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121.
122.
Maria Luisa Dalla Chiara 《International Journal of Theoretical Physics》1995,34(8):1331-1336
The event-structure of a state-event system, containing unsharp elements, can be described either as aregular involutive bounded poset, or alternatively as anunsharp orthoalgebra (called alsodifference poset oreffect algebra). Such structures give rise to different forms ofunsharp quantum logics. 相似文献
123.
Michela Gasperini Chiara Remondini Alessandro Caselli Sergio Cenini 《Journal of organometallic chemistry》2005,690(20):4517-4529
The application of the palladium-phenanthroline catalytic system to the carbonylation of nitrobenzene in the presence of aniline to afford diphenylurea has been investigated. The reaction is best performed with equimolar amounts of the two reagents. Use of higher concentrations of either aniline or nitrobenzene or an increase in temperature in the range 120-170 °C leads to the formation of higher amounts of azo- and azoxybenzene. The latter were found to contain exclusively the aryl moiety deriving from nitrobenzene, with no inclusion of that derived from aniline. The addition of a small amount of diphenylphosphinic acid doubles the conversion and improves the selectivity in diphenylurea, but the effect is attenuated for larger amounts of acid. Small amounts of chloride, of the order of 10-30 mol% with respect to palladium, improve both rate and selectivity, but only inhibiting effects are detected when chloride is added to the reaction mixture for the carbonylation of 2,4-dinitrotoluene to dimethyl 2,4-toluenedicarbamate. The data obtained and that previously reported in the literature has been analyzed in the context of a unifying mechanism and an explanation for some apparent contradictions has been given. 相似文献
124.
Chiara Dall'asta Gianluigi Ingletto Roberto Corradini Gianni Galaverna Rosangela Marchelli 《Journal of inclusion phenomena and macrocyclic chemistry》2003,45(3-4):257-263
Cyclodextrins have been used as fluorescence enhancers in HPLC to improve thedetection limits of aflatoxins, cancerogens which can be found in severalfoodstuffs. In this work, a screening of several cyclodextrins has been performedin order to find the factors affecting the fluorescence enhancement. Evidence for formationof a 1 : 1 AF-CD inclusion complex has been achieved by titration and competitiveexperiments with adamantanecarboxylic acid and by fluorescence quenching by KI.Stability constants of the AF-CD complexes were evaluated. 相似文献
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127.
F. S. Gaeta G. Scala G. Brescia A. Di Chiara 《Journal of Polymer Science.Polymer Physics》1975,13(1):177-202
Experiments have been carried out on thermal diffusion of macromolecular particles dispersed in various liquids, with the object of checking some predictions of the radiation-pressure theory of Soret effect in liquids and of establishing a method of physical characterization of macromolecules in liquid solutions. The experimental results confirm the importance of the ratio G between thermal conductivity K and (phase) velocity v of high-frequency elastic waves of the materials composing the mixture in determining the thermodiffusive behavior of a liquid solution. We have shown that the migration of the macromolecular component takes place in the same direction in which thermal energy is flowing or opposite to it, depending on whether G of the dispersed particles is smaller or larger relative to the G of the liquid. Another aspect of the same phenomenon may be observed when macroscopic pieces of nonmetallic materials are suspended in a liquid, and heat is made to flow through this solid plunger and the surrounding liquid. The experiments performed with molecular solutions and with macroscopic plungers mutually complement and confirm each other. Anomalous results obtained in the case of solutions of polyvinylpyrrolidone in methanol are also discussed, and the possibility that this might be the consequence of the existence of a marked velocity dispersion in the high-frequency region of the spectrum of thermal waves in both water and methyl alcohol is indicated. Finally the possibility is hinted that thermal diffusion might have been responsible for the phenomena of molecular selection and evolution which ultimately led to the origin of life on our planet. 相似文献
128.
Chiara Castiglioni Mariangela Gussoni Juan Teodomiro Lopez Navarrete Giuseppe Zerbi 《Mikrochimica acta》1988,94(1-6):247-249
A preliminary analysis of the spectra of poly-para-phenylene and of a few oligomers (bi to hexa) is reported. Both frequencies and intensities are discussed. 相似文献
129.
We prove quark confinement in the two-dimensional lattice Higgs-Villain model in the weak coupling region by using a Kirkwood-Salsburg equations for unbounded spins.Research partially supported by the National Science Foundation under Grant PHY-77-18762On leave from Department of Mathematics, University of British Columbia, Vancouver, B.C., Canada. Research partially supported by National Research Council under Grant A4015On leave from Istituto di Fisica Teorica, Napoli, Italy 相似文献
130.
Realini M Colombo C Sansonetti A Rampazzi L Colombini MP Bonaduce I Zanardini E Abbruscato P 《Annali di chimica》2005,95(3-4):217-226
The analytical studies carried out during two different diagnostic surveys, respectively in 1983 and 2003, offered the opportunity to control decay phenomena development on stones facing Certosa of Pavia (Italy). Calcium oxalate films and red stains, present on Carrara marble surface, have been particularly focused; these are the only decay phenomena which apparently have remained unchanged during a period of twenty years. More sensitive and in-depth analytical studies (FTIR equipped with diamond cell, GC-MS, SEM-EDS and optical microscopy) achieved a better knowledge about their composition. Results allowed a critical evaluation of the role of oxalate films on the external marble surface and to suggest new hypotheses about the formation of red stains. 相似文献