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141.
ZnO‐Coated Carbon Nanotubes: Inter‐Diffusion of Carboxyl Groups and Enhanced Photocurrent Generation 下载免费PDF全文
Chia‐I Hung Dr. Hua‐Chiang Wen Yao‐Cheng Lai Dr. Shih‐Hsin Chang Prof. Dr. Wu‐Ching Chou Prof. Dr. Wen‐Kuang Hsu 《Chemphyschem》2015,16(4):812-816
ZnO is a defect‐governed oxide and emits light at both visible and UV regimes. This work employs atomic layer deposition to produce oxide particles on oxygenated carbon nanotubes, and the composites only show emission profiles at short wavelengths. The quenching of defect‐related emissions at long wavelengths is verified, owing to carboxyl diffusion into oxygen vacancies, and doping is supported by ZnCO3 formation in oxide lattice. Fully coated tubes display an increased photocurrent and the quantum efficiency increases by 22 % relative to the bare nanotubes. 相似文献
142.
Electroluminescence (EL) performance of flexible organic light-emitting device (FOLED) has been found to be highly dependent upon the morphology of the surface of the indium thin oxide (ITO)/plastic substrate as well as the patterning and processing conditions of the substrate. We will present evidence showing that luminance efficiency of FOLED can be greatly improved by pretreatment. Surface analysis of the ITO/PET by means of atomic force microscope (AFM) and optical microscope will be compared with that of the ITO/glass and the influence of flexible OLEDs substrate treatment by various methods on EL performance will also be discussed. 相似文献
143.
Poly(p‐phenylenevinylene) presenting pendent pentaphenylene dendron groups for light‐emitting diodes
Ya‐Hsien Tseng Fang‐Iy Wu Ping‐I Shih Ching‐Fong Shu 《Journal of polymer science. Part A, Polymer chemistry》2005,43(21):5147-5155
We have synthesized, using the Gilch method, a novel poly(p‐phenylenevinylene) derivative (PPV‐PP) containing two pendent pentaphenylene dendritic wedges, and have characterized its structure and properties. The incorporated side chain pentaphenylene dendrons serve as solubilizing groups, prevent π‐stacking interactions from occurring between the polymer main chains, and suppress the formation of excimers in the solid state. Photoluminescence studies indicate that efficient intramolecular energy transfer occurred from the photoexcited pentaphenylene groups to the poly(p‐phenylenevinylene) backbone. The polymer film exhibits a maximum emission at 510 nm and had a photoluminescence efficiency of 46%, which is similar to that measured in dilute solution. The photoluminescence spectra remained almost unchanged after thermal annealing at 150 °C for 20 h, and displayed inhibited excimer formation. Polymer light‐emitting diodes that we fabricated in the configuration ITO/PEDOT/PPV‐PP/Mg:Ag/Ag exhibited a maximum emission peak at 513 nm, corresponding to the green region [x = 0.30 and y = 0.62 in the Commission Internationale de L'Eclairage (CIE) chromaticity coordinates]. The maximum brightness and maximum luminance efficiency were 1562 cd/m2 and 1.93 cd/A, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5147–5155, 2005 相似文献
144.
The study aims to exploit incremental analysis or marginal analysis to overcome the drawbacks of ratio scales utilized in various multi-criteria or multi-attribute decision making (MCDM/MADM) techniques. In the proposed 11-step procedure, multiple criteria of alternatives are first reorganized as two categories – benefits and costs – and decision information will be manipulated separately. The performances of alternatives are then evaluated on their incremental benefit–cost ratio, and the rank can be obtained by applying the group TOPSIS (technique for order preference by similarity to ideal solution) model (Shih et al., 2007). Two representations of cost, i.e., a cost index and utility index, are proposed in the model to better-fit real-world situations. In addition, some considerations on costs and input–output relations are also discussed in order to understand the essentials of incremental analysis. In the final part, a case of robot selection demonstrates the suggested model to be both robust and efficient in a group decision-making environment. 相似文献
145.
The concept of coefficient shift matrix is introduced to represent delay variables in block pulse series. The optimal control of a linear delay system with quadratic performance index is then studied via block pulse functions, which convert the problems into the minimization of a quadratic form with linear algebraic equation constraints. The solution of the two-point boundary-value problem with both delay and advanced arguments is circumvented. The control variable obtained is piecewise constant. 相似文献
146.
Vapor phase pyrolysis of -1,2-(dideuteriomethylene) cyclobutane iron tricarbonyl at 170° resulted in hydrogen scrambling. Degradation of the rearrangement product indicated that either one exomethylene group was exchanging with one ring methylene or hydrogens were being reversibly transferred from the ring carbons to the exocyclic ones. Mechanisms that would explain either possibility involve the intermediacy of a sigma bonded iron with a π-allyl ligand. 相似文献
147.
H. Hübel R. M. Diamond P. Aguer C. Ellegaard D. B. Fossan H. Kluge C. Schück S. Shih F. S. Stephens U. Smilanski 《Zeitschrift für Physik A Hadrons and Nuclei》1982,304(3):225-230
Average lifetimes of unresolved transitions deexciting very high spin states populated in28Si(136, 129Xe,xn)164? x, 157?xEr reactions have been determined by a Doppler shift attenuation method. We find that the yrast bump region between 1.0 and 1.6 MeV contains a majority of strongly collectiveE2 transitions with very short lifetimes (a few tens of fsec) in the well deformed nuclei around159Er and, with less certainty, almost comparably short lifetimes in the more spherical nuclei around152Er. In the high energy region of 2.0–3.2 MeV we observe transitions which depopulate longer lived states in the nuclei nearN=82 than in the well deformed systems. 相似文献
148.
Total syntheses of 1α- and 1β-methyl thienamycin are reported. 1β-Methyl thienamycin retains the antibacterial activity of thienamycin and is highly resistant to hydrolysis by DHP-I enzyme. 相似文献
149.
Journal of Optimization Theory and Applications - Optimal modal feedback control laws are synthesized from the modal equations which are obtained by eigenfunction expansion of the diffusion... 相似文献
150.