全文获取类型
收费全文 | 6813篇 |
免费 | 977篇 |
国内免费 | 553篇 |
专业分类
化学 | 4787篇 |
晶体学 | 32篇 |
力学 | 365篇 |
综合类 | 16篇 |
数学 | 789篇 |
物理学 | 2354篇 |
出版年
2024年 | 22篇 |
2023年 | 151篇 |
2022年 | 214篇 |
2021年 | 283篇 |
2020年 | 281篇 |
2019年 | 239篇 |
2018年 | 219篇 |
2017年 | 177篇 |
2016年 | 290篇 |
2015年 | 280篇 |
2014年 | 371篇 |
2013年 | 455篇 |
2012年 | 603篇 |
2011年 | 619篇 |
2010年 | 412篇 |
2009年 | 348篇 |
2008年 | 423篇 |
2007年 | 373篇 |
2006年 | 348篇 |
2005年 | 265篇 |
2004年 | 201篇 |
2003年 | 158篇 |
2002年 | 129篇 |
2001年 | 131篇 |
2000年 | 124篇 |
1999年 | 136篇 |
1998年 | 107篇 |
1997年 | 93篇 |
1996年 | 122篇 |
1995年 | 103篇 |
1994年 | 70篇 |
1993年 | 63篇 |
1992年 | 69篇 |
1991年 | 57篇 |
1990年 | 74篇 |
1989年 | 53篇 |
1988年 | 34篇 |
1987年 | 29篇 |
1986年 | 24篇 |
1985年 | 18篇 |
1984年 | 16篇 |
1983年 | 16篇 |
1982年 | 15篇 |
1981年 | 10篇 |
1979年 | 20篇 |
1978年 | 15篇 |
1977年 | 14篇 |
1976年 | 10篇 |
1975年 | 13篇 |
1973年 | 13篇 |
排序方式: 共有8343条查询结果,搜索用时 15 毫秒
21.
22.
Aromatization of methane over different Mo-supported catalysts in the absence of oxygen 总被引:2,自引:0,他引:2
Tan Pinglian Xu Zhusheng Zhang Tao Chen Liayuan Lin Liwu 《Reaction Kinetics and Catalysis Letters》1997,61(2):391-396
Both acidity and structure of the support are important factors in converting methane to aromatics. Lower SiO2/Al2O3 ratio seems to favor the aromatization of methane over the Mo/HZSM-5 catalyst. When Pt is added as a modifier the activity
of Mo/HZSM-5 catalyst will decrease slightly, but coke formation will enhanced. 相似文献
23.
Qingde Zhang Yisheng Tan Caihong Yang Yizhuo Han Jun Shamoto Noritatsu Tsubaki 《天然气化学杂志》2007,16(3):322-325
The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40(40%)/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40(40%)/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40(40%)/SiO2. 相似文献
24.
James Elver Johnson Joanne A. Maia Karen Tan Abdolkarim Ghafouripour Patrice De Meester Shirley S. C. Chu 《Journal of heterocyclic chemistry》1986,23(6):1861-1868
O-Methyl-α-ketophenylacetohydroximoyl chloride ( 1 ) was prepared by the reaction of O-methyl-α-methoxyphenylacetohydroximoyl chloride ( 5 ) with N-bromosuccinimide and concentrated hydrobromic acid. Reaction of 1 with ethylenediamine gave 3-phenyl-5,6-dihydro-2(1H)-pyrazinone-O-methyloxime ( 6 ). 3-Phenyl-5,6-cyclohexano-5,6-dihydro-2(1H)-pyrazininone-O-methyloxime ( 7 ) was prepared by reaction of 1 with trans-1,2-diaminocyclohexane. The X-ray structure of 6 has been determined. The crystals are orthorhombic, space group Pbca with a = 10.264(3), b = 18.262(4), c = 23.530(4)Å, V = 4411(2)Å3, and Z = 16. The structure, which was refined to R = 0.038 using 1652 observed reflections, shows the amidoxime moiety to be the Z configuration. Reaction of benzohydroximoyl chloride with aziridine gave (Z)-aziridinylbenzaldoxime ( 16a ). Ultraviolet irradiation of a benzene solution of 16a gave a mixture of the Z and E isomers 16a and 16b . The E isomer 16b underwent thermal isomerization to 16a at 100°. Reaction of 16a with dimethyl sulfate in sodium hydroxide solution gave (Z)-O-methylaziridinylbenzaldoxime ( 17a ). Photoisomerization of a hexane solution of 17a gave a mixture of the Z and E isomers 17a and 17b which were separated by preparative glc. The isomers 17a and 17b are resistant to thermal Z = E isomerization. The mechanisms of thermal isomerization of benzamidoximes are discussed. 相似文献
25.
26.
Changlun Chen Di Xu Xiaoli Tan Xiangke Wang 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(1):227-233
The fate and transport of toxic metal ions and radionuclides in the environment is generally controlled by sorption reactions.
The extent of sorption of divalent metal cations is controlled by a number of factors including cosorbing or complexing. In
this work, the effects of pH, humic acid HA/Co(II) addition orders, ionic strength, concentration of HA, and foreign cations
on the Co(II) sorption on γ-Al2O3 in the presence of HA were investigated. The sorption isotherms of Co(II) on γ-Al2O3 in the absence and presence HA were also studied and described by using S-type sorption model. The experimental results showed
that the Co(II) sorption is strongly dependent on the pH values, concentration of HA, but independent of HA/Co(II) addition
orders, ionic strength, and foreign cations in the presence of HA under our experimental conditions. The results also indicated
that HA enhanced the Co(II) sorption at low pH, but reduced the Co(II) sorption at high pH. It was hypothesized that the significantly
positive influence of HA at low pH on the Co(II) sorption on γ-Al2O3 was attributed to strong surface binding of HA on γ-Al2O3 and subsequently the formation of ternary surface complexes such as ≡S-OOC-R-(COO−)
x
Co2−x
. Chemi-complexation may be the main mechanism of the Co(II) sorption on γ-Al2O3 in the presence of HA. 相似文献
27.
PhenNO—TTA—乳化剂OP荧光光度法测定微量铕 总被引:3,自引:0,他引:3
研究了Eu(Ⅲ)-PhenNO-TTA-乳化剂OP体系的荧光性质及其用于微量铕的测定。该体系具有良好的分析特性,最低检测限可达7.0×10^-14mol/L. 相似文献
28.
29.
30.