Magnetic Order and Its Interplay with Structure Phase Transition in van der Waals Ferromagnet Ⅵ3

Van der Waals magnet Ⅵ3 demonstrates intriguing magnetic properties that render it great for use in various applications.However,its microscopic magnetic struct...     

一种适用于磁流体力学切向间断的HLLC黎曼算子

磁场的存在使得磁流体力学特征波模不同于流体力学, 因此直接由流体力学HLLC黎曼算子导出的HLLC双中间态在交界的间断面会出现不守恒的问题。通常降级采用HLL单磁场中间态代替HLLC双磁场中间态以实现守恒和计算稳定, 代价是切向间断的模拟精度不足。本文对此进行改进, 在模拟切向间断时仍然保留原有的HLLC双磁场中间态, 同时各守恒量仍然能够满足Toro相容条件; 改进型HLLC算子在间断两侧的磁场分量存在差异, 因此能够更精确还原切向间断面。基于数值测试, 包括一维激波管和切向间断的时变模拟, 以及地球磁层三维数值模拟, 将模拟结果进行对比, 结果表明: 相比于已发展的HLLC算子, 改进型HLLC算子对切向间断具有更好的捕捉精度, 能够达到或接近耗时更多的HLLD算子的模拟精度。     

Compact beam expander based on planar structure to avoid inner focus

Optical Review - Based on the planar optical theory, compact beam expanders are proposed to miniaturize the dimension of an optical system. Both simulated and experimental results have demonstrated...     

Synthesis of novel copolymer：Poly(p-dioxanone-co-L-phenylalanine)

In order to expand the application of poly(p-dioxanone) or PPDO in biomedical area,a series of novel copolymers were synthesized successfully by one-step,melted copolymerization of p-dioxanone(PDO) and L-phenylalanine N-carboxyanhydride(L-Phe-NCA) monomers.With the in-feed molar ratio of L-PheNCA /PDO equal to 1/20,the conversions of the two kinds of monomers were calculated from ~1H NMR. The average molecular weight and polydispersity of the copolymer increase with the increasing reaction time and catalyst concentration.However,the conversions of the two kinds of monomers did not change with the reaction conditions.A three-step mechanism is presented and proved by high resolution ~1H NMR and IR spectrums.     

Bis‐clickable Mesoporous Silica Nanoparticles: Straightforward Preparation of Light‐Actuated Nanomachines for Controlled Drug Delivery with Active Targeting

Bis(clickable) mesoporous silica nanospheres (ca. 100 nm) were obtained by the co‐condensation of TEOS with variable amounts (2–5 % each) of two clickable organosilanes in the presence of CTAB. Such nanoparticles could be easily functionalized with two independent functions using the copper‐catalyzed alkyne‐azide cycloaddition (CuAAC) reaction to transform them into nanomachines bearing cancer cell targeting ligands with the ability to deliver drugs on‐demand. The active targeting was made possible after anchoring folic acid by CuAAC click reaction, whereas the controlled delivery was performed by clicked azobenzene fragments. Indeed, the azobenzene groups are able to obstruct the pores of the nanoparticles in the dark whereas upon irradiation in the UV or in the blue range, their trans‐to‐cis photoisomerization provokes disorder in the pores, enabling the delivery of the cargo molecules. The on‐command delivery was proven in solution by dye release experiments, and in vitro by doxorubicin delivery. The added value of the folic acid ligand was clearly evidenced by the difference of cell killing induced by doxorubicin‐loaded nanoparticles under blue irradiation, depending on whether the particles featured the clicked folic acid ligand or not.