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91.
Kim SH Gwon SY Bae JS Son YA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(1):234-237
A new donor-π-acceptor (D-π-A) type isophorone dye was synthesized by the condensation reaction between 2-(3,5,5-trimethylcyclohex-2-enylidene)-malononitrile and indole-3-carboxaldehyde. The chemical structure of the dye was characterized by 1H NMR, EA and MS. A novel, chromogenic, fluorescent dye based on indol as donor unit and isophorone as acceptor unit displayed marked UV-visible absorption changes and highly selective fluorescence quenching in the presence of fluoride ion. The dye also exhibited sizeable colour changes when used as a pH-induced molecular switch and as a detector for volatile organic compounds. The absorption and fluorescent intensity of the dye can be reversibly selected by protonation/deprotonation of the amine moiety via control of intramolecular charge transfer (ICT), leading to a molecular switch with "on" and "off" states. 相似文献
92.
Choi J Jin J Jung IG Kim JM Kim HJ Son SU 《Chemical communications (Cambridge, England)》2011,47(18):5241-5243
Through a solution approach, SnSe(2) nanoplate-graphene composites were prepared and applied as anode materials in lithium ion batteries, showing promising storage performance superior to SnSe(2) nanoplates or graphene alone. 相似文献
93.
S.-W. Son H. Jeong J. D. Noh 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(3):431-437
We propose a method to determine the community
structure of a complex network. In this method the ground state
problem of a ferromagnetic random field Ising model is considered
on the network with the magnetic field Bs = +∞, Bt =
-∞, and Bi≠s,t=0 for a node pair s and t. The
ground state problem is equivalent to the so-called maximum flow
problem, which can be solved exactly numerically with the help of
a combinatorial optimization algorithm. The community structure is
then identified from the ground state Ising spin domains for all
pairs of s and t. Our method provides a criterion for the
existence of the community structure, and is applicable equally
well to unweighted and weighted networks. We demonstrate the
performance of the method by applying it to the Barabási-Albert
network, Zachary karate club network, the scientific collaboration
network, and the stock price correlation network.
(Ising, Potts, etc.) 相似文献
94.
The orientation of E7 liquid crystal (LC) confined within 200 nm diameter cylindrical cavities of Anodisc membranes are investigated by FTIR dichroism techniques. The cavity walls of the confining pores were chemically modified with different length perfluorinated carboxylic acids (PCAs, C n F2n+1COOH, n = 3, 4, 5, 6) at 1, 3 and 5 mM concentrations. From the FTIR spectra of PCA-treated alumina Anodsic membranes, we found salt formation between the -COOH group of the PCAs and the Anodisc membranes. From the FTIR spectra of LC-filled Anodisc membranes, we found an abrupt alignment direction change, from parallel to perpendicular, of the LC molecules along the long axis of the cavities between n = 4 and n = 5 for the 1 mM concentration of PCA. However, for the 5 mM concentration of PCA, the parallel-to-perpendicular alignment direction of LC molecules changed between n = 3 and n = 4. These LC orientation changes for PCA-treated Anodisc membranes occurred at shorter length than for hydrocarbon carboxylic acid (HCA, C n H2n+1COOH)-treated Anodisc membranes. This change may be caused by the lower surface energy of the -(CF2) n CF3 chain of PCA than that of the -(CH2) n CH3 chain of HCA. 相似文献
95.
Sang Ick LeeSeung Uk Son Mi Ra ChoiYoung Keun Chung Sueg-Geun Lee 《Tetrahedron letters》2003,44(25):4705-4709
Cobalt on charcoal (Co/C) can be used as a catalyst in the tandem carbocycloaddition reaction of 1,6-diyne and carbon monoxide. The reaction product is dependent upon the reaction temperature, the position of the functional group, and the substrate itself. 相似文献
96.
The synthesis and optical properties of a series of benz[f]indenes as new building blocks for electronic and optoelectronic materials are described. 相似文献
97.
98.
Byungki Son Bronislaw P. Czech David A. Babb Richard A. Bartsch 《Tetrahedron letters》1984,25(16):1647-1650
Reactions of 3,6,9,12-tetraoxa-7-(benzyloxymethyl)-1,14-tetradecanediol with appropriate ditosylates followed by hydrogenolysis produce hydroxymethyl-27-crown-9 and hydroxy- methyl-30-crown-10. Alkali metal cation complexation by lipophilic dodecyl ether derivatives of these crowns is examined. 相似文献
99.
Moon Bae Ko Ick Hwan Kwon Won Ho Jo Tae Won Son 《Journal of Polymer Science.Polymer Physics》1994,32(5):945-951
The thermoreversible gelation of polyacrylonitrile (PAN)/propylene carbonate (PC) solution was investigated by calorimetric, thermomechanical, optical, and rheological measurements. Two endothermic signals are observed for PAN/PC gels in DSC thermograms, and the peak temperature of the higher melting endotherm coincides with the gel melting temperature determined from the TMA thermogram. SEM micrographs show that the overall structure is separated into two phases and is composed of sperical domains, which may be formed upon passing through the thermodynamically unstable or metastable state via the liquid-liquid phase separation. The gelation rate increases with the aging temperature. This is also discussed on the basis of the elasticity theory of the fishnet gel. © 1994 John Wiley & Sons, Inc. 相似文献
100.
Two novel cryptands which each contains one carbon and one nitrogen atom at the bridgehead positions are synthesized and found to form strong complexes with lithium cations. 相似文献