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41.
The crystal structure, magnetic and magnetotransport properties of the variation of B′-site transition metal in Sr2FeMO6 (M=Mo, W) with double perovskites structure have been investigated systematically. Measurements of magnetization vs. temperature at H=5 T show that Sr2FeMoO6 is a ferromagnet and Sr2FeWO6 is an antiferromagnet with TN∼35 K. Additionally, the large magnetoresistance ratio (MR) of ∼22% (H=3 T) at room temperature (RT) was observed in the Sr2FeWO6 compound. However, the Sr2FeMoO6 compound did not show any significant MR even at high fields and RT (MR∼1%; H=3 T and 300 K). The implications of these findings are supported by band structure calculations to explain the interaction between the 4d(Mo) and 5d(W) orbitals of transition metal ions and oxygen ions. 相似文献
42.
Jong Chan Lee Jin Young Park So Young Yoon Yong Hun Bae Seung Jun Lee 《Tetrahedron letters》2004,45(1):191-193
A novel and direct method for the synthesis of α-halocarbonyl compounds using sequential treatment of carbonyl compounds with [hydroxy(tosyloxy)iodo]benzene followed by magnesium halides under solvent-free microwave irradiation conditions is described. 相似文献
43.
LIN Chang ZHANG Xiu-Lian 《理论物理通讯》2005,44(2):247-251
The nonlinear dust acoustic waves in two-dimensional dust plasma with dust charge variation is analytically investigated by using the formally variable separation approach. New analytical solutions for the governing equation of this system have been obtained for dust acoustic waves in a dust plasma for the first time. We derive exact analytical expressions for the general case of the nonlinear dust acoustic waves in two-dimensional dust plasma with dust charge variation. 相似文献
44.
S. H. Park J. H. Chang M. Yang H. S. Ahn S. N. Yi K. Goto M. W. Cho T. Yao J. S. Song 《Current Applied Physics》2004,4(6):607-610
Photoluminescence (PL) linewidth broadening of CdxZn1 − xSe/ZnSe triple quantum wells, grown on GaAs substrates by molecular beam epitaxy (MBE), has been investigated. Various quantum well (QW) samples have been prepared with different QW thickness and composition (Cd-composition). Measured and calculated PL linewidth are compared. Both composition and thickness fluctuations are considered for the calculation with the parameters such as the volume of exciton, nominal thickness and composition of QWs. Surface roughness measured by atomic force microscopy (AFM) is used to estimate the interface roughness. Results show that when Cd-composition increases additional linewidth broadening due to Zn/Cd interdiffusion is enhanced. 相似文献
45.
Fei Chang Dongheng Zhang Haijian Yang Haibin Song 《Journal of organometallic chemistry》2004,689(5):936-946
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene. 相似文献
46.
Vernon Barger Cheng-Wei Chiang Paul Langacker Hye-Sung Lee 《Physics letters. [Part B]》2004,580(3-4):186-196
We study the effects of an extra U(1)′ gauge boson with flavor changing couplings with fermion mass eigenstates on certain B meson decays that are sensitive to such new physics contributions. In particular, we examine to what extent the current data on Bd→φK and Bd→η′K decays may be explained in such models, concentrating on the example in which the flavor changing couplings are left-chiral. We find that within reasonable ranges of parameters, the Z′ contribution can readily account for the anomaly in SφKS but is not sufficient to explain large branching ratio of Bd→η′K with the same parameter value. SφKS and Sη′KS are seen to be the dominant observables that constrain the extra weak phase in the model. 相似文献
47.
Donghyun Cho Taihyun Chang Apostolos Avgeropoulos Nikos Hadjichristidis 《European Polymer Journal》2003,39(11):2155-2160
Temperature gradient interaction chromatography (TGIC) was applied for the separation of a complex miktoarm star copolymer which has one polystyrene (PS) arm and three polystyrene-b-polyisoprene (PS-b-PI) diblock copolymer arms. Such miktoarm star polymers are much more difficult to characterize than branched homopolymers since the byproduct, typically polymers with missing arm(s) or coupled products, have not only different molecular weights but also different compositions. TGIC was able to fully separate the byproducts, and the composition of the molecular species corresponding to the different separated elution peaks was determined by two methods, fractionation/NMR and multiple detection (UV and RI). A reasonable agreement between the results of the two methods was obtained. By using the composition found, the corresponding molecular weights were determined by multi-angle light scattering detection. Based on the composition and the molecular weight we were able to identify the structure of the different molecular species. 相似文献
48.
Sungyong Kim Lingxin Chen Sangyeop Lee Gi Hun Seong Jaebum Choo Eun Kyu Lee Chil-Hwan Oh Sanghoon Lee 《Analytical sciences》2007,23(4):401-405
A rapid DNA analysis has been developed based on a fluorescence intensity change of a molecular beacon in a PDMS microfluidic channel. Recently, we reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). However, there are some limitations in its application to real DNA samples because the target DNA must be labelled with a suitable fluorescent dye. To resolve this problem, we have developed a new DNA microfluidic sensor using a molecular beacon. By monitoring the change in the restored fluorescence intensity along the channel length, it is possible to rapidly detect any hybridization of the molecular beacon to the target DNA. In this case, the target DNA does not need to be labelled. Our experimental results demonstrate that this microfluidic sensor using a molecular beacon is a promising diagnostic tool for rapid DNA hybridization analysis. 相似文献
49.
N. Wright und W. C. Lee 《Fresenius' Journal of Analytical Chemistry》1940,120(1-2):39-40
Ohne Zusammenfassung 相似文献
50.
The transverse momentum spectra for pions observed by WA80 and NA35 collaborations are analysed within a fireball model with collective isentropic expansion and a realistic freeze-out criterion. By varing the initial state of the fireball, an excellent fit to the data is achieved for the whole measured range ofP T . Slight differences in the data for the spectral slopes from central and pheripheral collisions originate in our model from the difference in the size of the fireball and in the number of participating nucleons in central and peripheral collisions. Using additional information from two-pion correlations, we can extrapolate our model back from the freeze-out point (determined from the spectra) to the initial state; we find that an initial energy density of 1.5–2GGeV/fm3 is sufficient to explain the data from central O+Au collisions at 200A GeV. 相似文献