棒状分子聚合物溶液的微宏观数值模拟

利用微宏观耦合方法模拟了棒状分子聚合物溶液在平板Couette流动中的复杂流变行为,其中微宏观模型通过非均匀Doi理论来描述.数值模拟中,应用有限体积方法耦合求解了介观尺度上的Smoluchowski方程和宏观尺度上的流场守恒方程.数值结果不仅得到了若干种典型的流动类型,而且还预测了另外两种新的复合瑕疵结构.数值试验表明：棒状分子聚合物的流变结构主要依赖于De数、分子相对尺度以及溶液浓度常数的取值;并且De数对分子指向矢的翻滚周期、随流取向角等微观特性也均有明显影响. 关键词： 棒状分子 聚合物溶液 微宏观模拟     

Room-temperature direct-bandgap photoluminescence from strain-compensated Ge/SiGe multiple quantum wells on silicon

Strain-compensated Ge/Si_0.15Ge_0.85 multiple quantum wells were grown on an Si_0.1>Ge_0.9 virtual substrate using ultrahigh vacuum chemical vapor deposition technology on an n⁺-Si(001) substrate. Photoluminescence measurements were performed at room temperature, and the quantum confinement effect of the direct-bandgap transitions of a Ge quantum well was observed, which is in good agreement with the calculated results. The luminescence mechanism was discussed by recombination rate analysis and the temperature dependence of the luminescence spectrum.     

Experimental confirmation of a new reversed butterfly-shaped attractor

This paper reports a new reverse butterfly-shaped chaotic attractor and its experimental confirmation. Some basic dynamical properties, and chaotic behaviours of this new reverse butterfly attractor are studied. Simulation results support brief theoretical derivations. Furthermore, the system is experimentally confirmed by a simple electronic circuit.     

Design of square-shaped heat flux cloaks and concentrators using method of coordinate transformation

A square-shaped heat flux cloak and a square-shaped heat flux concentrator have been designed theoretically according to the invariance symmetry of steady state thermal conductive equation. The direction of heat flux in these devices can be modulated as desired. Using the method of coordinate transformation, the inhomogeneous and anisotropic thermal conductivity in the transformation region have been acquired. Two-dimensional finite element simulations were performed to confirm the theoretical results.     

Structural and electronic properties of cobalt carbide Co2C and its surface stability: Density functional theory study

Density functional theory calculations have been performed to investigate the structural and electronic properties of bulk Co₂C and the stability of low index Co₂C surfaces. We found that the formation of Co₂C is exothermic with the formation energy of ? 0.81 eV/Co₂C with respect to Co under the presence of syngas (mixture of CO and H₂). While formed Co₂C can be decomposed further to metal Co and graphite carbon with modest energy gain of 0.37 eV/Co₂C. This suggests that Co₂C is only metastable in Fischer–Tropsch synthesis, which agrees well with experimental findings. The density of states (DOSs) reveals that the Co₂C is paramagnetic and strong metallic-like. The difference of charge density analysis indicates that the bond of Co₂C is of the mixtures of metallic, covalent, and ionic properties. A variety of low index Co₂C surfaces with different terminations are studied. We find that the surface energy of low index stoichiometric Co₂C highly relies on the surface area, the number of coordination of surface atoms and the surface dipole, with the decreased stability order of (101) > (011) > (010) > (110) > (100) > (001) = (111). Our results indicate that under Co-poor condition, the formation of non ? stoichiometric surface (011) and (111) without terminated cobalt is energetically more favorable, while under Co-rich condition the formation of non ? stoichiometric (111) surface with cobalt overlayer are preferential.     

与偏振无关的双向3×3光开关结构设计

利用传统成熟的偏振控制技术,设计了一种由偏振光分束器、相位型空间光调制器、反射镜和四分之一波片构成的3×3光开关。该光开关具有结构紧凑规整、功能的实现与信号光的偏振态无关以及可以完成双向交换等特点。根据其路由控制表对该3×3光开关交换模块功能的实现进行了分析,结果表明,通过对各相位型空间光调制器状态的调整,控制通过其信号光的偏振态,完成信号光的路由,该交换模块可以完成输入信号光的全排列无阻塞输出与交换。同时,该交换模块具有一定的扩容和重构能力,对于构建大规模的交换矩阵具有一定的作用。     

Computer Simulation of a 3-D Sensing System with Structured Illumination

A computer simulation system of three-dimensional sensing with structured illumination is presented. It includes the generation of deformed fringe patterns from 3-D shapes and the reconstruction of 3-D shapes, conversely. Some experimental results of the deformed fringe pattern and the reconstructed object shapes are presented. We have also discussed the effect of some major system parameters on the measurement results and considered how to correct these parameters according to the measurement result of the standard plane. Using this simulation system, the major system parameters: environmental conditions, measurement accuracy and algorithm evaluation of the 3-D shape measurement system based on PMP, FTP, SPM, etc., can be researched. © 1997 Elsevier Science Ltd. All rights reserved.     

13CH4分子v3振动带空气和氮气加宽系数温度依赖性研究

采用中红外波段连续可调谐二极管激光器和自行研制的低温吸收池, 测量了温度为296 K, 252 K, 213 K, 173 K时, 3.38 μm附近¹³CH₄分子的四条跃迁谱线的氮气和空气加宽光谱; 首次通过实验获得空气和氮气对¹³CH₄分子的碰撞加宽系数, 以及谱线加宽系数的温度依赖系数. 实验过程中, 利用Voigt线型对所测量的光谱进行拟合. 实验结果表明, 氮气和空气对¹³CH₄分子的碰撞诱导加宽系数随温度的降低而增大; 相同温度下, 氮气对¹³CH₄分子的碰撞加宽系数普遍大于空气加宽系数. 实验数据为地球和外星体大气遥感探测提供了依据.     

丁酮分子内价轨道1a″的电子动量谱学研究

用高分辨率电子动量谱仪进行丁酮分子的结合能谱和内价轨道1a″电子动量谱的实验工作，以及用Hartree-Fock和密度泛函理论方法对1a″轨道电子动量谱的理论研究. 得到了各价轨道的电离能值以及理论计算的总能、偶极矩和1a″轨道的二维密度图. 并比较了内价轨道1a″的电子动量谱的实验和理论计算结果，实验结果与理论计算符合较好.     

碳纳米管锁模双包层光纤激光器的实验研究

本文采用双包层掺镱光纤作为增益介质,用单壁碳纳米管作为饱和吸收体,获得最高输出功率为336 mW的锁模脉冲激光.用飞秒激光诱导水击穿法直接在单模光纤上制备出D形区,通过在D形光纤上滴涂单壁碳纳米管溶液,成功制备出碳纳米管饱和吸收体,并对其饱和吸收特性进行测试,发现其调制深度为27％.利用该饱和吸收体作为锁模器件,制备出具有环形腔结构的锁模光纤激光器.当抽运功率为4W时,获得了脉宽为93.8 fs,中心波长为1083.8 nm,3 dB谱宽为8.6 nm,重复频率为5.59 MHz,平均功率为336 mW的飞秒脉冲激光输出.