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171.
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The electronic charge distribution in tetragonal closed packed (tcp) metal is approximated by a collection of spherical charge clouds situated midway between the ions. The anisotropy of the charge distribution is parameterized in terms of a charge shift δ derivable from the lattice parameters and the elastic coefficients of the metal. The electric field gradient (EFG) in the metal can be obtained through lattice summations over the charges. Numerical calculations are made to obtain the EFG in pure indium and indium-based dilute impurity alloys. Fairly good agreement with the experiments is achieved.  相似文献   
173.
Summary Polar heteroatomic concentrates were separated from deasphalted oils and asphalts of indigenous crudes by various separation techniques. Conditions have been standardized for its separation using Fuller's earth as adsorbent, and data is compared with those obtained by the techniques reported in the literature. Semiquantitative estimates of phenols, pyrrols, carboxylic acids and amides in the concentrates were also made by IR spectrometry.  相似文献   
174.
Amorphous metal Fe10Ni70Si8B12 has been studied by Mössbauer spectroscopy without and with an weak applied field in the plane of ribbons. Reentrant properties have been confirmed with the existence of a canted state at low temperature. Studies with different values of the applied field have shown that a field near 50 0e is sufficient to saturate the average direction of the ferromagnetism.  相似文献   
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A new efficient interval partitioning approach to solve constrained global optimization problems is proposed. This involves a new parallel subdivision direction selection method as well as an adaptive tree search. The latter explores nodes (intervals in variable domains) using a restricted hybrid depth-first and best-first branching strategy. This hybrid approach is also used for activating local search to identify feasible stationary points. The new tree search management technique results in improved performance across standard solution and computational indicators when compared to previously proposed techniques. On the other hand, the new parallel subdivision direction selection rule detects infeasible and suboptimal boxes earlier than existing rules, and this contributes to performance by enabling earlier reliable deletion of such subintervals from the search space.  相似文献   
177.
For the purpose of multichannel integrated-optical wavelength division MUX/DEMUX design, the wavelength tuning method of Ti:LiNbO3 zero-gap directional coupler is analysed by effective-index based matrix method (EIMM). In this method, first, the 2D refractive index profile of the Ti:LiNbO3 zero-gap directional coupler is transformed into lateral 1D effective-index profile by WKB method. Finally, matrix method is applied to this effective-index profile and the propagation constants are computed from the resonance peaks of the excitation efficiency versus propagation constant characteristics. It has been shown that the channel wavelength tuning can be achieved by varying the Y-branching angle at the input and output of the device or by a slight variation of two-mode-section length. The method of electro-optic fine tuning of the channel wavelength and channel separation of the device has also been investigated. A cascaded structure with proper parameters for four-channel application is also simulated and the results are presented.  相似文献   
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The variation of the recoilless fraction ‘f’ as a function of temperature and pressure of119Sn embedded as a dilute impurity in palladium (Pd) host has been calculated after incorporating the changes in the force constant and mass at the impurity site using Debye model and phonon frequency spectrum (pfs). The comparison of the results have been made with the available experimental values.  相似文献   
180.
The herbal medicament derived from the lipid soluble fraction obtained from Curcuma longa L. (Zingiberaceae) has shown potential neuroprotective activity in disorders like stroke. HM has been standardized with three biomarkers: ar-turmerone, α/β-turmerone and curlone, major bisabolane sesquiterpenes of turmeric oil. Development of a biaonalytical method for these sesquiterpenes was initiated to characterize its preclinical pharmacokinetics in rabbits to accelerate its development as a potential candidate for vascular complications. Since, the compounds are structurally and chemically very similar, gradient elution was utilized on a C-18 reversed phase column with a mobile phase comprising of acetonitrile and deionised water. The UV detector was set at wavelengths 240 and 270 nm. The sample clean-up was performed by protein precipitation with acetonitrile. The method was reasonably sensitive with limits of quantitation (LOQ) of 0.098 μg mL?1 in plasma for all the analytes. Accuracy and precision were within the acceptable limits, as indicated by relative standard deviation (% RSD) varying from 1.3 to 13.6% and bias values ranging from ?5.5 to 10.3%, respectively. Moreover, the analytes were stable in plasma even after three freeze-thaw cycles. The method was applied to generate preliminary pharmacokinetics of turmeric oil in rabbits after intravenous administration.  相似文献   
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