Accessing 1,2‐Substituted Cyclobutanes through 1,2‐Azaborine Photoisomerization

We provide a seminal example of the utility of the 1,2‐azaborine motif as a 4C+1N+1B synthon in organic synthesis. Specifically, conditions for the practically scalable photoisomerization of 1,2‐azaborine in a flow reactor are reported that furnish aminoborylated cyclobutane derivatives. The C?B bonds could also be functionalized to furnish a diverse set of highly substituted cyclobutanes.     

The physics of 2 ≠ 1 + 1

One of the most surprising consequences of quantum mechanics is the entanglement of two or more distant particles. In an entangled EPR two-particle system, the value of the momentum (position) for neither single subsystem is determined. However, if one of the subsystems is measured to have a certain momentum (position), the other subsystem is determined to have a unique corresponding value, despite the distance between them. This peculiar behavior of an entangled quantum system has surprisingly been observed experimentally in two-photon temporal and spatial correlation measurements, such as “ghost” interference and “ghost” imaging. This article addresses the fundamental concerns behind these experimental observations and to explore the nonclassical nature of two-photon superposition by emphasizing the physics of 2 ≠ 1 + 1.     

Copper(ll) Complexes of Diamino Diamide and Diamino Diamine in Aqueous Solution

In order to study the difference on the equilibrium, spectral properties of copper(II) complexes of diamino diamide and diamino diamine, new tetradentate ligands, 4,7‐dimethyl‐4,7‐diazadecanediamide (4,7‐N,N′‐Me₂‐L‐2,2,2) and 1,10‐diamino‐4,7‐dimethyl‐4,7‐diazadecane (4,7‐N,N′‐Me₂‐3,2,3‐tet), have been synthesized. Synthetic procedures for these new ligands are described. Their protonation constants have been determined potentiometrically in 0.10 MKC1 at 25.0°C. The formation of their copper(II) complexes have been investigated quantitatively by the potentiometric technique and by the measurement of their electronic spectra.     

Modeling of Internal Reacting Flows and External Static Stall Flows Using RANS and PRNS

The reacting flow in a research lean direct injection (LDI) hydrogen combustor and the static stall of NACA0012 airfoil were simulated using both Reynolds averaged Navier–Stokes (RANS) and partially resolved numerical simulation (PRNS) approaches. The concept and the main features of the PRNS approach are briefly described. The PRNS basic equations are grid independent or grid invariant; the subscale models are a dynamic equation system. We consider PRNS as an engineering tool for the very large eddy simulation of complex turbulent flows. Two CFD codes, NCC and Wind-US, with two different subscale models (i.e. two- and one-transport equation models, respectively) are used in the presented PRNS simulations. Based on the comparisons with available experimental data, the numerical results indicate that the PRNS subscale models seem to be able to capture important large scale turbulent structures and to improve the quality of numerical simulations while keeping a relatively low cost comparable to the unsteady RANS simulations.     

Distribution characteristics of methamphetamine and amphetamine in urine and hair specimens collected from alleged methamphetamine users in northern Taiwan

This study was conducted to better understand the distribution characteristics of methamphetamine and amphetamine in urine and hair specimens collected from alleged methamphetamine users in the local population. It is anticipated that the data hereby obtained will be helpful to the interpretation of the time and pattern of drug use. Eight alleged methamphetamine-using arrestees from Keelung Police Department (north of Taipei, Taiwan) consented to contribute both urine and hair specimens. Each arrestee contributed seven urine specimens collected at 0, 12, 24, 48, 72, 96, and 120 h, respectively, after the arrest. Hair specimens were cut into 2-cm sections. The limits of detection and quantitation of the urine protocol were 40 and 50 ng/mL, respectively, for both amphetamine and methamphetamine, while the corresponding limits of detection and quantitation for the hair protocol were 0.8 and 1.0 ng/mg, respectively. The concentration variations of methamphetamine and amphetamine in the urine specimens exhibited three distinct patterns: (a) continuous decrease in the analytes’ concentrations for specimens collected at hours 0-120; (b) increase in the analytes’ concentrations in specimens collected at hours 0-12, followed by decrease; (c) increase in analytes’ concentrations in specimens collected at later times. Together with the amphetamine/methamphetamine concentration ratios found in these urine specimens, the observed trends in the changes of the analytes’ concentrations are helpful for the interpretation on the time of drug use. Unlike urine specimens, amphetamine/methamphetamine concentration ratios in various hair specimens and hair sections remain relatively constant.     

Spatiotemporal optical modulation instability of coherent light in noninstantaneous nonlinear media

We report on the theoretical derivation and experimental observation of spatiotemporal modulation instability (MI) of a coherent light beam in noninstantaneous nonlinear media. We obtain analytically the MI growth rate as a function of the spatial and temporal frequencies of the perturbation and the material response time. In the experiment, we observe that the varying speed of the MI patterns increases with the decreased material response time. We also observe that increasing the material response time can arrest the MI, agreeing with our theoretical derivation.     

Giant nonlinear optical properties of bismuth thin films grown by pulsed laser deposition

Thin films of Bi were grown by pulsed laser deposition on glass substrates at room temperature. The thickness and roughness of the films were characterized by grazing-incidence x-ray reflectivity, and the complex refractive indices were measured in the range from 1.5 to 4 eV by spectroscopic ellipsometry. We performed Z-scan measurements to study the third-order optical nonlinearity of the films. It was found that the Bi films exhibited an unusually large nonlinear refractive coefficient, n(I)~1.24x10(-1) cm(2)/kW and nonlinear absorption coefficient, alpha(I)~-3.97 cm/W , at low laser intensity, ~60 kW/cm(2) . This anomaly is believed to have an origin related to melting of the Bi films at the focus spot by the laser beam.     

The Photochemical Reactions of Ketene-Benzene Mixture

In the photolysis of ketene with benzene in the gas phase, Cycloheptatriene (CHT) and totuene (Tol) have been observed as the products. The ratio, (CHT)/(CHT)+(Tol) are studied at various conditions. The difference of activation energy of formation between toluene and cycloheptariene is evaluated to be 4.76 kcal/mole.     

数值解多维问题的外推与组合技术的若干新进展

本文综述近年来数值解多维问题的外推与组合技术的新进展，内容包括分裂外推及其在偏微分方程、多堆积分方程、多维数值积分中的应用；Ｃ．Ｚｅｎｇｅｒ的稀疏网格法与组合求解技术；以及解边界积分方程的组合方法，本文通过算例表明这些方法是非常有效的，是解多维问题的钥匙。     

Preparation of alkyl-surface functionalized germanium quantum dots via thermally initiated hydrogermylation

A new, thermally initiated hydrogermylation-based method for the synthesis and surface functionalization of air- and moisture-stable germanium quantum dots is reported.