The effect of Hartmann-Hahn mismatching on polarization inversion spin exchange at the magic angle

The effect of the Hartmann-Hahn mismatch delta = omega(eff)-omega(1S) during polarization inversion spin exchange at the magic angle (PISEMA) has been investigated, where omega(eff) and omega(1S) represent the amplitudes of the 1H effective spin-locking field at the magic angle and the 15N RF spin-locking field, respectively. During the PISEMA evolution period, the exact Hartmann-Hahn match condition (i.e., delta = 0) yields a maximum dipolar scaling factor of 0.816 for PISEMA experiments, while any mismatch results in two different effective fields for the first and second half of each frequency switched Lee-Goldburg (FSLG) cycle. The mismatch effect on the scaling factor depends strongly on the transition angle from one effective field to the other within each FSLG cycle as well as on the cycle time. At low RF spin-lock amplitudes in which the FSLG cycle time is relatively long, the scaling factor rapidly becomes smaller as omega(1S) becomes greater than omega(eff). On the other hand, when omega(1S) < omega(eff), there is relatively little effect on the scaling factor with variation in delta. As a result, the presence of RF inhomogeneities may significantly broaden the line-width in the dipolar dimension because of the mismatch effect. Higher RF spin-lock amplitudes result in a relatively small variation for the scaling factor. Furthermore, ramped amplitude of the 15N RF spin-lock field in synchronization with the flip-flop of the FSLG sequence minimizes the transition angle between the two effective fields within the FSLG cycle. It is shown experimentally that such a ramped amplitude not only gives rise to the same scaling factor but also results in a narrower dipolar line-width in comparison with the rectangular amplitude.     

摩擦磨损试验机设计的基础——Ⅲ.设计方法学在摩擦磨损试验机设计中的应用

将设计方法学的一般方法应用于摩擦磨损试验机的设计,这对确定设计方案是科学的和行之有效的。本讲通过一个设计实例说明了设计方法学在摩擦磨损试验机设计中的具体应用问题,并以举例的形式详细地介绍了在方案设计阶段的各个主要工作步骤的实施方法,即建立要求明细表-功能分析-建立设计模幅箱-方案选择-方案评价。其中,关键的是进行功能分析、建立设计模幅箱和方案评价。     

影响内燃机活塞环—缸套擦伤的因素及防擦伤的摩擦学设计

阐述了内燃机活塞环－缸套擦伤的机理。分析了磨合，缸套表面形貌，活塞环外形，活塞组件的热变形与机械变形，润滑油，材料和表面覆层等因素对活塞环擦伤的影响。指出可以采用内燃机强化系数ｐｅｖｍ作为活塞环防擦伤摩擦学设计的判别特征值，从而为从设计上防止活塞环擦伤提供了思路。     

Movable partition designed for the seed‐assisted silicon ingot casting in directional solidification process

For the seed‐assisted casting process for silicon ingots, different partition blocks were designed in the directional solidification (DS) furnaces to preserve the seed crystals and optimize the thermal field in the hot‐zone. A transient global model was established to investigate the effects of different partition blocks during the solidification process. The simulation results showed that the partition blocks can significantly influence the temperature distributions and the melt flow fields. From the designed partition blocks, the movable partition block was more favorable for the seed‐assisted DS process. A suitable temperature gradient and a flat seed‐melt (s‐m) interface were obtained, which facilitated the preservation of seed crystals effectively, and an optimized crystal‐melt (c‐m) interface was achieved as well. One of the designs of the movable partition blocks was implemented in quasi‐mono crystalline silicon casting experiments and it has been confirmed that the designed movable partition block was helpful for the improvement of the single crystal area.     

