An unusual case of acute disseminated encephalomyelitis confined to brainstem

Acute disseminated encephalomyelitis (ADEM) is an immune-mediated demyelinating disorder usually encountered in children or adolescents and characterized by multifocal neurological deficits of rapid onset. Typical target areas of demyelination include the corona radiata, centrum semiovale, periventricular white matter, cerebellar peduncles and brainstem. Involvement of deep gray matter nuclei is also frequent. We report a 6-year-old boy with ADEM who had only brainstem involvement. Serial magnetic resonance images representing the stage of disease and response to steroid treatment are presented.     

A Class of Orthogonal Polynomials Suggested by a Trigonometric Hamiltonian: Symmetric States

A new subclass of the Jacobi polynomials arising in the exact analytical solution of the one-dimensional Schrödinger equation with a trigonometric potential has been introduced. The polynomials which consist of a free parameter are not ultraspherical polynomials and have been simply named the -polynomials since they are generated by a trigonometric Hamiltonian. In certain sense, it is shown that the -polynomials can be regarded as a generalisation of the airfoil polynomials or the Chebyshev polynomials of the third kind. This paper is intended to discuss the basic properties of the polynomials so defined.     

Numerical analysis of buoyant flow in a hemispherical enclosure at high Rayleigh numbers

A numerical analysis is presented for buoyancy driven flow of a Newtonian fluid contained in a two dimensional (R, ) hemispherical enclosure for high Rayleigh (Ra) numbers. It is assumed that the flow is driven by the uniformly distributed internal heat sources within the enclosure. All walls of the cavity are maintained at a constant temperature. Finite volume based SIMPLER algorithm has been used for the present analysis. Discretised governing equations, in primitive variables, are solved by a combination of Three Diagonal Matrix Algorithm (TDMA) and Point Successive Overrelaxation (PSOR) method. A benchmark solution prepared for a Ra number range of 10⁷ to 10¹² and Prandtl (Pr) number 7.0, shows an excellent agreement with the experimental results obtained from the open literature.     

Gomory integer programs

 The set of all group relaxations of an integer program contains certain special members called Gomory relaxations. A family of integer programs with a fixed coefficient matrix and cost vector but varying right hand sides is a Gomory family if every program in the family can be solved by one of its Gomory relaxations. In this paper, we characterize Gomory families. Every TDI system gives a Gomory family, and we construct Gomory families from matrices whose columns form a Hilbert basis for the cone they generate. The existence of Gomory families is related to the Hilbert covering problems that arose from the conjectures of Seb?. Connections to commutative algebra are outlined at the end. Received: May 17, 2001 / Accepted: February 7, 2002 Published online: April 24, 2003 RID="⋆" ID="⋆" Research partially supported by NSF grant DMS-0100141.     

Geometric Dynamics

A kinematic differential system on a Riemann (or semi-Riemann) manifold induces a Lorentz-Udrite world-force law, i.e., any local group with one parameter (any local flow) on a Riemann (or semi-Riemann) manifold induces the dynamics of the given vector field or of an associated particle, which will be called geometric dynamics.The cases of Riemann-Jacobi or Riemann-Jacobi-Lagrange structures are imposed by the behavior of an external tensor field of type (1,1). The case of the Finsler-Jacobi structure appears if the initial metric is chosen such that the energy of the given vector field is constant (Sec. 1). At the end of Sec. 1 are formulated open problems regarding some extensions of geometric dynamics.Adequate structures on the tangent bundle describe the geometric dynamics in the Hamilton language (Sec. 2).Section 3 proves the existence of a Finsler-Jacobi structure induced by an almost contact metric structure.The theory is applied to electromagnetic dynamical systems (the starting point of our theory), offering new principles of unification of the gravitation and the electromagnetism. Also, here, one enounces open problems regarding the geometric dynamics induced by the electric intensity and magnetizing force (Sec. 4).From the geometrical point of view, we create a wider class of Riemann-Jacobi, Riemann-Jacobi-Lagrange, or Finsler-Jacobi manifolds ensuring that all trajectories of a given vector field are geodesics. Having T₁M²ⁿ⁺¹ in mind, the problem of creating a wider class of Riemannian manifolds, in which there exists a vector field such that (1) all trajectories of the vector field are geodesics; (2) the flow defined by is incompressible; (3) the condition which corresponds to the property that is the associate vector field of the contact structure is satisfied;was studied intensively by S. Sasaki. The results were not satisfactory, but Sasaki discovered (, , )-structures [10].AMS Subject Classification (1991): 70H35, 53C22, 58F25, 83C22     

On the mechanism of the N,N‐dimethyl amination of Grignard reagents: a kinetic study

A direct kinetic study is reported for the electrophilic amination of substituted phenylmagnesium bromides with N,N‐dimethyl O‐(mesitylenesulfonyl)hydroxylamine in THF. Rate data, Hammett relationship, and activation entropy are consistent with a S_N2 displacement involving the attack of carbanions to sp³N in the amination reagent (AR). Copyright © 2007 John Wiley & Sons, Ltd.     

Global existence and decay of solutions for the generalized bad Boussinesq equation

In this paper,we consider the global existence of solutions for the Cauchy problem of the generalized sixth order bad Boussinesq equation.Moreover,we show that the supremum norm of the solution decays algebraically to zero as(1+t)(1/7)when t approaches to infnity,provided the initial data are sufciently small and regular.     

Effective metastability of Halpern iterates in CAT(0) spaces

This paper provides an effective uniform rate of metastability (in the sense of Tao) on the strong convergence of Halpern iterations of nonexpansive mappings in CAT(0) spaces. The extraction of this rate from an ineffective proof due to Saejung is an instance of the general proof mining program which uses tools from mathematical logic to uncover hidden computational content from proofs. This methodology is applied here for the first time to a proof that uses Banach limits and hence makes a substantial reference to the axiom of choice.     

Chiral lariat ethers as membrane carriers for chiral amino acids and their sodium and potassium salts

Four chiral lariat ethers 8–11 containing a (p-methoxyphenoxy) methyl side arm were used for chiral discrimination of amino acids in their zwitterionic form or as potassium and sodium salts in transport across a bulk chloroform membrane with satisfactory selectivity. The carriers that were employed exhibited different transport selectivity relative to the amino acids and their salts under study. The d/l selectivity strongly depends on the amino acids or their salts, and in some cases reverse selectivity has been obtained. The best selectivity was obtained in the case of tyrosine and its potassium salts for all carriers. The transport rates of amino acids and their salts were found to be controlled by factors such as the structure of the carriers and amino acids or their salts. Among these factors, it was also found that the side arm of the lariat ethers plays an important role in the transport process. As a consequence, the main goal of our investigation was to separate the chiral amino acids through liquid membranes.