Structural and photophysical studies of phenanthrene adducts involving C6F5HgCl and [o-C6F4Hg]3

Both pentafluorophenylmercury chloride and trimeric perfluoro-ortho-phenylene mercury interact with phenanthrene to form phosphorescent adducts which exhibit extended binary stacks in the solid state.     

Removing coordinated metal ions from proteins: a fast and mild method in aqueous solution

Thermodynamic and kinetic studies of metal binding to proteins require the investigation of metal-free proteins, which are often difficult to obtain. We have developed a very fast and mild method to eliminate metal ions from proteins by column chromatography using a commercially available Ni-NTA-type stationary phase. This material, initially designed for protein purification purposes in biotechnology, acts as a strong cation chelator when Ni²⁺ ions are removed. We have tested this new method with Ca-ATPase, an integral membrane protein exhibiting a strong affinity for Ca²⁺. By eluting the protein over the Ni²⁺-free NTA gel, we could remove 95% of the total Ca²⁺ and obtain an essentially Ca²⁺-free protein. This method is efficient with only a small amount of NTA gel, and we suggest that it can be applied in general for removal of metal ions from proteins. Moreover, as this procedure can be carried out under mild conditions, the chosen protein kept its enzymatic activity.     

Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+

The cationic cages nido-[C2Bu(t)2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.     

Ruled 4-manifolds and isotopies of symplectic surfaces

We study symplectic surfaces in ruled symplectic 4-manifolds which are disjoint from a given symplectic section. As a consequence, in any symplectic 4-manifold, two homologous symplectic surfaces which are C ⁰ close must be Hamiltonian isotopic.     

Designer Self-Assembling Peptide Materials for Diverse Applications

Summary: Macromolecuar chemistry and polymer science have had an enormous impact in many areas of science, engineering, medicine and our daily life. It has not only changed our way of life forever, but also continuously to improve our living standard. Macromolecuar chemistry now also encompasses bioengineering, biomimetics, designer biological materials and nanobiotechnology. Here we summarize a few classes of short peptides that we discovered and invented with broad applications including 3D tissue cell culture, reparative and regenerative medicine, tissue engineering, slow drug release, stabilization of membrane proteins for develop nanobiotechnology and molecular devices. Molecular design using short peptides as new materials will play increasingly important role in biomedical research, nanobiotechnology, clinical science and medicine.     

Control of defect concentrations within a semiconductor through adsorption

The technologically useful properties of a crystalline solid depend upon the concentration of defects it contains. Here we show that defect concentrations as deep as 0.5 microm within a semiconductor can be profoundly influenced by gas adsorption. Self-diffusion rates within silicon show that nitrogen atoms adsorbed at less than 1% of a monolayer lead to defect concentrations that vary controllably over several orders of magnitude. The results show that previous measurements of diffusion and defect thermodynamics in semiconductors may have suffered from neglect of adsorption effects.     

Exponential Finite Elements for a Phase Field Fracture Model

Sharp interface material models can be related to phase field models by introducing an order parameter, whose value is assigned to the different phases of a material. The elastic material law is coupled to the evolution equation of the order parameter and cracking is addressed as a phase transition problem instead of a moving boundary value problem. A regularization parameter ϵ controls the width of the diffuse cracks represented by the order parameter and the underlying sharp interface model can be recovered from the phase field model by the limit ϵ → 0. However, in numerical simulations using standard finite elements with linear shape functions, the minimum value of ϵ is restricted by the grid size and therefore the discretization of the crack field requires extensive mesh refinement for small values of ϵ. In this work, we construct special 2d shape functions which take into account the exponential character of the crack field and its dependence on the parameter ϵ. Especially in simulations with small values of ϵ and a rather coarse mesh, the elements with exponential shape functions perform significantly better than standard linear elements. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Existence and stability of foliations by <Emphasis Type="Italic">J</Emphasis>-holomorphic spheres

We study the existence and stability of holomorphic foliations in dimension greater than 4 under perturbations of the underlying almost-complex structure. An example is given to show that, unlike in dimension 4, J-holomorphic foliations are not stable under large perturbations of almost-complex structure.     

Stable isotope analysis of white-tailed deer teeth as a paleoenvironmental proxy at the Maya site of La Joyanca,northwestern Petén,Guatemala*

ABSTRACT

Carbon and oxygen isotopes ratios from herbivore teeth have previously been used as paleo-environmental proxies in temperate zones. However, their utility in tropical zones remains uncertain. In this study, sequential sub-samples from white-tailed deer (Odocoileus virginianus) teeth (second and third molars) from the Maya archaeological site of La Joyanca, located in northwestern Petén, Guatemala, show that δ¹⁸O of enamel carbonate corresponds broadly to modern observed precipitation δ¹⁸O over the 10-month period of tooth formation, capturing rainfall seasonality. The analyses also detect significant diachronic differences in the δ¹⁸O between the periods 1100–1000 BP (850–950 A.D.) and 1000–900 BP (950–1050 A.D.) at La Joyanca. The δ¹³C in both periods are indicative of a C₃-plant based diet, which suggests cultivation of maize did not differentially affect deer diet during this period.     

The Pocket Laboratory: The Blowpipe in Eighteenth-Century Swedish Chemistry

This article examines the role of the blowpipe in the discovery process of the disproportionately large number of new elements found by Swedish chemists during the eighteenth century and into the nineteenth. While individual chemists abroad used versions of the tool, in Sweden alone its use was ubiquitous across the chemical and mineralogical research community, and its consistently simple handheld design made basic dry chemical analysis quick, cheap, and portable. This shared use of the tool was crucial to the development of the mineral analysis projects that uncovered new substances, first by enabling the adoption of a system defining minerals by their chemical components and mineralogy by chemical analysis, and second by providing a simple and practical method for that analysis that facilitated collaboration across institutions, physical distance, and time.