechanisms. 相似文献
79.
Natarajan Senthil Kumar 《Tetrahedron》2009,65(4):822-830
Synthesis of mixed heterocyclic system containing benzo[c]thiophene, dibenzo-heterocycles, and thiophene unit is described. 相似文献
80.
Raj?Karthik Natarajan?Karikalan Shen-Ming?ChenEmail author Periyasami?Gnanaprakasam Chelladurai?Karuppiah 《Mikrochimica acta》2017,184(2):507-514
The authors describe an electrochemical method for the determination of the anti-cancer drug nilutamide. The method is based on the use of a composite prepared from β-cyclodextrin, gold nanoparticles and graphene oxide (β-CD-AuNP/GO). An alkaline solution of glucose was used as a reducing agent to reduce the gold ions, rather than citric acid and a harmful reducing agent such as hydrazine and sodium borohydride. The structure and surface morphology of the β-CD-AuNP/GO composite was characterized by Raman spectroscopy, transmission electron microscopy and energy-dispersive X-ray spectroscopy. A screen printed carbon electrode was modified with the nanocomposite, and the resulting electrode used as a disposable sensor for the determination of nilutamide by differential pulse voltammetry. Best operated at a working voltage of 0.43 V (vs Ag/AgCl), it exhibits excellent electrocatalytic activity and a detection limit as low as 0.4 nM. The sensor was applied to the determination of nilutamide in (spiked) human serum, as well as in a tablet, where it displays good recovery and accuracy. The sensor is repeatable, reproducible, stable and selective even in the presence of other aromatic nitro compounds. 相似文献