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通过对套铣筒这种特殊结构钻柱的分析,在现有钻柱力学模型研究的基础上,针对 套铣筒结构特点(大筒径、薄壁筒型钻柱),建立套铣筒与井壁接触力学模型,通过分析套铣 管柱在井下屈曲状态以及与井壁接触压力的计算,对套铣筒进行力学分析以及摩阻力计算.     

The First Principle Formula of the Relativistic Heat Conductivity of Coulomb Electronic Plasmas

Making use of the relativistic BBGKY technique,the relativistic generalization of Landau collision integral is botained.Furthermore,we calculate the relativistic hydrodynamic modes up to the second order in the hydrodynamic wave number.Combining Resibois‘ method,we present the first principle formula of the relativistic heat conductivity of Coulumb electronic plasmas for low-order corrections.     

用统一耦合模理论分析含布拉格光栅的对称光纤耦合器的传输特性

利用由麦克斯韦方程组直接导出的统一耦合模理论分析各类型的含布拉格光栅的对称光纤耦合器的传输特性。与以前发表的分析方法不同,对于含布拉格光栅的耦合区域,统一耦合模型理论同时考虑了布拉格光栅和耦合的耦合作用。模拟结果证明它能精确地模拟和解释各种类型的含布拉格光栅的对称光纤耦合器的有关实验现象。     

Construction of stationary self-similar generalized fields by random wavelet expansion

Random wavelet expansion is introduced in the study of stationary self-similar generalized random fields. It is motivated by a model of natural images, in which 2D views of objects are randomly scaled and translated because the objects are randomly distributed in the 3D space. It is demonstrated that any stationary self-similar random field defined on the dual space of a Schwartz space of smooth rapidly decreasing functions has a random wavelet expansion representation. To explicitly construct stationary self-similar random fields, random wavelet expansion representations incorporating random functionals of the following three types are considered: (1) a multiple stochastic integral over the product domain of scale and translate, (2) an iterated one, first integrating over the scale domain, and (3) an iterated one, first integrating over the translate domain. We show that random wavelet expansion gives rise to a variety of stationary self-similar random fields, including such well-known processes as the linear fractional stable motions. Received: 11 December 1998 / Revised version: 31 January 2001 / Published online: 23 August 2001     

The reliability of measurements on electron energy distribution function in silane rf glow discharges

Electron energy distribution function (EEDF) is a key parameter of plasmas, which is directly proportional to the second derivative of the probe I-V characteristics. Because of an amplifying effect of unavoidable noises in the experimental probe I-V curves during the derivation process, the experimental I-V curves should be smoothed before performing the numerical derivation. This paper investigates the effect of adjustable factors used in the smoothing process on the deduced second derivative of the I-V curves, and an optimum group of the adjustable factors is selected to make the rms deviation of the smoothed I-V curves from the measured curves less than 1%. A simple differentiation circuit is designed and used to measure the EEDF parameter straightforwardly. It is the first time, so far as we know, to measure the EEDF parameters simultaneously by means of both numerical and circuit derivative methods under the same discharge conditions and on the same discharge equipment. The deviation between two groups of mean electron energy E and electron density n_e obtained by the above different methods is within about 7%. This apparently improves the reliability of the measurements of the EEDF parameters.     

Synthesis and characterization of new hyperbranched poly(aryl ether oxadiazole)s

A new AB₂ monomer was synthesized for use in the preparation of a hyperbranched poly(aryl ether oxadiazole) with terminal phenol functionality. The AB₂ monomer contains two phenolic groups and a single aryl fluoride group that is activated toward nucleophilic displacement by the attached oxadiazole ring. The nucleophilic substitution of the fluoride with the phenolate groups led to the formation of an ether linkage. Subsequently, a hyperbranched poly(aryl ether oxadiazole) having approximately a 44% degree of branching, as determined by a combination of model compound studies and ¹H NMR, was obtained. The terminal phenolic groups underwent facile functionalization, furnishing hyperbranched polymers with a variety of functional chain ends. The nature of the chain‐end groups had a significant influence on the physical properties of the polymers, such as the glass‐transition temperature and their solubility. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3851–3860, 2001     

Synthesis of 1‐Methyl‐3‐aryl‐substituted Titanocene and Zirconocene Dichlorides and Crystal Structure of Bis[η5‐1‐methyl‐3‐(α, α‐dimethylbenzyl) cyclopentadienyl] titanium Dichloride

The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl₄·2THF, ZrCl₄ and (CpTiCl₂)₂O respectively, to give complexes 1–5. The complex [η⁵‐1‐methyl‐3‐(α, α‐dimethylbenzyl) cyclopentadienyl] titanium dichloride has been studied by X‐ray diffraction. The red crystal of this complex is monoclinic, space group P2_t/C with unit cell parameters: a =6.973(6) × 10^?1 nm, b =36.91(2) × 10^?1 nm, c = 10.063(4) × 10^?1 nm, α=β= γ = 93.35(5)°, V = 2584(5) × 10^?3 nm³ and Z = 4. Refinement for 1004 observed reflections gives the final R of 0.088. There are four independent molecules per unit cell.     

Reactions of Perfluoro(5-aza-4-nonene) with Hydrazine and Some Its Derivatives

The reaction of perfluoro(5-aza-4-nonene) with hydrazine hydrate in tetrahydrofuran at 0-20°C in the presence of triethylamine yields 2,5-bis(heptafluoropropyl)-1H-1,2,4-triazole; under similar conditions perfluoro(5-aza-4-nonene) reacts with arylhydrazines to form 1-aryl-3,5-bis(heptafluoropropyl)-1,2,4-triazoles.     

Density Functional Study on the Reactivity of Carbenes Toward 1,2‐H Shifts

The 1,2‐H shift reactions of simple carbenes (CH₂Y‐C‐X) have been studied using density functional theory (DFT). The influence of the substituent X and Y groups on the activation energy (Ea) of 1,2‐H shifts were examined. The ‘by stander’ Y substituents lower E_a in the order of Me, F > Cl, Br > H. Our analysis shows that the X effect is more significant than the by stander Y effect. X substitutions increase E_a of carbenes in the order of F > Cl > Br > Me > H. The influence of X on E_a is governed by the singlet‐triplet energy separation (ΔE_S‐T) of the carbene, i.e., E_a of a carbene is larger as its ΔE_S‐T in creases due to an X substitution. The X effect was also found to be related to the magnitude of the exothermicity: Ea of reaction is smaller when the reaction is more exothermic. Origin of the Y effect is attributed to the inter play between two factors: ‘lateness’ of transition state on the potential energy surface, and the exothermicity of the reaction.     

Synthesis of the Chiral Pair of a Novel Thromboxane Antagonist, 3‐[2‐(3‐Benzenesulfonylamino‐7‐oxabicyclo[2.2.1]hept‐2‐yl‐methyl)phenyl] Propionic Acid

Preparation of the enantiomeric pair of 3‐[2‐(3‐benzenesulfonylamino‐7‐oxabicyclo[2.2.1]hept‐2‐yl‐methyl)phenyl] propionic acid, a novel thromboxane antagonist is reported. They are synthesized from either enantiomers of known (1R,2R,3R,4S)‐3‐[2‐(3‐carboxy‐7‐oxabicyclo[2,2,1]hept‐2‐yl‐methyl)phenyl]‐propionic acid methyl ester via epimerization, modified Curtius' rearrangement and sulfonylamino formation. Other derivatives may be prepared similarly.