Magnetic properties of porous glass-CuO nanocomposites

The magnetization of the porous glass nanocomposite with CuO nanoparticles embedded in the pores has been studied in the temperature range from 1.8 to 350 K for different pore fillings. It has been shown that the magnetic properties of these nanocomposites depend significantly on pore filling. It has been found that, in the low-temperature range for the nanocomposite with a pore filling of 55% and for pressed CuO, the ZFC and FC susceptibilities diverge, a feature which has been almost absent in the nanocomposite with 21% filling. It has been demonstrated that the kink in the temperature dependence of magnetization, which corresponds to the paramagnetic-multiferroic phase transition, does not shift in the sample with a larger pore filling as compared to that observed in the bulk sample.     

基于符号动力学的耦合映像格子系统的初值估计

在符号动力学的基础上,深入探讨了基于动力学符号序列的局部耦合映像格子系统求逆问题.在理论上系统地分析耦合映像系统初值估计的性能与耦合系数及映射函数之间的数学关系,证明相空间I^M上的任意取值通过基于符号向量序列的逆迭代过程并不一定收敛至初值,其敛散性与耦合强度和映射函数的选择有直接关系.同时证明了混沌或其拓扑共轭的逆不一定为压缩映射,其总体的敛散性与整个逆迭代过程中的收敛与发散的强度对比有关.理论分析与数值实验结果完全一致,说明本文提出的耦合映像格子系统初值估计问题的分析 关键词： 耦合映像格子 符号动力学 初值估计     

meso‐Ester and Carboxylic Acid Substituted BODIPYs with Far‐Red and Near‐Infrared Emission for Bioimaging Applications

A series of meso‐ester‐substituted BODIPY derivatives 1–6 are synthesized and characterized. In particular, dyes functionalized with oligo(ethylene glycol) ether styryl or naphthalene vinylene groups at the α positions of the BODIPY core ( 3 – 6 ) become partially soluble in water, and their absorptions and emissions are located in the far‐red or near‐infrared region. Three synthetic approaches are attempted to access the meso‐carboxylic acid (COOH)‐substituted BODIPYs 7 and 8 from the meso‐ester‐substituted BODIPYs. Two feasible synthetic routes are developed successfully, including one short route with only three steps. The meso‐COOH‐substituted BODIPY 7 is completely soluble in pure water, and its fluorescence maximum reaches around 650 nm with a fluorescence quantum yield of up to 15 %. Time‐dependent density functional theory calculations are conducted to understand the structure–optical properties relationship, and it is revealed that the Stokes shift is dependent mainly on the geometric change from the ground state to the first excited singlet state. Furthermore, cell staining tests demonstrate that the meso‐ester‐substituted BODIPYs ( 1 and 3 – 6 ) and one of the meso‐COOH‐substituted BODIPYs ( 8 ) are very membrane‐permeable. These features make these meso‐ester‐ and meso‐COOH‐substituted BODIPY dyes attractive for bioimaging and biolabeling applications in living cells.     

模糊层次分析法及其在优化建材连锁配送方案中的应用

本文首先说明模糊ＡＨＰ方法是在传统的ＡＨＰ方法的基础上，考虑到人们对复杂事物判断的模糊性，提出程度分析和综合决策理论，并介绍了模糊ＡＨＰ方法的主要理论及步骤。最后把它用于建材连锁配送系统模式的评价，可将专家对诸方案指标体系所进行的带有模糊性判断，通过定量计算，转化为对连锁配送系统模式的排序，从而达到选优的目的。     

Single-sided mobile NMR apparatus using the transverse flux of a single permanent magnet

