Oxidative transformation of azides to aryl nitriles using DIB/TBHP: scope and mechanistic insights

Bis(tert-butylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene (DIB) and tert-butyl hydroperoxide (TBHP), was used in the oxidative transformation of primary azides to nitriles, and secondary azides to ketones.     

Unified boundary integral equation for the scattering of elastic and acoustic waves: solution by the method of moments

A unified boundary integral equation (BIE) is developed for the scattering of elastic and acoustic waves. Traditionally, the elastic and acoustic wave problems are solved separately with different BIEs. The elastic wave case is represented in a vector BIE with the traction and displacement vectors as unknowns whereas the acoustic wave case is governed by a scalar BIE with velocity potential or pressure as unknowns. Although these two waves can be unified in the form of a partial differential equation, the unified form in its BIE counterpart has not been reported. In this work, we derive the unified BIE for these two waves and then show that the acoustic wave case can be derived from this BIE by introducing a shielding loss for small shear modulus approximation; hence only one code needs to be maintained for both elastic and acoustic wave scattering. We also derive the asymptotic Green's tensor for zero shear modulus and solve the corresponding vector equation. We employ the method of moments, which has been widely used in electromagnetics, as a numerical tool to solve the BIEs involved. Our numerical experiments show that it can also be used robustly in elastodynamics and acoustics.     

Prediction of double-pomeron cross sections from single-diffraction measurements

A particular case of a Mueller formula describing the absence of long-range two-particle correlations is used to predict double-pomeron cross sections from available data on single-diffraction dissociation. Although success of the formula in this application would immediately verify the double-pomeron hypothesis, the converse is not true because the formula may be invalidated by prominent low-energy resonances (such as the f₀) in the pomeron-pomeron total cross section. Low-statistics experiments at s = 200 and 400 GeV² are in order of magnitude agreement with the formula.     

Bootstrapping the photon

A nontechnical review is given of a topological bootstrap theory, with emphasis on theraison d'être for an electromagnetism whose fine-structure constant is of order10 ^?2.     

Topological “vector gluons”

It is shown that the axion can be made invisible in the family-unifyingSU(9) model and that all the light fermions become massive due to the radiative correction.     

Radiative width for the 10.35−6.92 MeV transition in 16O

From a measurement of the cross section for ¹²C(α, γ)¹⁶O at the E_α = 4.253±0.014 MeV(E = 10.352±0.011 MeV) resonance, the radiative width for the 10.35 MeV (J^π = 4⁺) to 6.92 MeV (J^π = 2⁺) transition was determined to be Γ_γ = 58±7 meV. This is somewhat higher than the value predicted by large j-j shell-model calculations, but agrees well with predictions based on the rotational and the SU(3) models for a 4p-4h band, and the deformed- basis calculation of Green and Brown.     

On Ito-Kurzweil-Henstock Integral and Integration-by-Part Formula

In this paper we derive the Integration-by-Parts Formula using the generalized Riemann approach to stochastic integrals, which is called the Ito-Kurzweil-Henstock integral.     

Highly sensitive miniature photonic crystal fiber refractive index sensor based on mode field excitation

A highly sensitive miniature photonic crystal fiber refractive index sensor based on field mode excitation is presented. The sensor is fabricated by melting one end of a photonic crystal fiber into a rounded tip and splicing and collapsing the other end with a single-mode fiber. The rounded tip is able to induce cladding mode excitation, which resulted in an additional phase delay. Linear response of 262.28 nm/refractive index unit in the refractive index range of 1.337 to 1.395 is obtained for the physical length of a 953 μm sensor. The sensor is also shown to be insensitive to environmental temperature.     

Axiomatic rank-dependent means

This paper provides an axiomatization for the implicit rank-dependent mean value, which class includes a number of mean values that have appeared in statistics, in utility theory and in the theory of income inequality measurement.