Synthesis of tetrasubstituted thiophenes from pyridinium 1,4-zwitterionic thiolates and modified activated alkynes

Pyridinium 1,4-zwitterionic thiolates were applied to a formal [3 + 2] annulation reaction with modified activated alkynes, affording various tetrasubstituted thiophenes with aryl, alkenyl, alkyl or silyl group at the special position. The structural modification of alkyne substrates enabled the synthesis of diverse thiophenes to be achieved using the pyridinium 1,4-zwitterionic thiolates as the sulfur-containing building blocks. This approach is metal-free and catalyst-free.     

On the two methods of kinetic theory of ECRM

The kinetic theory based on the expansion of local field in the guiding center coordinate system, presented by paper[1]–[3], has successfully developed into a theoretical system. The mathematical background and physical explanation of setting up the guiding center coordinate system is expounded in the paper. By using the methods of the guiding center and waveguide coordinate systems respectively, the same dispersion equations for interaction of an axially symmetrical single momentum electron beam with TE_mn field in the circular waveguide are rigorously derived. A number of mistakes in paper[4] are indicated as well.     

Excited states in126Ba

The K=3/2 ₁ ^T rotational band has been identified in⁹⁹Y with a band-head energy of 536 keV. This result is in contradiction with previously reported data, but is in agreement with predictions of the IBFM/PTQM model.     

Continuum regularization of gauge theory with fermions

The covariant-derivative regularization program is discussed ford-dimensional gauge theory coupled to fermions in an arbitrary representation.     

硅薄膜沉积过程中等离子发光基团的一维空间分布研究

使用光发射谱(OES)对甚高频等离子增强化学气相沉积(VHF-PECVD)技术沉积硅薄膜时的等离子体发光基团的空间分布进行了在线监测和研究. 研究表明：等离子体的不同发光基团都存在着一个中间强度较大的区域和两边电极附近的暗区;增大硅烷浓度和提高辉光功率都会增大SiH^*峰强度;硼烷的加入,使得SiH^*和Hα^*峰强度增大,但硼烷流量变化的影响很小;硼烷流量增大,材料的晶化率下降,而I_{［Hα^*］关键词： 甚高频等离子增强化学气相沉积 等离子体 发光基团 空间分布}     

声表面波MIM隧道发光二极管

我们在研究MIM隧道发光结(金属-绝缘层-金属)的过程中,首次以表面声波代替表面随机粗糙度的作用,将MIM结制作在声表面波场中,结果使结的发光效率、发光强度、稳定性、均匀性都有改善.本文介绍了结的基本结构,基本工艺,阐明了结的发光机理,讨论了结的Ⅰ-Ⅴ特性曲线和光谱曲线,根据结具有显著的负阻现象,我们设计出了一种新型的开关器件.     

激光等离子体能量角分布及吸收定标律

主要研究激光平面靶等离子体发射能量角分布及吸收定标律。实验利用高斯型1.06μm激光脉冲,其能量为2～50J,脉冲宽度为0.3～2.2ns,靶面平均辐照强度为1.8×1013～1.1x10~(15)W/cm~2,光束以25°角入射。实验采用了Au、Ag、Ti、Al和C_8H_8等厚靶。用等离子体卡计测量靶面吸收的激光能量。用指数函数拟合实验数据,给出了吸收效率分别作为激光强度、脉冲宽度和靶材料原子序数的函数的定标关系式。这些关系式定性地与逆轫致吸收的理论关系式相一致。     

类He的Y离子双电子复合计算

采用准相对论的多组态Hartree-Fock(HFR)方法计算了类Li的Y离子(Z=39)的能级和振子强度,并且通过采用扭曲波方法计算自由电子的波函数,我们得到了由类He的基态到类Li的双激发态的自电离几率和双电子复合系数。在计算中,相对论质量—速度和Darwin修正都包含在哈密顿中。为了便于等离子体细致能级占据数密度的动力学计算,我们用一个解析表达式来表示作为自由电子温度函数的双电子复合速率系数,这个表达式精确地描写了从类He的基态到类Li的单激发态的双电子复合。