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41.
42.
Gisèle Cory-Goulard 《Czechoslovak Journal of Physics》1986,36(8):971-975
Experimental measurements and theoretical calculations are discussed for theA = 3 nuclei. With the sum rule formalism, the need for a better bound state is investigated. Some reactions on3He and3H like electron scattering, photodisintegration,-capture involve transitions to the continuum but with the work developed by Merkuriev, Gignoux and Laverne (1976) some progress is possible. The same realisticNN interactions used for calculating the bound state wave function of the three nucleon system are incorporated in the scattering equations based on the Faddeev approach.Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985. 相似文献
43.
Roubin P Chandesris D Rossi G Lecante J Desjonquères MC Tréglia G 《Physical review letters》1986,56(12):1272-1275
44.
LetG be a graph andr a cardinal number. Extending the theorem of J. Folkman we show that if eitherr or clG are finite then there existsH with clH = clG andH (G)
r
1
. Answering a question of A. Hajnal we show that countably universal graphU
3 satisfiesU
3 (U3)
r
1
for every finiter. 相似文献
45.
Pradier CM Rubio C Poleunis C Bertrand P Marcus P Compère C 《The journal of physical chemistry. B》2005,109(19):9540-9549
Adhesion of bacterial strains on solid substrates is likely related to the properties of the outer shell of the micro-organisms. Aiming at a better understanding and control of the biofilm formation in seawater, the surface chemical composition of three marine bacterial strains was investigated by combining Fourier transform IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary-ion mass spectrometry (ToF-SIMS). The D41 strain surface showed evidence of proteins, as deduced from the NH2 and NCO XPS and ToF-SIMS fingerprints; this strain was found to adhere to stainless steel, glass, or Teflon surfaces in a much higher quantity (2 orders of magnitude) than the two other ones, DA and D01. The latter are either enriched in COOH or sulfates, and this makes them more hydrophilic and less adherent to all substrates. Correlations with physicochemical properties and adhesion seem to demonstrate the role of the external layer composition, in particular the role of proteins more than that of hydrophobicity, on their adhesion abilities. 相似文献
46.
Pegaz B Debefve E Borle F Ballini JP Wagnières G Spaniol S Albrecht V Scheglmann D Nifantiev NE van den Bergh H Konan YN 《Photochemistry and photobiology》2005,81(6):1505-1510
In the present study, photodynamic activity of a novel photosensitizer (PS), Chlorin e(6)-2.5 N-methyl-d-glucamine (BLC 1010), was evaluated using the chorioallantoic membrane (CAM) as an in vivo model. After intravenous (i.v.) injection of BLC 1010 into the CAM vasculature, the applicability of this drug for photodynamic therapy (PDT) was assessed in terms of fluorescence pharmacokinetics, i.e. leakage from the CAM vessels, and photothrombic activity. The influence of different PDT parameters including drug and light doses on the photodynamic activity of BLC 1010 has been investigated. It was found that, irrespective of drug dose, an identical continuous decrease in fluorescence contrast between the drug inside and outside the blood vessels was observed. The optimal treatment conditions leading to desired vascular damage were obtained by varying drug and light doses. Indeed, observable damage was achieved when irradiation was performed at light doses up to 5 J/cm(2) 1 min after i.v. injection of drug doses up to 0.5 mg/kg body weight(b.w.). However, when irradiation with light doses of more than 10 J/cm(2) was performed 1 min after injection of drug doses up to 2 mg/kg body weight, this led to occlusion of large blood vessels. It has been demonstrated that it is possible to obtain the desired vascular occlusion and stasis with BLC 1010 for different combinations of drug and/or light doses. 相似文献
47.
The molecular energy of the complex (η5-C5H5)2TiCl2 has been calculated for experimental geometry and for several hypothetical forms by a semi-empirical CNDO/2 approach. The energy difference between experimental (quasi-tetrahedral) geometry and a planar geometry is ca. 20 kcal mol?1. This difference is sufficiently high to explain the difficulty of the inversion process. 相似文献
48.
Aubailly M Haigle J Giordani A Morlière P Santus R 《Journal of photochemistry and photobiology. B, Biology》2000,56(1):61-67
The 365-nm irradiation of 4.6 microM (approximately equal to 1.1 mg/ml) catalase solutions in pH 7.4 phosphate buffer induces spectral modifications. Difference spectra show maxima at 434, 555, 584 nm at the beginning of the irradiation, then a final spectrum with a maximum at 568 nm and a shoulder at 530 nm is observed. These results suggest the formation of compound III (oxyferrous catalase) and compound II, respectively. In deaerated 0.1 M, pH 8.7 borate buffer, the ferrous catalase is characterized by maxima at 563 and 594 nm. Hydrogen donors such as ethyl alcohol, formate and p-cresol inhibit, but citrate ions enhance the formation of these intermediates. A mechanism involving Fe(III) reduction according to an internal electron transfer is proposed. 相似文献
49.
We focused our work on the separation of phenothiazines that are important drugs used for the treatment of psychic diseases. For a better understanding of the metabolism of these solutes, we wanted to separate not only a mixture of 12 phenothiazines but also a mixture containing phenothiazines and their N-demethyl metabolites by capillary electrophoresis. Separations in capillary zone electrophoresis were performed using 3 x 10(-2) mol/L H3PO4 (pH 2.5) but the obtained resolutions were not entirely satisfactory especially with regard to phenothiazine -N-demethyl derivative pairs. To improve the obtained results, we have performed separations by using micellar electrokinetic chromatography. In this approach, we used a running electrolyte containing 3 x 10(-2) mol/L H3PO4 electrolyte (pH 2.5) and octaethylene glycol monododecyl ether (C12E8) as neutral surfactant. By introducing 2 x 10(-3) mol/L C12E8 in the electrolyte, 11 out of 12 phenothiazines have been baseline separated. With respect to the separation of a mixture containing 3 phenothiazines and their 3 demethyl derivatives, we obtained an excellent separation by using a running electrolyte prepared with 7.5 x 10(-4) mol/L C12E8 and 3 x 10(-2) mol/L H3PO4. 相似文献
50.
At pH 5 (AcOHAcONa) protonation of the enamine of 3,6,6-trimethylnorpinane 2-one (3-methylnopinone) yields the cis immonium ion 6 (X OAc), which isomerizes to the thermodynamically more stable trans immonium ion 6′ (X OAc). Under more strongly acid conditions (aqueous hydrochloric or perchloric acids), the enamonium salts 7 (X Cl or ClO4) are formed; these isomerize, with a rate increasing with decreasing acidity to the cis immonium salts 6, stable under these conditions. Epimerization of the cis salt 6 (X Cl), occurs in ethereal hydrogen chloride, the rate increasing also with decreasing acidity. At pH 5, hydrolysis of the enamine yields 3-methylnopinone, the proportion of the less thermodynamically stable trans isomer increasing with a rise in reaction temperature. 相似文献