Fabrication of Graphitic Carbon Nitride-Based Film: An Emerged Highly Efficient Catalyst for Direct C-H Arylation under Solar Light

Photoredox C-H bond formation can proceed in aerobic environment under solar light and has therefore become attractive.Nowadays,different types of expensive nov...     

Metal-free decarboxylative acylation of isoquinolines using α-keto acids in water

An efficient method for acylation of isoquinolines has been developed using α-ketoacids under metal- and additive-free conditions in water. The protocol involves C(sp²)H functionalization of isoquinolines providing an easy access to C1-benzoylated isoquinolines, which constitute the core structure of a number of biological active compounds and serve as key intermediate in the synthesis of many alkaloids.     

Zinc ferrite nanoparticles as MRI contrast agents

Mixed spinel hydrophobic ZnxFe1-xO x Fe2O3 (up to x = 0.34) nanoparticles encapsulated in polymeric micelles exhibited increased T2 relaxivity and sensitivity of detection over clinically used Feridex.     

Dye Degradation and Sulfur Oxidation of Methyl Orange and Thiophenol via Newly Designed Nanocomposite GQDs/NiSe-NiO Photocatalyst Under Homemade LED Light

Photocatalytic processes triggered by graphene-based photocatalysts under solar light have sparked interest as a new sort of instrument for solar chemical synthesis. Herein we investigated self-assembled graphene quantum dots (GQDs)/NiSe-NiO composite photocatalyst for organic transformation as well as dye degradation. The synthesized GQDs/NiSe-NiO composite photocatalyst has an excellent suitable band gap, high molar extinction coefficient, low toxicity and chemical/thermal stability. The GQDs/NiSe-NiO composite photocatalyst emerges as a new standard for sulfur oxidation and dye degradation reactions under homemade LED light with high yield.     

SPM induced limitations for 40 Gbps chirped Gaussian pulses in optical channel

An analysis of self-phase modulation (SPM) induced nonlinearities in a 40 Gbps link with chirped Gaussian pulses of different duty cycles has been reported in this paper. In the present analysis only SPM effect has been considered to control the pulse propagation behavior through the fiber by appropriate selection of pulse width, peak power and channel length to suppress the other channel impairments caused by group velocity dispersion (GVD) and third order dispersion (TOD). The effect of SPM on the Q-factor for the transmission of 40 Gbps chirped pulses with different initial pulse widths and input peak powers has been investigated. It has been observed that a wider pulse having maximum negative chirp can withstand the nonlinear effect of SPM for relatively higher ranges of input peak power.     

Bianchi Type-I Universe with wet dark fluid

The Bianchi Type-I Universe filled with dark energy from a wet dark fluid has been considered. A new equation of state for the dark energy component of the Universe has been used. It is modeled on the equation of state p = γ(ρ − ρ*) which can describe a liquid, for example water. The exact solutions to the corresponding field equations are obtained in quadrature form. The solution for constant deceleration parameter have been studied in detail for both power-law and exponential forms. The cases γ = 1 and γ = 0 have also been analysed.      

Estimation of a common mean of several univariate inverse Gaussian populations

The problem of estimating the common mean of k independent and univariate inverse Gaussian populations IG(, _i ), i=1,..., k with unknown and unequal 's is considered. The difficulty with the maximum likelihood estimator of is pointed out, and a natural estimator % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% acciGaf8hVd0MbaGaaaaa!3D38!\[\tilde \mu \] of along the lines of Graybill and Deal is proposed. Various finite sample properties and some decision-theoretic properties of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% acciGaf8hVd0MbaGaaaaa!3D38!\[\tilde \mu \] are discussed.This research was partially supported by research grants #A3661 and #A3450 from NSERC of Canada.     

Immobilization of lactate dehydrogenase on tetraethylorthosilicate-derived sol-gel films for application to lactate biosensor

Tetraethylorthosilicate (TEOS)-derived sol-gel films were utilized for the immobilization of lactate dehydrogenase (LDH) by physical adsorption and sol-gel/LDH/sol-gel sandwich configuration. An attempt was made to ascertain the optimum pH and temperature for the immobilized LDH. It was shown that TEOS-derived sol-gel films containing physically adsorbed LDH exhibited linearity from 0.5 to 4 mM, whereas those containing LDH in sandwich configuration showed linearity from 0.5 to 3 mM l-lactate. These sol-gel films, immobilized with LDH, were found to be stable for about 4 weeks at 4–10°C.     

Cosmic no-hair conjecture in scalar-tensor theories

We have shown that, within the context of scalar-tensor theories, the anisotropic Bianchi-type cosmological models evolve towards de Sitter Universe. A similar result holds in the case of cosmology in Lyra manifold. Thus the analogue of cosmic no-hair theorem of Wald [1] hold in both the cases. In fact, during inflation there is no difference between scalar-tensor theories, Lyra’s manifold and general relativity (GR).