Instant nano-hydroxyapatite: a continuous and rapid hydrothermal synthesis

Nano-particle hydroxyapatite (HA) rods, were rapidly synthesised using a three pump continuous hydrothermal process (using a water feed at up to 400 degrees C and at 24 MPa): the product was obtained as a highly crystalline and phase pure material, without the need for an ageing step or subsequent heat treatment.     

Analysis of stationary discrete-time GI/D-MSP/1 queue with finite and infinite buffers

This paper considers a single-server queueing model with finite and infinite buffers in which customers arrive according to a discrete-time renewal process. The customers are served one at a time under discrete-time Markovian service process (D-MSP). This service process is similar to the discrete-time Markovian arrival process (D-MAP), where arrivals are replaced with service completions. Using the imbedded Markov chain technique and the matrix-geometric method, we obtain the system-length distribution at a prearrival epoch. We also provide the steady-state system-length distribution at an arbitrary epoch by using the supplementary variable technique and the classical argument based on renewal-theory. The analysis of actual-waiting-time (in the queue) distribution (measured in slots) has also been investigated. Further, we derive the coefficient of correlation of the lagged interdeparture intervals. Moreover, computational experiences with a variety of numerical results in the form of tables and graphs are discussed.     

Luminescence study of cerium-doped La2Hf2O7: Effects due to trivalent and tetravalent cerium and oxygen vacancies

X-ray excited emission spectra, photoluminescence excitation and emission spectra, optical reflectivity spectra, and pulsed X-ray and optical excited luminescence decay measurements are reported for cerium-doped La₂Hf₂O₇ powders prepared by solid state synthesis. A broad luminescence associated with oxygen vacancies is observed in the region 350–750 nm with a peak around 460 nm. The photoluminescence spectra and the number of oxygen vacancies vary for samples annealed in oxidizing or reducing atmospheres and with the temperature of the synthesis process. Increasing the cerium concentration reduces the oxygen-vacancy-related emission due to the presence of Ce⁴⁺. First principles calculations predict that Ce⁴⁺ can substitute in Hf sites; this is confirmed from the optical reflectivity spectrum of cerium-doped La₂Hf₂O₇. Photoluminescence excitation and emission spectra characteristic of Ce⁴⁺ charge transfer transitions and possibly Ce³⁺ are also observed. Although trivalent cerium may be present, no emission observed from cerium-doped La₂Hf₂O₇ can be attributed to Ce³⁺ in La sites.     

ChemInform Abstract: The Ground-State Potential Energy Surface of Diazene

has been studied by using a complete active space MCSCF wave function generated by distributing eight electrons among eight orbitals.