置换矩阵的组合合成及其图表示

考察了有向圈或圈并的r级合成图，分别确定了它们的所有圈长和圈数；用图论方法完全刻画了置换矩阵的组合合成。     

Ultrathin Multilayer Films Incorporating Keggin-type Heteropolyanion Clusters

In recent years, there has been considerable interest in the fabrication of self-assembled ultrathin multilayer films, because of their availability to form nanostructured materials with tailored architecture and properties1. The layer-by-layer (LBL) self-assembly, initially developed for pairs of oppositely charged polyelectrolytes2, is an unusually simple and versatile technique to built up of ultrathin multilayer films. A special feature of the multilayer films is that the composition, t…     

碳化钨制备中升温速率对Pt-WC/C电氧化甲醇催化性能的研究

本文采用程控升温还原法(TPR)制备了碳化钨颗粒,然后使用EG+NaBH4作为还原剂制备了Pt-WC/C催化剂,详细地研究了碳化过程中升温速率对碳化钨样品的形貌以及Pt-WC/C对电氧化甲醇催化性能的影响.XRD分析结果表明所有获得的样品均为WC,是多晶的六方结构,且改变碳化过程中升温速率不仅直接影响到样品表面形貌,而...     

Synthesis and characterization of novel aliphatic amine-containing dimethacrylate cross-linkers and their use in UV-curable resin systems

Two novel aliphatic amine-containing dimethacrylate monomers were synthesized from the ringopening reaction of hexamethylene diamine and ethylenediamine with glycidyl methacrylate. The UV-curable and heat-curable formulations were prepared with amine-containing dimethacrylate and active diluents. The curing process was controlled by Fourier transform infrared analysis. The mechanical, physical, and thermal characterizations of the UV-cured films and the UV-heat-cured films were investigated. Thermo-gravimetric analysis of the cured films revealed that the thermo-oxidative stability of the UV-heat-cured films was higher than that of the UV-cured samples. An increase in the cross-linker content caused an increase both in tensile strength and in the elongation values of the UV-heat-cured films. It was also found that the water absorption capacities and gel content of the UV-heat-cured dimethacrylated films depended on the amount of the active diluents.     

Hard nanocomposite comprising stereoregular syndiotactic polypropylene with chemically bonded gold nanoparticles

An effective method to synthesize directly a hard composite material containing uniformly dispersed nanogold particles chemically bonded with a stereospecific, crystalline polymer matrix has been developed. Syndiotactic polypropylene was synthesized and functionalized to have a hydroxyl terminal group (sPP_OH) via a metallocene catalysis with a selective chain transfer. Next, sPP_OH was activated to react with ethylene sulfide forming the thiol‐terminated polymer, sPP_SH. sPP_SH was then chemically bonded to gold nanoparticles (AuNPs) formed in situ via a reduction of HAuCl₄. The bonding between thiol and AuNP stabilized the AuNPs and led to the formation of sPP_AuNPs composite containing uniformly‐dispersed AuNPs of a 19–40 nm size without noticeable aggregation. Furthermore, the chemical bonding of AuNPs has afforded sPP_AuNPs a thermal degradation temperature (T_D) 49.4 °C higher than the pristine sPP or sPP_OH and 25.7 °C higher than sPP_SH without any adverse effect on the crystalline temperature and melting temperature. In addition, the characteristic UV‐Vis absorption wavelength of sPP_AuNPs remains the same at various temperatures, thus indicating the independence of optical property on temperature as well as the good thermal stability of the sPP_AuNPs composite. ¹H NMR, ¹³C NMR, FESEM, STEM, XPS, TGA and DSC were used to investigate the molecular structure, morphology and thermal properties of the resulting sPP_AuNPs nanocomposite. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

A simple method for large-scale preparation of ZnS nanoribbon film and its photocatalytic activity for dye degradation

ZnS nanoribbon film has been successfully prepared by solvothermal treating of Zn foil and S powder in hydrazine hydrate without any surfactant and post-high temperature treatment. The prepared samples were characterized by XRD, SEM and PL. Results show that the obtained films were with high crystallinity and uniformity. The obtained samples were used as a photocatalyst for degradation of dye X-3B, and results show that the dye can be photocatalytically degraded with high rate by as-prepared ZnS nanoribbon film under UV light irradiation.     

A neighborhood search heuristic for pre-marshalling export containers

In a yard where export containers are piled up, only those on the top are directly accessible to the stacking equipment. As a result, extra rehandles may occur when lifting them up for loading onto ships. One way to improve operational efficiency is to pre-marshal the containers in such an order that it fits the loading sequence. This paper proposes a model to develop a movement plan to improve the layout of containers in a bay. The proposed heuristic consists of a neighborhood search process, an integer programming model, and three minor subroutines. Each of the components plays a different role in the heuristic. Several sets of testing results demonstrate the performance of the heuristic as well as the contributions of the components.