全文获取类型
收费全文 | 172篇 |
免费 | 7篇 |
专业分类
化学 | 143篇 |
数学 | 3篇 |
物理学 | 33篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 2篇 |
2012年 | 6篇 |
2011年 | 16篇 |
2010年 | 8篇 |
2009年 | 3篇 |
2008年 | 9篇 |
2007年 | 6篇 |
2006年 | 7篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 4篇 |
2002年 | 17篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有179条查询结果,搜索用时 15 毫秒
11.
Forster PM Burbank AR Livage C Férey G Cheetham AK 《Chemical communications (Cambridge, England)》2004,(4):368-369
Five different cobalt succinate materials synthesized from an identical starting mixture using temperature as the only independent variable show increasing condensation and density at higher synthesis temperatures. 相似文献
12.
Min Liu Mike Ronk Da Ren Judy Ostovic Nina Cauchon Zhaohui Sunny Zhou Janet Cheetham 《Journal of chromatography. A》2010,1217(22):3598-3611
A hydrophilic interaction liquid chromatography (HILIC) method was used to separate a commonly used pharmaceutical starting material, 4-aminomethylpyridine (4-AMP), and its degradants. The structures of the major degradants were characterized and elucidated without prior isolation by accurate mass measurement, MS/MS analysis and on-line hydrogen/deuterium (H/D) exchange experiments. The mass spectra obtained from H/D exchange experiments are particularly useful to differentiate structural isomers, to elucidate the fragmentation pathways, and to aid in structure elucidation in the absence of MS/MS fragmentation information. The impact of deuterium oxide and temperature on HILIC separation has also been explored here. The integration of H/D exchange with HILIC has been described here for the first time and has been demonstrated to be a powerful structure elucidation tool via the study of degradants in 4-AMP. 相似文献
13.
Paul J. Saines Dr. Brent C. Melot Ram Seshadri Prof. Anthony K. Cheetham Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(25):7579-7585
An anhydrous manganese succinate, Mn(C4H4O4), has been synthesised hydrothermally and studied by single‐crystal X‐ray diffraction. It adopts a succinate pillared structure in which layers of corner‐sharing MnO6 octahedra alternate with sheets that contain chains of edge‐sharing octahedra. This unique 3D framework structure contains highly distorted MnO6 octahedra, which are made possible by the lack of ligand field stabilisation energy for the high‐spin Mn2+ ion. Attempts to dope the structure with other divalent transition‐metal ions were accordingly unsuccessful. Magnetic susceptibility and heat capacity measurements indicate that Mn(C4H4O4) undergoes antiferromagnetic ordering below 12 K, with a second antiferromagnetic transition at approximately 6 K. These two antiferromagnetic phases undergo further transitions in applied fields, underlining the subtle magnetic behaviour that is possible in inorganic–organic frameworks of this structural complexity. 相似文献
14.
15.
16.
17.
The mechanical properties of hybrid framework materials, including both nanoporous metal-organic frameworks (MOFs) and dense inorganic-organic frameworks, are discussed in this critical review. Although there are relatively few studies of this kind in the literature, major recent advances in this area are beginning to shed light on the fundamental structure-mechanical property relationships. Indeed research into the mechanical behavior of this important new class of solid-state materials is central to the design and optimal performance of a multitude of technological applications envisaged. In this review, we examine the elasticity of hybrid frameworks by considering their Young's modulus, Poisson's ratio, bulk modulus and shear modulus. This is followed by discussions of their hardness, plasticity, yield strength and fracture behavior. Our focus is on both experimental and computational approaches. Experimental work on single crystals and amorphized monoliths involved primarily the application of nanoindentation and atomic force microscopy to determine the elastic moduli and hardness properties. The compressibility and bulk moduli of single crystals and polycrystalline powders were studied by high-pressure X-ray crystallography in the diamond anvil cell, while in one instance spectroscopic ellipsometry has also been used to estimate the elastic moduli of MOF nanoparticles and deposited films. Theoretical studies, on the other hand, encompassed the application of first principles density-functional calculations and finite-temperature molecular dynamics simulations. Finally, by virtue of the diverse mechanical properties achievable in hybrid framework materials, we propose that a new domain be established in the materials selection map to define this emerging class of materials (137 references). 相似文献
18.
Cheetham AK 《Angewandte Chemie (International ed. in English)》2011,50(16):3596-3598
19.
Furman JD Melot BC Teat SJ Mikhailovsky AA Cheetham AK 《Physical chemistry chemical physics : PCCP》2011,13(17):7622-7629
Three novel inorganic-organic framework compounds containing the organic chromophore ligand 9-fluorenone-2,7-dicarboxylic acid (abbreviated H(2)FDC) and barium (BaFDC), cadmium (CdFDC) and manganese (MnFDC), respectively, have been synthesized and evaluated for their use as phosphor materials for solid state lighting and other applications. The results are compared with two earlier reported structures containing the same ligand with calcium (CaFDC) and strontium (SrFDC). The barium- and cadmium-containing compounds both show blue excited, yellow photoluminescence, while the manganese structure does not. The trends in luminescent efficiency for the Ba, Cd, Ca, and Sr derivatives are discussed in relation to crystallographic, optical, and low-temperature specific heat considerations. 相似文献
20.
Study of magnetoresistance and conductance of bicrystal grain boundary in La0.67Ba0.33MnO3 thin film
La0.67Ba0.33MnO3 (LBMO) thin film is deposited on a 36.7°C SrTiO3 bicrystal substrate using laser ablation technique. A microbridge is created across bicrystal grain boundary and its characteristics
are compared with a microbridge on the LBMO film having no grain boundary. Presence of grain boundary exhibits substantial
magnetoresistance ratio (MRR) in the low field and low temperature region. Bicrystal grain boundary contribution in MRR disappears
at temperature T>175 K. At low temperature, I-V characteristic of the microbridge across bicrystal grain boundary is nonlinear. Analysis of temperature dependence of dynamic
conductance-voltage characteristics of the bicrystal grain boundary indicates that at low temperatures (T<175 K) carrier transport across the grain boundary in LBMO film is dominated by inelastic tunneling via pairs of manganese
atoms and tunneling through disordered oxides. At higher temperatures (T>175 K), magnetic scattering process is dominating. Decrease of bicrystal grain boundary contribution in magnetoresistance
with the increase in temperature is due to enhanced spin-flip scattering process. 相似文献