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871.
Jie‐Lian Han Ying Qin Cheng‐Wei Ju Dongbing Zhao 《Angewandte Chemie (International ed. in English)》2020,59(16):6555-6560
Organosilicon compounds have been extensively utilized both in industry and academia. Studies on the syntheses of diverse organosilanes is highly appealing. Through‐space metal/hydrogen shifts allow functionalization of C?H bonds at a remote site, which are otherwise difficult to achieve. However, until now, an aryl to alkyl 1,5‐palladium migration process seems to have not been presented. Reported herein is the remote olefination, arylation, and borylation of a methyl group on silicon to access diverse vinyl‐, benzyl‐, and borylsilanes, constituting a unique C(sp3)?H transformation based on a 1,5‐palladium migration process. 相似文献
872.
Wang C. Cheng S. Y. Zhao W. W. Yang X. N. Zhou K. Z. Tian J. J. Jiang D. F. Ma P. H. 《Crystallography Reports》2020,65(7):1156-1160
Crystallography Reports - This paper reports on the supramolecular self-assembly of cyclopentano cucurbit[5]uril (CyP5Q[5]), L-phenylalanine (L-Phe), and cadmium ions. The crystal structure is... 相似文献
873.
The processes of electric ion extraction from plasma induced by pulse lasers are simulated by particle-in-cell(PIC)method and hybrid-PIC method.A new calculation scheme named preprocessing hybrid-PIC is presented because neither of the two methods above is omnipotent,especially under the circumstance of high initial plasma density.The new scheme provides credible results with less computational consumption than PIC method in both one-and two-dimensional simulations,except forΠ-type electrode configuration.The simulation results show that the M-type performs best in all electrode configurations in both high-density and low-density plasma conditions. 相似文献
874.
875.
Kun Chen Yong Cheng Yongzhi Chang Enqin Li Qing-Long Xu Can Zhang Xiaoan Wen Hongbin Sun 《Tetrahedron》2018,74(4):483-489
N-Substituted-3(10H)-acridones have been established as visible-light organic photocatalyst. These photosensitizers are efficient for oxidative coupling reaction of N-aryl tetrahydroisoquinolines with various nucleophiles. Notably, N-methyl-3(10H)-acridone (Ia) is stable and can be effectively prepared. It is a water-soluble and atom-economic catalyst, and thus holds promise for green chemical applications. Mechanistic studies confirm a single electron transfer (SET)-induced radical process and a rate-limiting step. Analysis of the photocatalytic reactivity?structure relationship reveals that the acridones are robust and tunable photosensitizers for photoredox catalysis. 相似文献
876.
The extent to which drugs combine with trypsin is influenced by the interaction of tartrazine and trypsin, which may cause overdose or underdose of drugs. Therefore, the interaction of tartrazine and trypsin is investigated by methods of spectrometry in this paper. The binding rate of tartrazine to trypsin is 80.95–95.71% at 310?K, and Hill’s coefficients are almost 1. The effect of tartrazine on trypsin structure was studied by synchronous and circular dichroism. The results showed that the binding of tartrazine and trypsin induced the conformational change of trypsin, and quenched the endogenous fluorescence in trypsin. The results of molecular docking revealed that tartrazine is located in the catalytic active site of trypsin, and is consistent with that of experimental calculation. 相似文献
877.
Wen-Zhong Zhu Qiu-Yue Lin Mei Lu Rui-Ding Hu Xiao-Liang Zheng Jian-Ping Cheng Yun-Yun Wang 《Journal of fluorescence》2009,19(5):857-866
Three novel complexes [Nd(L)(NO3)(H2O)2]·NO3·2H2O (HL1 = N-pyrimidine norcantharidin acylamide acid, C12H13N3O4; HL2 = N-pyridine norcantharidin acylamide acid, C13H14N2O4; HL3 = N-phenyl norcantharidin acylamide acid, C14H15NO4) were synthesized. HL1, HL2 and HL3 are the ligand of complex(1), complex(2) and complex(3), respectively. Their structures were characterized by elemental analysis, conductivity measurement, infrared spectra and
thermogravimetric analysis. The DNA-binding properties of the complexes have been investigated by fluorescence spectroscopy
and viscosity measurements. The results suggest that the complexes can bind to DNA by partial intercalation. The liner Stern-Volmer
quenching constant Ksq values are 3.3(±0.21)(1), 1.7(±0.19)(2) and 0.9(±0.04)(3), respectively. Complex (1) and (2) have been found to cleave pBR322 plasmid DNA at physiological pH and temperature. The test of antiproliferation activity
indicates that complex(1) has strong antiproliferative ability against the SMMC7721 (IC50 = 131.7 ± 23.4 μmol·L−1) and A549 (IC50 = 128.4 ± 19.9 μmol·L−1) cell lines. The inhibition rates of complex(2) (IC50 = 86.3 ± 11.3 μmol·L−1) are much higher than that of NCTD (IC50 = 115.5 ± 9.5 μmol·L−1) and HL2 (111.0 ± 5.7 μmol·L−1) against SMMC7721 cell lines. 相似文献
878.
Hai-chao Zhang Peng-fei Zhang Xin-ping Xu Feng Cheng Yu-zhu Wang 《Optics Communications》2009,282(16):3278-3281
Driven by resonance probe light background Rubidium gas can emit fluorescence, which interacts with the falling atomic cloud in the temperature measurement with the time-of-flight (TOF) method and influence the experimental results. The dependencies of the acceleration and the temperature of the atomic cloud on the detuning of the probe beams were studied. We propose that the deviation of the acceleration from the gravity acceleration can be taken as a criterion of the accuracy of the temperature measurement using TOF method. Moreover, using the principle of the radiation force on the cold atomic cloud, one may measure the considerably weak intensity of the fluorescence. 相似文献
879.
Chaos anticontrol of three time scale brushless dc motors and chaos synchronization of different order systems are studied. Nondimensional dynamic equations of three time scale brushless DC motor system are presented. Using numerical results, such as phase diagram, bifurcation diagram, and Lyapunov exponent, periodic and chaotic motions can be observed. By adding constant term, periodic square wave, the periodic triangle wave, the periodic sawtooth wave, and kx|x| term, to achieve anticontrol of chaotic or periodic systems, it is found that more chaotic phenomena of the system can be observed. Then, by coupled terms and linearization of error dynamics, we obtain the partial synchronization of two different order systems, i.e. brushless DC motor system and rate gyroscope system. 相似文献
880.
Cheng Gan-Zhen 《International Journal of Infrared and Millimeter Waves》1986,7(3):379-390
In this paper the theory of FEL operation in a longitudinal uniform magnetic field integrated with a synchronous precessing electro-magnetic field is expounded in view of the main problems in FEL development. A new energy compensation method is suggested as a new way and basis for the development of FEL research. 相似文献