全文获取类型
收费全文 | 8439篇 |
免费 | 1625篇 |
国内免费 | 1052篇 |
专业分类
化学 | 6260篇 |
晶体学 | 211篇 |
力学 | 528篇 |
综合类 | 116篇 |
数学 | 841篇 |
物理学 | 3160篇 |
出版年
2024年 | 24篇 |
2023年 | 187篇 |
2022年 | 260篇 |
2021年 | 347篇 |
2020年 | 466篇 |
2019年 | 417篇 |
2018年 | 339篇 |
2017年 | 336篇 |
2016年 | 522篇 |
2015年 | 555篇 |
2014年 | 607篇 |
2013年 | 773篇 |
2012年 | 814篇 |
2011年 | 825篇 |
2010年 | 560篇 |
2009年 | 470篇 |
2008年 | 519篇 |
2007年 | 451篇 |
2006年 | 373篇 |
2005年 | 350篇 |
2004年 | 281篇 |
2003年 | 228篇 |
2002年 | 253篇 |
2001年 | 194篇 |
2000年 | 114篇 |
1999年 | 99篇 |
1998年 | 80篇 |
1997年 | 52篇 |
1996年 | 53篇 |
1995年 | 28篇 |
1994年 | 43篇 |
1993年 | 41篇 |
1992年 | 40篇 |
1991年 | 27篇 |
1990年 | 40篇 |
1989年 | 24篇 |
1988年 | 21篇 |
1987年 | 19篇 |
1986年 | 18篇 |
1985年 | 23篇 |
1984年 | 24篇 |
1983年 | 22篇 |
1982年 | 27篇 |
1981年 | 25篇 |
1980年 | 15篇 |
1979年 | 23篇 |
1978年 | 14篇 |
1977年 | 10篇 |
1976年 | 8篇 |
1974年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
ZhongJunMA XianLI YangLU ChengWANG QiTaiZHENG 《中国化学快报》2003,14(6):594-596
A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis. 相似文献
22.
采用高温热解法,以乙二胺为前驱液,在沉积有铁催化剂的p型硅(111)基底上制备出了定向生长的CNx纳米管.利用扫描电子显微镜、高分辨率透射电子显微镜和拉曼光谱对CNx纳米管进行了形貌观察和表征.CNx纳米管的高度在20?μm左右,直径在50—100nm之间,具有明显的“竹节状”结构,结晶有序度较差.对CNx纳米管薄膜进行低场致发射性能测试:外加电场为1.4V/μm,观察到20?μA /cm2发射电流,外电场升至2.54V/μm时发射电流达到1.280mA/cm2,在较高外电场下,没有发现电流“饱和”.这比
关键词:
CNx纳米管
高温热解
“竹节状”结构
场致发射 相似文献
23.
We study the spectral characteristics theoretically and experimentally in the Fraunhofer diffraction pattern formed by the diffraction of a spatially coherent, polychromatic light through a slit. It is found that the spectrum in some diffraction directions close to the singular direction is redshifted, compared to the spectrum of the incident polychromatic light, and blueshifted in other directions, and splits into two lines at the singular direction. We show that the experimental results are consistent with the theoretical expectations. 相似文献
24.
The gas‐transport properties of poly[2,6‐toluene‐2,2‐bis(3,4‐dicarboxylphenyl)hexafluoropropane diimide] (6FDA‐2,6‐DAT) have been investigated. The sorption behavior of dense 6FDA‐2,6‐DAT membranes is well described by the dual‐mode sorption model and has certain relationships with the critical temperatures of the penetrants. The solubility coefficient decreases with an increase in either the pressure or temperature. The temperature dependence of the diffusivity coefficient increases with an increase in the penetrant size, as the order of the activation energy for the diffusion jump is CH4 > N2 > O2 > CO2. Also, the average diffusion coefficient increases with increasing pressure for all the gases tested. As a combined contribution from sorption and diffusion, permeability decreases with increases in the pressure and the kinetic diameter of the penetrant molecules. Even up to 32.7 atm, no plasticization phenomenon can be observed on flat dense 6FDA‐2,6‐DAT membranes from their permeability–pressure curves. However, just as for other gases, the absolute value of the heat of sorption of CO2 decreases with increasing pressure at a low‐pressure range, but the trend changes when the feed pressure is greater than 10 atm. This implies that CO2‐induced plasticization may occur and reduce the positive enthalpy required to create a site into which a penetrant can be sorbed. Therefore, a better diagnosis of the inherent threshold pressure for the plasticization of a glassy polymer membrane may involve examining the absolute value of the heat of sorption as a function of pressure and identifying the turning point at which the gradient of the absolute value of the heat of sorption against pressure turns from a negative value to a positive one. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 354–364, 2004 相似文献
25.
从激光推进的要求出发,阐述了用于激光推进的高功率激光器的选择原则,即激光器必须满足:(1)高的平均功率和峰值功率;(2)高的单脉冲能量;(3)高的重复频率;(4)优良的大气传输特性。主要分析了目前YAG固体激光器、自由电子激光器和TEA脉冲CO2激光器的特点,通过上述4个方面性能的比较,认为在目前水平下,TEA脉冲CO2激光器是进行激光推进的首选强激光源,其优点表现在:功率可达10kW量级,单脉冲能量可达0.5~1kJ,重复频率为20~40Hz;激光波长处于大气传输窗口,对大气变化不敏感;工作物质快速流动,不存在热透镜效应和破坏阈值;相关光学元件易于制造;光束质量较好;运行成本低。 相似文献
26.
27.
We propose a weighted evolving network model in which the underlying topological structure is still driven by the degree according to the preferential attachment rule while the weight assigned to the newly established edges is dependent on the degree in a nonlinear form. By varying the parameter a that controls the function determining the assignment of weight, a wide variety of power-law behaviours of the total weight distributions as well as the diversity of the weight distributions of edges are displayed. Variation of correlation and heterogeneity in the network is illustrated as well. 相似文献
28.
Hongrui Zhang Mingju Chao Mingyi Gao Liwen Zhang Jianquan Yao 《Optics & Laser Technology》2003,35(6):573-449
A fiber-coupled diode-single-end-pumped Nd:YVO4 laser with an Nd:YVO4 crystal of 0.3 at% doping concentration and 3×3×10 mm3 dimensions was reported. 14.850 W of continuous-wave output power in an M2 factor of 1.12 was obtained under pump power of 27.365 W, with an optical conversion efficiency of 60.49%, and a slope efficiency of 64.5%. 相似文献
29.
L. K. Seah U. S. Dinish S. K. Ong Z. X. Chao V. M. Murukeshan 《Optics & Laser Technology》2004,36(5):371-376
Imaging of latent fingerprints using time-resolved (TR) method offers a broader platform to eliminate the unwanted background emission. In this paper, a novel TR imaging technique is demonstrated and implemented, which facilitates the detection of latent fingerprints with nanosecond resolution. Simulated experiments were carried out with two overlapping fingerprints treated with two fluorescent powders having different lifetimes in nanosecond range. The dependence of the fluorescence emission intensity in nanosecond resolution of TR imaging is also revealed. 相似文献
30.
多目标半定规划的互补弱鞍点和G-鞍点最优性条件 总被引:1,自引:0,他引:1
对于含矩阵函数半定约束和多个目标函数的多目标半定规划问题,给出Lagrange函数在弱有效意义下的互补弱鞍点和Geofrrion恰当有效意义下的G-鞍点的定义及其等价定义.然后,在较弱的凸性条件下,利用含矩阵和向量约束的择一性定理,建立多目标半定规划的互补弱鞍点和G-鞍点充分必要条件. 相似文献