Long pulse duration of the UV laser with a multi-reflected cavity: Experiment and modeling

The long pulse operation of ultraviolet (UV) laser attributed to multi-reflection is presented on an acousto-optic (AO) Q-switched ultraviolet laser system blocking green light inside a cavity. The ultraviolet laser with the highest average power of 456 mW is obtained with 20 kHz repetition-rate. The numerical simulation of UV pulse broadening was studied using Gaussian curve approximation. The conclusion suggests that the short multi-reflected cavity and high incident pump power will be beneficial to alleviate the width broadening effect. The results, for the first time, would provide the technology for controlling the pulse width of an AO Q-switched DUV laser.     

赤铁矿和三羟铝石吸附Cu~(2+)的红外光谱研究

应用红外光谱法,研究了不同pH值和Cu2+浓度条件下,合成赤铁矿和三羟铝石吸附Cu2+后表面羟基结构及其特征吸收峰的变化。结果表明:(1)随Cu2+浓度增加,赤铁矿表面H—O—H和OH的变形振动参与了吸附反应,Cu2+强烈地缔结在Fe—O上,形成了Fe—O—(Cu)结构。(2)酸性条件下,H+破坏了赤铁矿表面的O—H结构,NO3-促使弱峰1 131 cm-1的产生。随pH值增大,赤铁矿表面OH-逐渐由伸缩振动转变为变形振动,Fe—OH和Fe3+—O2-结构不断发生改变。(3)三羟铝石对Cu2+的吸附发生在高波位,随Cu2+浓度增大,其表面游离羟基的O—H弯曲振动、水分子的OH-伸缩振动和H—O—H弯曲振动均参与了吸附反应,Al—O基中的Al3+渐被Cu2+取代从而加强了较低波位的振动强度。(4)随pH值增加,三羟铝石Al—OH的弯曲振动和Al—O的伸缩振动逐渐发生着改变,表明吸附Cu2+后,在其表面形成了AlOCu+与AlOCuOH结构。     

基于均值置信区间带的高光谱特征波段选择与树种识别

以柏木、雷竹和无患子野外高光谱数据为基础,在统计学理论和实践分析的基础上,提出了利用均值置信区间带筛选树种间最佳特征区分波段及利用Manhattan距离和Min-Max区间相似度识别树种的问题。研究结果表明:(1)柏木与雷竹之间的最佳区分波段为358～386,452～1 145和1 314～2 500 nm,柏木与无患子之间的最佳区分波段为350～446,497～527,553～1 330,1 355～2 400和2 436～2 500 nm,雷竹与无患子之间的最佳区分波段为434～555,580～1 903,1 914～2 089,2 172～2 457和2 475～2 500 nm;(2)在最佳区分波段内,同种树种间的Manhattan距离远小于异种树种间的Manhattan距离,同种树种间的Min～Max区间相似度远大于异种树种间的Min～Max区间相似度,Manhattan距离和Min～Max区间相似度可以有效区分和识别不同类型的树种。     

对巯基苯胺分子表面增强拉曼光谱的密度泛函理论研究

采用密度泛函理论(density functional theory,DFT),在B3LYP/6-31++-G** (C,H,N,S)/LANL2DZ(Ag)水平上,对对巯基苯胺(p-aminothiophenol,PATP)分子进行了几何结构优化,计算了 PATP的常规拉曼散射(normal Raman scatte...     

Beam controller using nonlinear embedded optical transformation

Flexible and adjustable beam splitters, expanders/compressors and the cloak are presented based on a universal two-dimensional transformation formula for the embedded transformation optics. Nonlinear transformation results by the suggested formula under different conditions reveal several interesting phenomena and potential applications. All beam controllers are achieved by the nonlinear coordinate transformation.     

Influence of thermal annealing duration of buffer layer on the crystalline quality of In0.82Ga0.18As grown on InP substrate by LP-MOCVD

In_0.82Ga_0.18As epilayers were grown on InP substrates using a two-step growth technique by LP-MOCVD. A homogeneous low-temperature (450 °C) In_0.82Ga_0.18As buffer layer was introduced to improve the crystalline quality of epilayers. The influence of low-temperature buffer layer deposition condition, such as thermal annealing duration, on the crystalline quality of the In_0.82Ga_0.18As epilayer was investigated. Double-crystal X-ray diffraction measurement, Hall measurement, and Raman scattering spectrum were used to evaluate the In_0.82Ga_0.18As epilayers. Atomic force microscope was used to study the surface morphology. It is found that the In_0.82Ga_0.18As epilayer, with buffer layer thermal annealing for 5 min, exhibits the best crystalline quality. The change of the surface morphology of the buffer layer after thermal annealing treatment was suggested to explain the phenomenon.     

