水母雪莲化学成分的研究（Ⅱ）

前文已报道从水母雪莲(Saussurea Medusa Maxim)中分得4种黄酮甙,本文报道另外6种化合物的分离和鉴定。 1 化合物Ⅰ—Ⅳ物化性质及分离鉴定 1.1 化合物Ⅰ 黄色结晶,m.p.:249～251℃,水解所得甙元鉴定为木樨草素,纸层析检出鼠李糖和葡萄糖。MS(FAB):m/z 595(M~++1),287(M~++H-葡萄糖基-鼠李糖)。化合物I与木樨草素的~(13)C NMR比较,C_6、C_8、C_(10)分别向低场位移1.1、1.0、1.8 ppm,而C,向高场移动     

两个非平行波导间的能量转换

提出一种分析非平行波导间耦合的简明方法-耦合系数推广法.利用这种方法,导出一种新的非平行双波导的耦合方程,由此得到一组非平行波导耦合的完美的分析解,依据这些分析解可以优化非平行波导的传输距离、输入／输出端口波导间距和夹角.     

Vector Ordinal Optimization

Ordinal optimization is a tool to reduce the computational burden in simulation-based optimization problems. So far, the major effort in this field focuses on single-objective optimization. In this paper, we extend this to multiobjective optimization and develop vector ordinal optimization, which is different from the one introduced in Ref. 1. Alignment probability and ordered performance curve (OPC) are redefined for multiobjective optimization. Our results lead to quantifiable subset selection sizes in the multiobjective case, which supplies guidance in solving practical problems, as demonstrated by the examples in this paper.This paper was supported in part by Army Contract DAAD19-01-1-0610, AFOSR Contract F49620-01-1-0288, and a contract with United Technology Research Center (UTRC). The first author received additional funding from NSF of China Grants 60074012 and 60274011, Ministry of Education (China), and a Tsinghua University (Beijing, China) Fundamental Research Funding Grant, and the NCET program of China.The authors are grateful to and benefited from two rounds of reviews from three anonymous referees.     

Facile Yb(OTf)3 promoted one-pot synthesis of polyhydroquinoline derivatives through Hantzsch reaction

Yb(OTf)₃ catalyzed efficient Hantzsch reaction via four-component coupling reactions of aldehydes, dimedone, ethyl acetoacetate and ammonium acetate at ambient temperature was described as the preparation of polyhydroquinoline derivatives. The process presented here is operationally simple, environmentally benign and has excellent yield. Furthermore, the catalyst can be recovered conveniently and reused efficiently.     

The Standard Association Constant of Ion Pair [GaCl]~(2+)in the System of HCl+GaCl_3+H_2O

This paper reports the EMF(electromotive force) measurements of cell (A) without liquid junction at five temperatures from 278.15 to 318.15 K. Pt|H2(101.325kPa)|HCl(m1),GaCl3(m2),H2O|Ag|AgCl (A) The measurements on the system HCl+GaCl3+H2O was carried out in an appropriate concentration of hydrochloric acid when the concentration of hydrochloric acid is not lower than 0.13 mol/kg the hydrolysis of Ga3+ can be avoided or elimited1. The standard association constant, KAS ,…     

电流型大面积PIN探测器

研制了灵敏区面积为40,50和60mm,耗尽层厚度为200—300μm的电流型大面积薄型PIN半导体探测器,并对其物理性能进行了测量.测试和应用表明,这些探测器性能稳定,漏电流符合使用要求.与市场上的大面积PIN半导体探测器相比,这些探测器主要在几百伏偏压下工作在电流模式,但也可用于计数模式,而目前的商用产品仅适用于计数测量. 关键词： 半导体探测器 大面积 电流型     

Interior estimates for solutions of a fourth order nonlinear partial differential equation

Let be a locally strongly convex hypersurface, given by the graph of a convex function xn+1=f(x₁,…,xn) defined in a convex domain Ω⊂Rn. M is called a α-extremal hypersurface, if f is a solution of

     

Study on measurement of linear electro-optic coefficient of a minute irregular octahedron cBN wafer

The cubic boron nitride (cBN) is a kind of artificial electro-optic (EO) crystal, and we have not found any relative reports so far. Because the artificial synthetic cBN wafers are very small and hard, the wafers cannot be cut into rectangular slabs. The polarizer-sample-λ/4 retardation plate (compensator)-analyzer (PSCA) transverse EO modulator has to be adjusted to the minute irregular octahedron of cBN wafers. When the applied voltage is along [1 1 1] direction of the wafer, due to refraction, the angle between the incident beam direction and the (1 1 1) plane (top or bottom plane) of the wafer should be 25.4°, and the angle between the polarization direction of the polarizer and the plane of incidence should be 50.8° by calculation, respectively. The half-wave voltage of the cBN sample was obtained for the first time, by means of detection of the output optic signals from the modulator with and without an applied electric field on the sample, respectively. Furthermore, the linear EO coefficient was obtained, . The analysis of the experimental resulting error was carried out.     

An augmented Lagrangian method for optimization problems with structured geometric constraints

This paper is devoted to the theoretical and numerical investigation of an augmented Lagrangian method for the solution of optimization problems with geometric constraints. Specifically, we study situations where parts of the constraints are nonconvex and possibly complicated, but allow for a fast computation of projections onto this nonconvex set. Typical problem classes which satisfy this requirement are optimization problems with disjunctive constraints (like complementarity or cardinality constraints) as well as optimization problems over sets of matrices which have to satisfy additional rank constraints. The key idea behind our method is to keep these complicated constraints explicitly in the constraints and to penalize only the remaining constraints by an augmented Lagrangian function. The resulting subproblems are then solved with the aid of a problem-tailored nonmonotone projected gradient method. The corresponding convergence theory allows for an inexact solution of these subproblems. Nevertheless, the overall algorithm computes so-called Mordukhovich-stationary points of the original problem under a mild asymptotic regularity condition, which is generally weaker than most of the respective available problem-tailored constraint qualifications. Extensive numerical experiments addressing complementarity- and cardinality-constrained optimization problems as well as a semidefinite reformulation of MAXCUT problems visualize the power of our approach.

     

Cauchy problems for Hilfer fractional evolution equations on an infinite interval

It is well known that the classical Ascoli-Arzelà theorem is powerful technique to give a necessary and sufficient condition for investigating the relative compactness of a family of abstract continuous functions, while it is limited to finite compact interval. In this paper, we shall generalize the Ascoli-Arzelà theorem on an infinite interval. As its application, we investigate an initial value problem for fractional evolution equations on infinite interval in the sense of Hilfer type, which is a generalization of both Riemann-Liuoville and Caputo fractional derivatives. Our methods are based on the Hausdorff theorem, classical/generalized Ascoli-Arzelà theorem, Schauder fixed point theorem, Wright function, and Kuratowski measure of noncompactness. We obtain the existence of mild solutions on an infinite interval when the semigroup is compact as well as noncompact.