Iodine-catalyzed synthesis of pyrazolo[4,3-f]quinoline derivatives via a highly regio-selective Povarov reaction

A highly regio-selective Povarov reaction of an aromatic aldehyde, 1H-indazol-5-amine, and methyl 3-oxobutanoate catalyzed by iodine is described. This novel reaction selectively gave 3H-pyrazolo[4,3-f]quinolin-9-yl acetates, in high yield, rather than 3H-pyrazolo[4,3-f]quinoline-8-carboxylate derivatives. This procedure has the advantages of mild reaction conditions, high yields, metal-free catalyst, and high regio-selectivity.     

SiOM(M=Li,Be,B,Na,Mg,Al)分子结构的DFT研究

利用Gaussian-94计算程序,B3LYP方法,6-311+G(2d)6d基组,对SiOM(M=Li,Be,B,Na,Mg,Al)诸体系的几何结构进行优化.结果表明,M既可与SiO中的Si键合,也可与O键合.第一和第二主族的SiOM体系以折线形构型为最稳定构型,而第三主族则以近直线形或直线形构型为最稳定构型.从Si-O间键长R_SiO、力常数f_SiO及自然键轨道分析可知,第一主族的SiOLi和SiONa的最稳定构型中SiO-M间的离子键成分较大,可近似看作离子键;而对SiOLi,SiOBe,SiOB和SiOMg体系的以Si为中心的构型,M-SiO间的离子键成分很小,不能看作离子键,可认为M与SiO之间存在着弱相互作用     

Magnetoresistance and magnetic properties of Fe3O4 nanoparticle compacts

In this paper,we report on the magnetic properties of Fe3O4 nanoparticles with different grain sizes under different pressures.In all the samples,the saturated magnetization Ms shows a linear decrease with increasing pressure.The thickness of the magnetic dead layer on the nanoparticle surface nuder different pressures was roughly estimated,which also increases with increasing pressure.The transport measurements of the nanoparticle Fe3O4 compacts show that the low-field magnetoresistance (MR) value is insensitive to the grain size in a wide temperature range;however,the high-field MR value is dependent on grain size,especially at low temperatures.These experimental results can be attributed to the different surface states of the nanoparticles.     

Different Versions of Perturbation Expansion Based on the Single-Trajectory Quadrature Method

The newly developed single trajectory quadrature method is applied to a two-dimensional example. Theresults based on different versions of new perturbation expansion and the new Green‘s function deduced from thismethod are compared with each other, also compared with the result from the traditional perturlbation theory. As thefirst application to higher-dimensional non-separable potential thc obtained result further confirms the applicability andpotential of this new method.     

Synchrotron infrared measurements of dense hydrogen to 360 GPa

Diamond-anvil-cell techniques have been developed to confine and measure hydrogen samples under static conditions to pressures above 300 GPa from 12 to 300 K using synchrotron infrared and optical absorption techniques. A decreasing absorption threshold in the visible spectrum is observed, but the material remains transparent at photon energies down to 0.1 eV at pressures to 360 GPa over a broad temperature range. The persistence of the strong infrared absorption of the vibron characteristic of phase III indicates the stability of the paired state of hydrogen. There is no evidence for the predicted metallic state over these conditions, in contrast to recent reports, but electronic properties consistent with semimetallic behavior are observed.     

β-SiAlON晶须的诱导合成和生长机制研究

以β-SiAION粉料为晶种,SiC为基体,加入Si粉、AI粉和Al2O3粉在1900 K氮气气氛下合成β-SiAlON晶须,研究了晶须的显微结构、相组成和晶须增韧SiC复合材料的力学性能,并结合热力学研究了晶须的生长机制.结果表明:(1)以β-SiAlON粉料为诱导晶种时可以合成β-SiMON晶须材料,其生长机制为VLS机制和VS机制;(2)当以VLS机制生长时,晶须合成z值为1.56,直径约为200 -300nm,呈柱状和纤维状,当以VS机制生长时,晶须合成z值为1.76,直径为0.5～1.5 μm,呈柱状和竹节状,发育较为规则;(3)晶须相可有效提高复合材料的力学性能,相同组成的复合材料中,当β-SiAlON晶须相的含量较高时,材料可以在气孔率较高(32.1;)条件下获得了较好的抗折强度(55.2 MPa).     

Chaos synchronization between two different 4D hyperchaotic Chen systems

This paper presents chaos synchronization between two different four-dimensional (4D) hyperchaotic Chen systems by nonlinear feedback control laws. A modified 4D hyperchaotic Chen system is obtained by changing the nonlinear function of the 4D hyperchaotic Chen system, furthermore, an electronic circuit to realize two different 4D hyperchaotic Chen systems is designed. With nonlinear feedback control method, chaos synchronization between two different 4D hyperchaotic Chen systems is achieved. Based on the stability theory, the functions of the nonlinear feedback control for synchronization of two different 4D hyperchaotic Chen systems is derived, the range of feedback gains is determined. Numerical simulations are shown to verify the theoretical results.