全文获取类型
收费全文 | 961篇 |
免费 | 19篇 |
国内免费 | 1篇 |
专业分类
化学 | 569篇 |
晶体学 | 17篇 |
力学 | 37篇 |
数学 | 49篇 |
物理学 | 309篇 |
出版年
2023年 | 3篇 |
2022年 | 12篇 |
2021年 | 15篇 |
2020年 | 12篇 |
2019年 | 13篇 |
2018年 | 24篇 |
2017年 | 17篇 |
2016年 | 25篇 |
2015年 | 20篇 |
2014年 | 33篇 |
2013年 | 54篇 |
2012年 | 65篇 |
2011年 | 74篇 |
2010年 | 56篇 |
2009年 | 43篇 |
2008年 | 60篇 |
2007年 | 65篇 |
2006年 | 52篇 |
2005年 | 44篇 |
2004年 | 28篇 |
2003年 | 30篇 |
2002年 | 26篇 |
2001年 | 15篇 |
2000年 | 12篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 14篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 12篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1973年 | 3篇 |
1918年 | 2篇 |
排序方式: 共有981条查询结果,搜索用时 15 毫秒
61.
Krishna C. Majumdar Buddhadeb Chattopadhyay Santanu Chakravorty Nilasish Pal Randhir Kumar Sinha 《Tetrahedron letters》2008,49(50):7149-7152
The synthesis and characterization of a homologous series of Schiff bases consisting of an N-methyldiphenylamine moiety as the central core is reported, which exhibits smectic A phase and transitions from the partial bilayer SmAd phase to the bilayer SmA2 phase as the temperature is lowered. 相似文献
62.
Alok Chakrabarty Pradipta Purkayastha Nitin Chattopadhyay 《Journal of photochemistry and photobiology. A, Chemistry》2008,198(2-3):256-261
The cis-skew to trans-planar photoisomerization of benzil in the photoexcited state was studied by laser-induced optoacoustic spectroscopy (LIOAS) in a series of normal alkane solvents at room temperature. The structural volume change due to the photoisomerization process has been estimated and compared with the same calculated from the optimized skew and trans structures. The magnitude of the structural volume change is estimated to be 22.9 ± 1.2 mL/mol. This study reveals that an expansion in volume occurs during the photoinduced isomerization process. In non-polar alkane solvents, the estimated volume change has been argued to be free from electrostrictional contribution. 相似文献
63.
A concise and efficient method for the preparation of oxocine derivatives is described via sequential Wittig and intramolecular Heck reactions. The method is highly regioselective and affords high yields of the products. 相似文献
64.
Transparent and highly conducting thin films of cadmium oxide (CdO) with titanium doping were synthesized by using radio frequency magnetron sputtering technique. The thin films were deposited on glass and silicon substrates with different percentages of titanium at a fixed substrate temperature 473 K and a fixed pressure of 0.1 mbar in Ar atmosphere. The deposited films were characterized by studying their crystallographic structure, optical and electrical properties. X-ray diffractometer, atomic force microscope, UV–Vis–NIR spectrophotometer, and X-ray photoelectron spectrophotometer were used for different characterizations. All the films have a rock-salt structure. A systematic increase in the optical bandgap was found for the CdO thin films with Ti doping, so that it can be considered as a candidate material for different optoelectronic device applications. Electrical conductivity was also found to increase with Ti doping concentration. 相似文献
65.
Soumya Basu Basab Chattopadhyay A. Ganguly P. Chakraborty P. Roy Chowdhury S. Samanta M. Mukherjee A. K. Mukherjee S. K. Choudhuri 《应用有机金属化学》2009,23(12):527-534
A mononuclear copper (II) complex of N‐2‐hydroxyhippuric acid (2HHA), [Cu(HA)(H2O)2], has been synthesized and characterized by spectroscopic and X‐ray powder diffraction studies. Crystal structure of [Cu(HA)(H2O)2] reveals a distorted square‐pyramidal geometry around the metal center. The crystal packing in the complex exhibits a three‐dimensional framework formed by intermolecular O? ; H···O and C? H···O hydrogen bonds. Toxicity and antitumor properties of the complex have been studied in vivo. The complex, capable of depleting glutathione (GSH) at nontoxic doses, may be utilized to sensitize drug‐resistant cells where resistance is due to an elevated level of GSH. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
66.
67.
Surajit Chattopadhyay Ujjal Debnath 《International Journal of Theoretical Physics》2011,50(2):315-324
Purpose of the present paper is to view the correspondence between Ricci and other dark energies. We have considered the Ricci
dark energy in presence of dark matter in non-interacting situation. Subsequently, we have derived the pressure and energy
density for Ricci dark energy. The equation of state parameter has been generated from these pressure and energy density.
Next, we have considered the correspondence between Ricci and other dark energy models, namely tachyonic field, DBI-essence
and new agegraphic dark energy without any interaction and investigated possible cosmological consequences. 相似文献
68.
69.
Tri-state logic plays a significant role in carry free arithmetical operation. Design of all-optical scheme of three basic tri-state logical operation (NOT, AND, OR) with the help of polarization encoded semiconductor optical amplifier (SOA)-assisted Sagnac interferometric switch has been studied and investigated in this present paper. Numerical simulation is also presented, which verifies the theoretical results. Insertion loss, contrast ratio, extinction ratio, amplitude modulation, bit error rate and signal to noise ratio values have also been analyzed. 相似文献
70.
Two-photon absorption(2PA) in zinc sulphide(ZnS) and Mn2+-doped ZnS quantum dots is reported by the z-scan technique,with nanosecond pulsed laser radiation at 355 nm.The observed values of the 2PA cross section of all the samples are 105 times larger than that of bulk ZnS. 相似文献