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101.
The energy and angular momentum flux carried by gravitational waves from a spinning rod are calculated exactly in the weak field limit of general relativity. It is shown that contrary to common belief, the energy and angular momentum flux are not proportional and the energy and angular momentum equations governing the evolution of the rod are not identical. The spinning rod does not remain rigid: Its length increases. Both the angular deceleration and the rate of change of length are dependent on the nature of the material of the rod, and these rates are small, as expected.  相似文献   
102.
Thienylmercury(II)chloride reacts with [Pd(PPh3)2Cl2], [Pd(PPh3)4] and [Pt(PPh3)4] to afford new compounds containing a metal-2-thienyl linkage. The compound [Pd(PPh3)2(2-C4H3S)Cl] probably has trans stereochemistry.2-Bromothiophen undergoes oxidative addition with [Pd(PPh3)4] and [Pt(PPh3)4], probably via a radical mechanism. With [Pd(CO)(PPh3)3], a carbonyl inserted product is obtained. The bromo-metal(II) complexes have trans stereochemistry. The course of the reaction between 3-methyl-2-bromothiophen and Pd(PPh3)4 is more complex. Thus, there is evidence of some cis bromopalladium(II) compounds amongst the products, also there is good evidence to support the view that some isomerisation of 3-methyl-2-thienyl to 4-methyl-2-thienyl occurs during the reaction, thus giving greater molar quantities of [Pd(PPh3)2(4-CH3-2-C4H2S)Br] than can be accounted for from any initial 4-methyl-2-bromothiophen impurity.The metallation of the thiophen ring, probably in the 4-position, with palladium(II) is described for 3-theylidene-4-methylaniline.  相似文献   
103.
    
A time-dependent box model is developed to calculate oxygen isotope compositions of bone phosphate as a function of environmental and physiological parameters. Input and output oxygen fluxes related to body water and bone reservoirs are scaled to the body mass. The oxygen fluxes are evaluated by stoichiometric scaling to the calcium accretion and resorption rates, assuming a pure hydroxylapatite composition for the bone and tooth mineral. The model shows how the diet composition, body mass, ambient relative humidity and temperature may control the oxygen isotope composition of bone phosphate. The model also computes how bones and teeth record short-term variations in relative humidity, air temperature and δ18O of drinking water, depending on body mass. The documented diversity of oxygen isotope fractionation equations for vertebrates is accounted for by our model when for each specimen the physiological and diet parameters are adjusted in the living range of environmental conditions.  相似文献   
104.
    
A new way has been investigated for tuning the optical and electronic performance of cyclometalated iridium(III) phosphors by simple tailoring of the phenyl ring of ppy (Hppy = 2‐phenylpyridine) with various main group moieties in [Ir(ppy‐X)2(acac)] (X = POPh2, SO2Ph, GePh3, OPh, OPh(CF3)3, SOPh). The geometric and electronic structures of the complexes in the ground state are studied with time‐dependent density functional theory (TD‐DFT) and Hartree–Fock method, whereas the lowest singlet and triplet excited states are optimized by the configuration interaction singles method. At the TD‐DFT level, absorptions and phosphorescence properties of the studied molecules were calculated on the basis of the optimized ground‐ and excited‐state geometries, respectively. The various main group moieties produce a remarkable influence on their optoelectronic properties. The calculated data reveal that the studied molecules have improved charge transfer rate and balance and can be used as hole and electron transport materials in organic light‐emitting devices. In particular, the work can provide valuable insight toward future design of new and relatively rare luminescent materials with enhanced electron‐injection and electron‐transporting features. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
105.
    