氧负离子解吸附过程HPM大气击穿弛豫时间分析

基于全局模型,引入氧负离子解吸附过程,完善了重复频率高功率微波脉冲弛豫模型,理论研究了重复频率高功率微波脉冲大气击穿弛豫过程,数值模拟了不同附着频率、解吸附频率以及初始电子浓度条件下,弛豫过程电子浓度随时间的变化规律。结果表明：弛豫过程电子浓度变化分为快衰减和慢衰减两个阶段;发现氧负离子的引入明显延缓了弛豫过程后期电子的衰减;解吸附频率与附着频率对弛豫过程有着相反的影响,解吸附频率越高,慢衰减阶段的电子浓度越高,快衰减阶段电子浓度变化不明显;附着频率越高,快衰减阶段电子浓度变化越剧烈,慢衰减阶段的电子浓度越低;初始电子浓度越大,慢衰减阶段电子浓度变化越剧烈。     

无人机GPS接收机超宽谱电磁脉冲效应与试验分析

基于无人机GPS接收机干扰容限,分析了GPS超宽谱强电磁脉冲效应机理,开展了高重复频率超宽谱电磁脉冲干扰机对典型微型无人机的效应试验,测试分析了在不同位置、不同高度、不同状态、不同飞行模式下无人机GPS接收机的高重复频率超宽谱电磁脉冲干扰效应。试验结果表明,高重复频率超宽谱电磁脉冲对无人机GPS、图传系统、下视传感器均有不同程度的干扰作用,导致无人机无法正常起飞、失控等异常现象,验证了高重复频率超宽谱电磁脉冲干扰GPS接收机的可行性。     

Re/Ga2O3/WO3/ZrO2催化剂对正己烷异构化反应的催化性能

通过浸渍法制备了系列Re/Ga2O3/WO3/ZrO|2(ReGWZ)催化剂,采用X射线衍射、氢气程序升温还原和氨气程序升温脱附等方法对催化剂进行了表征,考察了该催化剂催化正己烷异构化反应性能.结果表明,Re的引入改变了催化剂的氧化还原性能和酸中心分布,且使催化剂由单一的酸中心催化变成由酸中心与金属中心共同催化,因而正己烷异构化率和2,2-二甲基丁烷选择性显著增加.在195℃,1.0MPa,LHSV=1.0h-1和n(H2)/n(C6)=2.0的反应条件下,1.0Re/1.0GWZ催化剂上正己烷转化率、异己烷选择性和2,2-二甲基丁烷选择性分别达到84.8%,97.7%和20%,裂解产物(C5-)选择性为2.1%.150h的稳定性实验表明该催化剂性能稳定.     

铜锌超氧化物歧化酶的突变与神经退行性紊乱的生物无机化学

本文简单介绍了铜锌超氧化物歧化酶的结构、功能及其相互关系,较为详细地讨论了与神经退行性紊乱,尤其是与肌萎性脊髓侧索硬化症有关的铜锌超氧化物歧化酶突变体的生物无机化学的研究进展,提出由该酶突变而引起的蛋白质局部结构变化和金属离子缺失,以及由此导致的氧化损伤和聚集作用可能是导致神经退行性紊乱的主要原因之一.     

偏振-同步荧光法同时测定(艹屈)、蒽和苝

在荧光分光光度计的激发和发射光路中分别置入偏振互为垂直的偏振片,能有效地抑制同步扫描过程中散射光的影响。建立了(艹屈)蒽和苝的同时偏振-同步荧光分析法,其检出限改善3.9倍,相对标准偏差小于3.1%。     

静电堵漏串级镜MM－4U的约束位形的理论研究

本文分析了双会切静电堵漏串级磁镜ＭＭ－４Ｕ中粒子损失的可能机制，考虑了等离子体粒子能量的切断，从平衡的Ｖｌａｓｏｖ方程的解出发，数值求解了一组静态的达朗倍尔方程，即Ｐｏｉｓｓｏｎ方程和Ｍａｘｗｅｌｌ方程，得到了等离子体电位、密度及非中性度（净余电子数密度）分布。结果表明，堵漏电压及堵漏电极极板的几何位形、磁场位形及磁场大小、电子温度及电子－离子温度比在串级磁镜的约束位形的形成中起着重要的作用。