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91.
Double-diffusive convection due to a cylindrical source submerged in a salt-stratified solution is numerically investigated
in this study. For proper simulation of the vortex generated around the cylinder, a computational domain with irregular shape
is employed. Flow conditions depend strongly on the thermal Rayleigh number, Ra
T
, and the buoyancy ratio, R
ρ. There are two types of onset of instability existing in the flow field. Both types are due to either the interaction of
the upward temperature gradient and downward salinity gradient or the interaction of the lateral temperature gradient and
downward salinity gradient. The onset of layer instability due to plume convection is due to the former, whereas, the onset
of layer instability of layers around the cylinder is due to the latter. Both types can be found in the flow field. The transport
mechanism of layers at the top of the basic plume belongs to former while that due to basic plume and layer around the cylinder
are the latter. The increase in Ra
T
reinforces the plume convection and reduces the layer numbers generated around the cylinder for the same buoyancy ratio.
For the same Ra
T
, the increase of R
ρ suppresses the plume convection but reinforces the layers generated around the cylinder. The profiles of local Nusselt number
reflects the heat transfer characteristics of plume convection and layered structure. The profiles of averaged Nusselt number
are between the pure conduction and natural convection modes and the variation is due to the evolution of layers.
Received on 13 September 1996 相似文献
92.
M.-K. Chen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(1):13-18
We examine the influence of relativistic and QED effects on the existence of the 1,3P
o
H- resonances between n
= 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet
states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths
of fifteen 1P
o
resonances, and fifteen 3P
o
resonances. The fifteen 1P
o
resonances are classified to be
3
(2, 0)
-
n
( 4 ?
n
? 12) and
3
(1, 1)
+
n
( 3 ?
n
? 8). The fifteen 3P
o
resonances are classified to be
3
(2, 0)
+
n
( 3 ?
n
? 12) and
3
(1, 1)
-
n
( 4 ?
n
? 8). We found there exist six Feshbach resonances for
3
(2, 0)
-
n
(1P
o
) series, four Feshbach resonances for
3
(1, 1)
+
n
(1P
o
) series, seven Feshbach resonances for
3
(2, 0)
+
n
(3P
o
) series, and three Feshbach resonances for
3
(1, 1)
-
n
(1P
o
) series.
Received 22 February 2002 Published online 24 September 2002 相似文献
93.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007 相似文献
94.
Browder-Petryshyn 型的严格伪压缩映射的粘滞迭代逼近方法 总被引:1,自引:0,他引:1
主要研究Browder-Petryshyn型的严格伪压缩映射的粘滞迭代逼近过程,证明了Browder-Petryshyn型的严格伪压缩映射的不动点集F(T)是闭凸集.在q-一致光滑且一致凸的Banach空间中,对于严格伪压缩映射T,利用徐洪坤在2004年引进的粘滞迭代得到的序列弱收敛于T的某个不动点.同时证明了Hilbert空间中Browder-Petryshyn型的严格伪压缩映射的相应迭代序列强收敛到T的某个不动点,其结果推广与改进了徐洪坤2004年的相应结果. 相似文献
95.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
96.
Chii-Wann Lin Kuo-Ping Chen Ming-Chii Su Chih-Kung Lee Chih-Chung Yang 《Optical and Quantum Electronics》2005,37(13-15):1423-1437
We have reported a novel design of surface plasmon resonance (SPR) device, which uses alternating dielectric layers to enhance the SPR signal quality and modulate its resonant position. Admittance loci method of thin film design has been used in the design of such a device. The use of biomolecular thin film, such as DNAs or Porteins, in this design can result in resonant condition of wavelength changes as well. Bio-plasmonics is proposed for the research and development of novel devices, which use biomolecules as a part of the plasmon oscillation system to actively interact with nano/micro structure. 相似文献
97.
Daria E. Lonsdale Geoffrey Johnston‐Hall Amanda Fawcett Craig A. Bell Carl N. Urbani Michael R. Whittaker Michael J. Monteiro 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3620-3625
In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (Ctrs) determined using the Mayo method is equal to 3.8 × 10?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the Mn data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007 相似文献
98.
J‐F. Masson Slaana Bundalo‐Perc Ana Delgado 《Journal of Polymer Science.Polymer Physics》2005,43(3):276-279
Differential scanning calorimetry (DSC) does not allow for easy determination of the glass‐transition temperature (Tg) of the polystyrene (PS) block in styrene–butadiene–styrene (SBS) block copolymers. Modulated DSC (MDSC), which deconvolutes the standard DSC signal into reversing and nonreversing signals, was used to determine the (Tg) of both the polybutadiene (PB) and PS blocks in SBS. The Tg of the PB block was sharp, at ?92 °C, but that for the PS blocks was extremely broad, from ?60 to 125 °C with a maximum at 68 °C because of blending with PB. PS blocks were found only to exist in a mixed PS–PB phase. This concurred with the results from dynamic mechanical analysis. Annealing did not allow for a segregation of the PS blocks into a pure phase, but allowed for the segregation of the mixed phase into two mixed phases, one that was PB‐rich and the other that was PS‐rich. It is concluded that three phases coexist in SBS: PB, PB‐rich, and PS‐rich phases. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 276–279, 2005 相似文献
99.
Masaharu Asano Jinhua Chen Yasunari Maekawa Takahiro Sakamura Hitoshi Kubota Masaru Yoshida 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2624-2637
A novel process comprising the UV‐induced photografting of styrene into poly(tetrafluoroethylene) (PTFE) films and subsequent sulfonation has been developed for preparing proton‐conducting membranes. Although under UV irradiation the initial radicals were mainly generated on the surface of the PTFE films by the action of photosensitizers such as xanthone and benzoyl peroxide, the graft chains were readily propagated into the PTFE films. The sulfonation of the grafted films was performed in a chlorosulfonic acid solution. Fourier transform infrared and scanning electron microscopy were used to characterize the grafted and sulfonated membranes. With a view to use in fuel cells, the proton conductivity, water uptake, and mechanical properties of the prepared membranes were measured. Even through the degree of grafting was lower than 10%, the proton conductivity in the thickness direction of the newly prepared membranes could reach a value similar to that of a Nafion membrane. In comparison with γ‐ray radiation grafting, UV‐induced photografting is very simple and safe and is less damaging to the membranes because significant degradation of the PTFE main chains can be avoided. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2624–2637, 2007 相似文献
100.
本文对近20年来多复变函数的一个发展迅速的数学热门分支-逆紧映照作了一个回顾和整理。这是作者继续从事此方向研究的先声,也希望本文能为有志于此的研究者提供一些便利。本文从经典的结果开始,通过对逆紧映照在边界上的开拓及分支点的分布的讨论,详细地阐述了这些年来关于逆紧映照何时成为双全纯映照的若干结果。最后,对近年来关于逆紧映照另外的一些工作进行了简单的介绍。 相似文献