We present a review of photoexcited quasiparticle dynamics of cuprate and pnictide high‐temperature superconductors in regimes (temperature, doping) where different phases such as superconductivity, spin‐density‐wave (SDW) and pseudogap phases coexist or compete with one another. We start with the overdoped cuprate superconductor Y1–xCax Ba2Cu3O7–δ, where the superconducting gap and pseudogap coexist in the superconducting state. In another cuprate Tl2Ba2Ca2Cu3Oy, we ob‐ serve a competition between SDW and superconducting orders deep in the superconducting state. Finally, in the underdoped iron pnictide superconductor (Ba,K)Fe2As2, SDW order forms at 85 K, followed by superconductivity at 28 K. We also find the emergence of a normal‐state order that suppresses SDW at a temperature T * ~ 60 K and argue that this normal‐state order is a precursor to superconductivity. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
106.
    
Conductive‐tip atomic force microscopy (C‐AFM) is a powerful tool for investigating the electrical characteristics of phase‐change materials commonly used for electronic and optical data storage. We demonstrate the usefulness of this technique by examining the electrical conductivity of crystalline marks recorded with a focused laser pulse on a thin Ge2Sb2Te5 film.  相似文献   
107.
    
Transformation optics, a recent geometrical design strategy of light manipulation with both ray trajectories and optical phase controlled simultaneously, promises an invisibility cloaking device that can render a macroscopic object invisible even to a scientific instrument measuring optical phase. Recent “carpet” cloaks have extended their cloaking capability to broadband frequency ranges and macroscopic scales, but they only demonstrated the recovery of ray trajectories after passing through the cloaks, while whether the optical phase would reveal their existence still remains unverified. In this paper, a phase‐preserved macroscopic visible‐light carpet cloak is demonstrated in a geometrical construction beyond two dimensions. As an extension of previous two‐dimensional (2D) macroscopic carpet cloaks, this almost‐three‐dimensional carpet cloak exhibits three‐dimensional (3D) invisibility for illumination near its center (i.e. with a limited field of view), and its ideal wide‐angle invisibility performance is preserved in multiple 2D planes intersecting in the 3D space. Optical path length is measured with a broadband pulsed‐laser interferometer, which provides unique experimental evidence on the geometrical nature of transformation optics.

  相似文献   

108.
    
A series of regiochemically varied and core size extension‐modulated arene‐ and fluoroarene‐thiophene co‐oligomers and the unsubstituted sexithiophene α6T were investigated theoretically to explore their electronic and optical properties. These phenylene‐thiophene oligomers show great potential for application in organic light‐emitting diodes (OLEDs), organic diode lasers, and organic thin‐film transistors (OTFTs) because of their feasible tuning of optical and electronic properties by the various structural tunings. Density functional theory (DFT) and the ab initio HF were employed to investigate the geometric and electronic structures of the oligomers in the ground state, and the singles configuration interaction (CIS) methods were used to study the lowest singlet excited state. The lowest excitation energies (Egs), the radiative lifetime τ, and the maximal absorption/emission wavelength of the oligomers were studied within time‐dependent DFT (TDDFT). All calculations were performed using the 6‐31G(d) basis set. The results show that the HOMOs, LUMOs, energy gaps, ionization potentials (IPs), electron affinities (EAs), and reorganization energies are significantly affected by the various structural tunings in these co‐oligomers, which is important for the improvement of the hole and electron injection into OLEDs. Interestingly, the LUMO energy of 1b , 2b , and 3b is lower than that of α6T and 1a , 2a , 3a by about 0.12 ~ 0.47 eV, indicating that the fluorophenyl‐substitution has significantly improved the electron injection properties of the oligomers. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
109.
In this paper, we applied the polyharmonic splines as the basis functionsto derive particular solutions for the differential operator ∆2 ± λ2. Similar to thederivation of fundamental solutions, it is non-trivial to derive particular solutionsfor higher order differential operators. In this paper, we provide a simple algebraicfactorization approach to derive particular solutions for these types of differentialoperators in 2D and 3D. The main focus of this paper is its simplicity in the sensethat minimal mathematical background is required for numerically solving higherorder partial differential equations such as thin plate vibration. Three numericalexamples in both 2D and 3D are given to validate particular solutions we derived.  相似文献   
110.
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