This study presents a simple design for a mobile, single-sided nuclear magnetic resonance (NMR) apparatus which uses the magnetic flux parallel to the magnetization direction of a single, disc-shaped permanent magnet polarized in radial direction. The stray magnetic field above the magnet is approximately parallel to the magnetization direction of the magnet and is utilized as the B₀ magnetic field of the apparatus. The apparatus weighs 1.8 kg, has a compact structure and can be held in one's palm. The apparatus generates a B₀ field strength of about 0.279 T at the center of apparatus surface and can acquire a clear Hahn echo signal of a pencil eraser block lying on the RF coil in one shot. Moreover, a strong static magnetic field gradient exists in the direction perpendicular to the apparatus surface. The strength of the static magnetic field gradient near the center of the apparatus surface is about 10.2 T/m; one-dimensional imaging of thin objects and liquid self-diffusion coefficient measurements can be performed therein. The available spatial resolution of the one-dimensional imaging experiments using a 5×5 mm horizontal sample area is about 200 μm. Several nondestructive inspection applications of the apparatus, including distinguishing between polyethylene grains of different densities, characterizing epoxy putties of distinct set times and evaluating the fat content percentages of milk powders, are also demonstrated. Compared with many previously published designs, the proposed design bears a simple structure and generates a B₀ magnetic field parallel to the apparatus surface, simplifying apparatus construction and simultaneously rendering the selection of the radiofrequency coil relatively flexible.     

Transesterification of Soybean Oil Catalyzed by Calcium Hydroxide which Obtained from Hydrolysis Reaction of Calcium Carbide

Calcium carbide residue (CCR) was investigated in transesterification reaction of triglycerides to determine its viability as a solid catalyst for biodiesel synthesis. Literature survey showed that CCR has never been studied as a solid catalyst in the transesterification of triglyceride. The scope of the study includes the effects of CCR calcination temperature, calcination time, the alcohol/oil molar ratio, the catalyst amount (wt % of oil) and the reaction time. The relationship between chemical composition and catalytic activity of waste cement was also investigated. These CCR catalysts, thermally activated at 600 °C, can give rise to fatty acid methyl esters (FAME) purity higher than 99.5%, after 3 h of reaction, when oil/methanol molar ratio of 1/12 and 1 wt % of the catalyst were employed. Application of CCR as catalyst for biodiesel production in this study may not only provide a cost‐effective and environment friendly way of recycling CCR waste but also reduce hopefully the cost of biodiesel production.     

一种新型面阵CCD航天立体摄影测量光学系统

采用一台大面阵CCD和广角摄影物镜的组合，研制成功一种新型的单面阵CCD航天立体摄影测量系统.该系统焦距为23.3 mm;视场角为40°;在空间分辨率为36 lp/mm时，MTF均值达到0.8以上;光谱适应范围为0.5 μm~0.75 μm.和国内外常用的三线阵CCD遥感立体测量相机相比，本系统结构更简单、体积更小，重量更轻，更加适用于航天遥感应用环境.     

Finite 2-Geodesic Transitive Abelian Cayley Graphs

In this paper, we first give a classification of the family of 2-geodesic transitive abelian Cayley graphs. Let \(\Gamma \) be such a graph which is not 2-arc transitive. It is shown that one of the following holds: (1) \(\Gamma \cong \mathrm{K}_{m[b]}\) for some \(m\ge 3\) and \(b\ge 2\); (2) \(\Gamma \) is a normal Cayley graph of an elementary abelian group; (3) \(\Gamma \) is a cover of Cayley graph \(\Gamma _K\) of an abelian group T / K, where either \(\Gamma _K\) is complete arc transitive or \(\Gamma _K\) is 2-geodesic transitive of girth 3, and A / K acts primitively on \(V(\Gamma _K)\) of type Affine or Product Action. Second, we completely determine the family of 2-geodesic transitive circulants.     

Permeability-frequency spectra of (Fe1−xcox)73.5Cu1Nb3Si13.5B9 nanocrystalline alloys under different magnetic fields

Under various amplitude of AC magnetic fields domain wall motion is the main mechanism in the magnetization process. This includes domain wall bulging and domain wall displacing. In this paper complex permeability-frequency spectra of (Fe_1−xCo_x)_73.5Cu₁Nb₃Si_13.5B₉ (x=0,0.5$x=0,0.5$) nanocrystalline alloys were measured as a function of the AC magnetic field, ranging from 0.001 to 0.04 Oe. Obvious changes have been found in complex permeability spectra for alloy x=0$x=0$ with the change of the amplitude of AC magnetic field, but variation of AC magnetic field has little effect on complex permeability spectra for alloy x=0.5$x=0.5$. This is attributed to the increased pinning field after substitution of Fe with Co in Fe_73.5Cu₁Nb₃Si_13.5B₉ nanaocrystalline alloy.