On heat transfer and flow characteristics of jets impinging onto a concave surface with varying jet arrangements

A new electrospinning process was developed for preparing TiO₂ nanofibers using a water-soluble Ti-precursor, [bis(kappa1O-hydroxo)(bis(kappa2O,O′-lactato)titanium(IV)] commonly known as titanium(IV) bis (ammonium lactato) dihydroxide (TiBALDH). The importance of the study is justified by the fact that Ti-precursors used for electrospinning, sol–gel, hydrothermal and other fiber synthesis processes are mostly non-water soluble. Accordingly, anatase TiO₂ nanofibers of diameter between 20 and 140 nm were synthesized by electrospinning and annealing. Polyvinylpyrrolidone (PVP) and different concentrations of TiBALDH were dissolved in a mixture of water, ethyl alcohol and acetic acid to optimize the electrospinning conditions. The thermal decomposition and fragmentation of PVP, TiBALDH and the fibers with 50% mass fraction of TiBALDH were studied by TGA-MS measurements. The fibers were then annealed at 1 °C min^?1 until 600 °C. The TiO₂ fibers were characterized using SEM–EDX, FTIR and XRD

     

High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries

Material innovation on high‐performance Na‐ion cathodes and the corresponding understanding of structural chemistry still remain a challenge. Herein, we report a new concept of high‐entropy strategy to design layered oxide cathodes for Na‐ion batteries. An example of layered O3‐type NaNi_0.12Cu_0.12Mg_0.12Fe_0.15Co_0.15Mn_0.1Ti_0.1Sn_0.1Sb_0.04O₂ has been demonstrated, which exhibits the longer cycling stability (ca. 83 % of capacity retention after 500 cycles) and the outstanding rate capability (ca. 80 % of capacity retention at the rate of 5.0 C). A highly reversible phase‐transition behavior between O3 and P3 structures occurs during the charge‐discharge process, and importantly, this behavior is delayed with more than 60 % of the total capacity being stored in O3‐type region. Possible mechanism can be attributed to the multiple transition‐metal components in this high‐entropy material which can accommodate the changes of local interactions during Na⁺ (de)intercalation. This strategy opens new insights into the development of advanced cathode materials.     

A Sodalite‐Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster

The synthesis and structure of a giant 102‐silver‐atom nanocluster (NC) 1 is presented. X‐ray structural analysis reveals that 1 features a multi‐shelled metallic core of Ag₆@Ag₂₄@Ag₆₀@Ag₁₂. An octahedral Ag₆ core is encaged by a truncated octahedral Ag₂₄ shell. The Ag₂₄ shell is composed of a hitherto unknown sodalite‐type silver orthophosphate cluster (SOC) {(Ag₃PO₄)₈}, reminiscent of the Ag₃PO₄ photocatalyst. The SOC is capped by six interstitial sulfur atoms, giving a unique anionic cluster [Ag₆@{(Ag₃PO₄)₈}S₆]^6?, which functions as an intricate polyhedral template with abundant surface O and S atoms guiding the formation of a rare rhombicosidodecahedral Ag₆₀ shell. An array of 6 linear Ag₂ staples further surround this Ag₆₀ shell. [Ag₆@{(Ag₃PO₄)₈}S₆]^6? is an unusual Ag‐based templating anion to induce the assembly of a SOC within silver NC. This finding provides molecular models for bulk Ag₃PO₄, and offers a fresh template strategy for the synthesis of silver NCs with high symmetry.     

具有固定敲定价格的算术平均亚式期权的计算

本文研究算术平均的欧式亚式期权.我们将充分利用偏微分方程的Fichera理论和边值问题的定解理论,求出了一个简单的近似解析表达式.经实际数据验算,有较满意的逼近结果,特别地,在部分区域内的计算效果好于文章[1].     

广义Burger方程的解析解

本文讨论广义Burger方程的解析解,我们证明了:当粘性系数γ(t)=常数或对γ(t)=(3kt k_1)~(-1/3)时,方程满足“有条件的Painlev(?)可积”.并求出了相应的解析解.     

对苯二甲酰氯与N-甲基吡咯烷酮反应机理以及对聚对苯二甲酰对苯二胺聚合的影响

稳定合成高分子量聚对苯二甲酰对苯二胺(PPTA)树脂是生产高性能芳纶纤维的基础.在PPTA聚合过程中,以单体对苯二甲酰氯(TPC)/N-甲基吡咯烷酮(NMP)溶液与单体对苯二胺(PPD)/NMP溶液进行溶液缩聚反应是最理想高效的方式,但是因为TPC/NMP间未知的相互作用导致这种聚合方式难以实现.通过实验与计算模拟相结合的方式,利用红外光谱(FTIR)、核磁共振(1H NMR)、飞行时间质谱及示差扫描量热分析对TPC/NMP间的反应进行了分析,并通过分子模拟计算证明TPC与NMP会发生类似Vilsmeier-Haack反应,导致TPC上的酰氯基团失活,从而严重影响其聚合反应活性.最后,通过PPTA聚合实验验证了该结论的正确性.     

热晕小尺度不稳定性实验研究

本文报导了STRS不稳定性的模拟实验结果,研究了正弦强度分布的小尺度扰动源在热晕介质中传播的不稳定性发展情况,对不同扰动空间周期、不同光功率下小尺度不稳定性的增长做了一些实验研究,证实了激光在介质传播中,热晕将导致小尺度不稳定性的指数增长。     

新型发射药爆炸TNT当量系数的实验研究

TNT当量系数是危险品工程抗爆设计和安全距离确定的重要依据。为确定H1和H2两种新型高能发射药的TNT当量系数,分别开展了10 kg TNT和新型发射药的空气自由场静爆实验。基于修正的当量系数计算方法和测量得到的不同爆心距离处冲击波超压时程曲线,确定了不同比例距离处两种高能发射药的超压和比冲量TNT当量系数。研究结果表明,发射药爆炸产生的冲击波传播规律与TNT炸药爆炸产生的冲击波传播规律相同,符合爆炸相似律,相同质量发射药爆炸产生的冲击波超压和比冲量都显著高于TNT的。随着比例距离的增大,H1的超压当量系数先增大后减小,最大值为1.34;H2的超压当量系数逐渐减小,最大值为1.26。两种新型发射药的比冲量TNT当量系数均随比例距离的增大先减小后增大,H2的比冲量TNT当量系数大于H1的,最大值为1.38。本文中修正的计算方法能更准确计算被试样品的TNT当量系数,实验结果可为提高抗爆结构安全性设计提供参考。