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S. Pandey K. A. Fletcher W. E. Acree Jr C. Fetzer 《Fresenius' Journal of Analytical Chemistry》1998,360(6):669-674
Applicability of the nitromethane selective quenching rule for discriminating between alternant versus nonalternant polycyclic
aromatic hydrocarbons (PAHs) is examined for 20 representative PAH solutes dissolved in micellar sodium dodecylsulfate (SDS)
+ cetyltrimethylammonium bromide (CTAB), SDS + dodecyltrimethylammonium bromide (DTAB), SDS + Brij-35, and SDS + sodium octanoate
(SO) mixed surfactant solvent media. Experimental results show that nitromethane quenched fluorescence of all 8 alternant
PAHs studied in the four different solvent systems. Unexpected quenching behavior was observed, however, in the case of nonalternant
PAHs. Nitromethane quenched fluorescence emission of nonalternant PAHs dissolved in the SDS + SO solvent media, which is contrary
to the selective quenching rule. In the case of the mixed anionic + cationic surfactant solvent media, nitromethane quenching
selectivity was restored at concentration ratios of approximately 4 : 1 (anionic:cationic) or less.
Received: 22 May 1997 / Revised: 29 September 1997 / Accepted: 3 October 1997 相似文献
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The synthesis and structure-activity-relationship (SAR) for a series of N-substituted piperazinyl carbamoyl 7-15 and piperazinyl acetyl 18-26 derivatives of tetrahydropapaverine have been carried out. The general synthetic methods of carbamoyl tetrahydropapaverine analogues involve N-substituted piperazines and carbamoyl imidazole tetrahydropapaverine as starting materials. Another route for synthesizing these compounds, involving the formation of carbamoyl imidazole piperazine has also been explored. Acylation of tetrahydropapaverine followed by substitution with various piperazinyl moities afforded the acetyl tetrahydropapaverine derivatives. Variously substituted piperazines have been used to monitor the effect of electron releasing and electron withdrawing substituents upon the antispasmodic activity of the molecules. Effect of varying electron densities on the antispasmodic activity, by altering the position of these groups on the benzene ring has also been monitored. Pharmacological methods involve the in vitro antispasmodic activity studies on a freshly removed guinea pig ileum using a force displacement transducer amplifier connected to a physiograph. Among the analogues synthesized in the present study, a promising compound 7, a potent muscle relaxant as compared to papaverine has been obtained. 相似文献
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Various new structural entities related to x-azatricyclo[m.n.0. 0(a)()(,)(b)()]alkanes are constructed by the intramolecular [3 + 2] dipolar cycloaddition of nonstabilized cyclic azomethine ylides. The ylide is generated by the sequential double desilylation of N-alkyl alpha,alpha'-bis(trimethylsilyl)cyclic amines using Ag(I)F as a one-electron oxidant. 相似文献