Synthesis and transition temperatures of liquid crystals incorporating a 1,4-tetrafluorophenylene unit

Two homologous series of mesogenic materials which incorporate a 1,4-tetrafluorophenylene moiety and a terminal cyano- or nitro-substituent have been synthesized by using palladiumcatalysed coupling procedures. The compounds exhibit nematic and/or smectic A phases.     

First observation of yrast band in odd-odd162Lu

High spin states of the odd-odd¹⁶²Lu nucleus have been studied via¹⁴⁷Sm(¹⁹F,4nγ)¹⁶²Lu reaction at 95 MeV beam energy. Level scheme for yrast band based onπ[h_11/2 v[i_13/2] quasiparticle configuration was established up to I ^π = (23^?) for the first time. This band shows the signature inversion in energy before backbending generally appeared in this mass region. It is stressed that the signature splitting in¹⁶²Lu is larger than that in the¹⁶⁰Tm nucleus.     

CsBr高压X光研究

 采用同步辐射X光源和能散法，对CsBr粉末样品进行高压原位X光衍射实验。由金刚石对顶压砧高压装置（DAC）产生高压，用已知状态方程的Pt粉末作内标，由Pt的衍射数据确定样品压力，最高压力达64.4 GPa。实验结果表明：室温常压下原始CsBr样品是具有简单立方结构的晶体，其晶格常数α＝0.428 5 nm。高压下CsBr的结构有所变化，在51.3~58.4 GPa的压力范围内，(110)线和(211)线发生劈裂，从而形成了四方相。     

双（十二烷基亚磺酰）乙烷溶剂萃取钯及其机理的研究

本文研究用双（十二烷基亚磺酰）乙烷萃取钯的性能，在ＫＩ存在下从７ｍｏｌ／Ｌ盐酸介质中用含有ＢＤＳＥ的氯仿能定量萃取钯，有机的钯可被硫脲或氨溶液反萃继之用ＴＭＫ－ＴｒｉｔｏｎＸ－１００光度法测定，研究了萃取的最佳条件及干扰情况，斜率法测得萃合物组成为Ｐｄ：Ｉ：ＢＤＳＥ＝１：２：１，红外光谱证实萃合物中ＢＤＳＥ的二个亚砜以硫原子与钯配位，萃合物为异位体络合物，提出了选择性萃取分离钯的新方法。     

ICP－AES同时测定土壤和沉积物中全硼与其它微量及常量元素

本文阐述了用Ｈ３ＰＯ４、ＨＦ、ＨＮＯ３及ＨＣｌＯ４消化土壤及水系沉积物样品。其中磷酸的作用是避免在样品消化过程中硼的挥发损失。应用电感耦合等离子体发射光谱（简称ＩＣＰ－ＡＥＳ）同时测定样品中全硼及其它微量、常量元素的含量。该法具有高的准确度及精密度。方法快速、简便、适合土壤和沉积物的多元素测定。     

Determination of low level85Kr and133Xe concentrations in the environment

This study was performed under the joint TRMC/INER program for the determination of low level⁸⁵Kr and¹³³Xe concentrations in the environmental air samples. Based on cryogenic adsorption of krypton and xenon on charcoal followed by chromatographic separation from other gases, the⁸⁵Kr and¹³³Xe recovered from 200 liters of atmospheric air can be determined by either on-line gas flow proportional counter or liquid scintillation counting. The recovery yields of krypton and xenon examined by using⁸⁵Kr and¹³³Xe tracers were nearly 100%. The minimum detectable activity of⁸⁵Kr and¹³³Xe by gas flow proportional counting is about 7.40 Bq. The method is satisfactory for environmental monitoring applications under abnormal conditions of nuclear facilities. However, for lower level environmental⁸⁵Kr and¹³³Xe measurements, the liquid scintillation counting method can be applied due to their extremely low detection limits (i.e. 0.107 Bq and 0.093 Bq for⁸⁵Kr and¹³³Xe, respectively). Using this method, the measurable limits of concentrations are 0.535 Bq/m³ and 0.466 Bq/m³ for⁸⁵Kr and¹³³Xe, respectively.     

酞菁钴薄膜的折射率及吸收特性

通过真空镀法在单晶硅片上制备了酞菁钴薄膜，在波长扫描和入射角可变全自动椭圆偏振光谱仪上研究了ＣｏＰｃ薄膜的椭偏光谱并分析了其电子结构。     

再论q^—图

本文在文[1]的基础上,讨论了没有q-割团、但有(q+1)-割团且q-色唯一的q-图的结构。     

等径管道的三维重建

由轮廓线重建物体的现有方法，不能准确地恢复原有管道的形状．本文提出了一种等径管道的三维重建方法，能较为准确地恢复原管道的三维结构．     

德摩根拓扑代数上的紧性与q—收敛性

在文（１），（２），（３）的基础上，我们首先在德摩根拓扑代数上用有限覆盖性质定义了紧性，并引入ω－元，ω－ｄ－ｑ－聚点等概念，并着重讨论了紧性与ｑ－收敛性之间的关系。