Photonic gap vanishing in one-dimensional photonic crystals with single-negative metamaterials

The properties of photonic band gap in one-dimensional photonic crystals composed of single-negative metamaterials are studied theoretically. Our study shows that the photonic gap will vanish at a certain incident angle when both the phase-match and impedance-match conditions are satisfied simultaneously, suggesting that the bandwidth and location of the photonic gap are strongly dependent on the incident angle and polarization. However, the photonic gap will not vanish and may become insensitive to the incident angle when the two match conditions cannot be met. Our study also shows that losses in metamaterials have little effect on the properties of the photonic gap.     

亚波长金属线栅的设计、制备及偏振成像实验研究

针对红外偏振成像系统,运用等效介质理论,在氟化钙基底上设计了周期为200 nm,深度为100 nm的金属铝栅.模拟计算结果表明,设计的金属铝栅在中红外(3—5 μm)和远红外(8—12 μm)双波段范围内,以及±20°的视场范围内能够提供大于35dB的消光比.利用电子束曝光、反应离子束刻蚀、等离子去胶等工艺完成了金属铝栅的制作.将金属铝栅放在中波红外热像仪前,得到了目标轮廓清晰的偏振图像. 关键词： 亚波长衍射光栅 偏振成像 等效介质理论     

Z箍缩驱动器与丝阵负载耦合特性研究

以丝阵内爆零维模型为基础,采用Pspice模拟行为建模方法,建立了丝阵内爆动态电感与Z箍缩驱动器耦合的全电路模型,实现驱动器放电过程与丝阵内爆过程的自洽求解,并研究了丝阵参数、电路参数对内爆过程的影响.结果表明:丝阵负载与驱动器存在强耦合关系,丝阵参数、电路参数对丝阵峰值箍缩电流、内爆时间、内爆动能影响很大;在驱动器参数不变,内爆时间不超过电路固有放电周期1/4的前提下,峰值箍缩电流、内爆时间、内爆动能随丝阵质量的增加而增大,内爆时间随丝阵初始半径的增加而增大;在丝阵参数不变时,随着驱动器等效电容的增大,内爆时间减小,丝阵内爆动能增大,但驱动器储能转化为内爆动能的效率却先增大后减小.对于特定的驱动器,优化的丝阵参数应使内爆过程充分利用驱动器固有放电周期的上升沿,使丝阵快速收缩的时间起点接近电路固有放电周期的四分之一,以获得最大的动能效率. 关键词： Z箍缩驱动器 零维内爆模型 模拟行为建模 耦合特性     

紫外可见光谱的水产养殖水体有机物浓度快速检测研究

应用紫外可见（ultraviolet/visible,UV/Vis）光谱技术对表征水产养殖水体中有机物浓度的指标化学需氧量（chemical oxygen demand,COD）进行快速测量,对采集到的135份甲鱼养殖水样进行UV/Vis波段全光谱扫描,采用无信息变量消除（uninformative variable elimination,UVE）和连续投影算法（successive projections algorithm,SPA）相结合的变量选择算法选取全波段光谱中的特征波长,从201个UV/Vis光谱变量中选取了7个特征波长,只占全波段光谱变量的3.48%,降低了建模的时间和模型的复杂度。结合最小二乘支持向量机（least-square support vector machine,LS-SVM）算法进行COD预测建模,结果表明：使用特征波长建模的预测效果（相关系数r（correlation coefficient）=0.89,预测均方根误差（root mean square error of prediction,RMSEP）=15.46 mg·L-1）好于使用全波段光谱建模的预测效果（r=0.88,RMSEP = 15.71 mg·L-1）。使用UVE-SPA变量选择算法获取UV/Vis光谱特征波长,结合LS-SVM建模,可以快速、准确的测量水产养殖水体中的COD浓度,为进一步实现水产养殖水质的在线检测以及其他水质参数的快速测定奠定了基础。