A molecular network model to describe the nonlinear viscoelastic behavior of polymers

A transient molecular network model is built to describe the nonlinear viscoelasticity of polymers by considering the effect of entanglement loss and regeneration on the relaxation of molecular strands. It is an extension of previous network theories. The experimental data on three thermoplastic polymers (ABS, PVC and PA6) obtained under various loading conditions are used to test the model. Agreement between the theoretical and experimental curves shows that the suggested model can describe successfully the relaxation behavior of the thermoplastic polymers under different loading rates by using relatively few relaxation modes. Thus the micromechanism responsible for strain-rate dependence of relaxation process and the origin of nonlinear viscoelasticity may be disclosed. The project supported by the National Natural Science Foundation of China and Doctorial Fund     

Activity coefficients for NaBr in aqueous ternary solutions with sodium propionate and butyrate from EMF measurements

The activity coefficients of NaBr in the NaBr–NaPropionate–H₂O and NaBr–NaButyrate–H₂O systems were determined from EMF measurements at constant total ionic strength of 0.1 0.5 1.0 1.5 2.0 and 2.5 mol-kg^–1 and at 25° C. The activity coefficients were fitted using Scatchard, Pitzer and Lim equations. Finally the excess Gibbs free energy of these mixtures were also calculated.     

产量──密度模型讨论

本文给出产量与密度函数关系     

Quantitative dependence of MR signal intensity on tissue concentration of Gd(HP-DO3A) in the nephrectomized rat.

Cardiac-gated SE 20/224 +/- 20 MR images were obtained from nephrectomized rats before and after intravenously administering 153Gd-Gd(HP-DO3A). The concentration of Gd, [Gd], was linear in dose in myocardium, skeletal muscle, and blood. Under steady-state conditions, where d[Gd]/dt = 0, image intensities (IIN) in regions of interest were compared with the measured [Gd]. IIN was linear in myocardium at less than or equal to 0.61 mumol/g-myocardium (less than or equal to 0.5 mmol/kg dose) and in skeletal muscle at less than or equal to 0.63 mumol/g-muscle (less than or equal to 0.75 mmol/kg). Above 0.6 mumol Gd/g-tissue, IIN did not increase further. The in vivo data were consistent with measured ex vivo and in vivo relaxivities. A 29% greater slope for IIN versus [Gd] in myocardium [14,439 +/- 4350 IIN (mumol/g)] than in muscle [10,258 +/- 5,296 IIN/(mumol/g)] was attributed to a significant difference in blood content: 25% versus 2% weight blood in myocardium and skeletal muscle, respectively. Two components were apparent from plots of ex vivo 1/T1 versus [Gd] in myocardium and muscle, and only one for blood.     

A posteriori error analysis for linearization of nonlinear elliptic problems and their discretizations

The paper is devoted to a posteriori quantitative analysis for errors caused by linearization of non-linear elliptic boundary value problems and their finite element realizations. We employ duality theory in convex analysis to derive computable bounds on the difference between the solution of a non-linear problem and the solution of the linearized problem, by using the solution of the linearized problem only. We also derive computable bounds on differences between finite element solutions of the nonlinear problem and finite element solutions of the linearized problem, by using finite element solutions of the linearized problem only. Numerical experiments show that our a posteriori error bounds are efficient.     

热辐射驱动烧蚀平面金靶的数值定标定律

利用一维辐射流体力学编码数值研究了辐射烧蚀波在平面金靶中的传播情况,并在常温边界条件下得到了辐射流、烧蚀压、质量烧蚀率和特征等离子体密度的定标定律。     

Investigation of the chemical state of ultrathin Hf-Al-O films during high temperature annealing

Al₂O₃ incorporated HfO₂ films grown by atomic layer deposition (ALD) were investigated by high-resolution X-ray photoelectron spectroscopy (HRXPS). The core level energy state of a 15 Å thick film showed a shift to higher binding energy, as the result of a silicate formation and Al₂O₃ incorporation. The incorporation of Al₂O₃ into the HfO₂ film had no effect on silicate formation at the interface between the film and Si, while the ionic bonding characteristics and hybridization effects were enhanced compared to a pure HfO₂ film. The dissociation of the film in an ultrahigh vacuum (UHV) is effectively suppressed compared to a pure HfO₂ film, indicating an enhanced thermal stability of Hf-Al-O. Any dissociated Al₂O₃ on the film surface was completely removed into the vacuum by vacuum annealing treatment over 850 °C, while HfO₂ contributed to Hf silicide formation on the film surface.     

微腔激光器的发展与应用

本文探讨了微腔激光器的分类、基本原理及特点，并简单介绍了目前几种微型激光器的发展及应用。     

非奇异单圈图的刻划

边数等于顶点个数的连通图称为单圈图.本文修正了文献[1]中关于奇异单圈图的充要条件,并且利用该条件证明了文献[2]中一个关于非奇异单圈图的猜想.     

On meromorphic functions that share three values of finite weights

A uniqueness theorem for two distinct non-constant meromorphic functions that share three values of finite weights is proved, which generalizes two previous results by H.X. Yi, and X.M. Li and H.X. Yi. As applications of it, many known results by H.X. Yi and P. Li, etc. could be improved. Furthermore, with the concept of finite-weight sharing, extensions on Osgood-Yang's conjecture and Mues' conjecture, and a generalization of some prevenient results by M. Ozawa and H. Ueda, ect. could be obtained.