A study of plasma filled parallel plate waveguide with one boundary corrugated

Warm plasma theory is used to investigate the propagation of electromagnetic waves in a plasma filled parallel plate waveguide with one boundary plate corrugated. Dispersion relations for TE- and TM-modes are derived and it is found that the propagation of TE-modes is unaffected by corrugation of one boundary plane while the propagation of TM-modes is affected by it. For TM-modes the wave numberk depends on the frequency ta as well as on the distance through which the wave is propagated.The authors take the opportunity to thank Professor M. L. Ghosh, Department of Mathematics, North Bengal University for suggesting the problem and one of the authors (S. K. Ghosh) wishes to express his thanks to the University of North Bengal for financial support.     

Amperometric determination of 2-benzothiazole sulphenamide accelerators

A simple method for the amperometric estimation of N-cyclohexyl-2-benzothiazole sulphenamide, N-dicyclohexyl-2-benzothiazole sulphenamide, 2-(morpholinothio)benzothiazole and N-tert.-butyl-2-benzothiazole sulphenamide is reported. The results are obtained within 5 min and are correct within +/- 2.0%.     

Resonance production in the reaction π±p→Ks0K±p at 30 and 50 GeV/c

The mass and momentum transfer spectra of the charged $\text{K}\text{K}$ system produced in the reaction π^±p→K_s⁰K^±p are analyzed. The data have been collected at the CERN SPS with the Geneva-Lausanne two-arm, non-magnetic spectrometer at 30 and 50 GeV/c incident momenta. The general features of the reactions at these energies and the results of partial-wave analyses of the two kaon system are presented.The channel is dominated by the diffractive production of even spin resonances. The spin 4 recurrence of the A₂(1320) is clearly observed at 2040 MeV (Γ=380 MeV. A new resonance is observed with a mass M=2450MeV and a width Γ=400 MeV; the quantum numbers of this state are found to be I^G(J^PC)=1^?(6++). The analysis also shows the decay of the decay of the meson ?′(1600) through the $\text{K}\text{K}$ channel at both energies.The production amplitudes are determined both as a function of the $\text{K}\text{K}$ effective mass and of the momentum transfer. Isoscalar natural parity exchange is dominant. The energy dependence between 10 and 50 GeV/c is shown to be well described by a Regge pole model based on the f-dominated pomeron hypothesis. We compare the production mechanisms of the 2⁺ resonances A₂(1320) and K¹(1430). Finally, we estimate the $\text{K}\text{K}$ branching ratios of the spin 4 A₂(2040) and spin 6 A₂(2450) resonances.     

Comments on the presence of a peak in the static structure factor of an electron liquid

Emphasis is laid on the fact that the peak in the static structure factor S(k) observed in a recent experiment at k≈2k_F for conduction electrons in beryllium agrees well with the one predicted by us theoretically some time back. The error in the calculation of the pair correlation function g(r) using the experimental data on S(k) is pointed out. The position of the peak obtained in our g(r) clearly indicates that the effect of electron correlation is to condense into a Wigner lattice at a distance equal to the average interparticle separation rather than making a Mott type transition to an atomic-like state.     

Die Abtrennung des metachromatischen Bestandteils von Methylenblau und Chondroitinsulfat durch Ultrazentrifugation

Ohne Zusammenfassung     

Stress in polycrystalline GaN films prepared by r.f sputtering

Undoped, Be-doped and Si-doped polycrystalline GaN films were deposited by R.F. sputtering onto fused silica substrates. The films were deposited at various deposition temperatures ranging from 300 K to 623 K and characterized by optical measurements while the microstructural information was obtained from SEM and XRD studies. The compositional study for the GaN film was carried out using SIMS. Residual stresses in these films were evaluated from the band tail of the absorption spectra as well as from direct measurements of hardness by commercially available depth sensing indentometer. It was observed that undoped GaN films had the highest hardness followed by that for Be-doped and Si-doped films. The values of hardness obtained form the above optical measurement tallied quite well with those obtained from direct indentation measurement.     

Excited state property of hardly photodissociable heme-CO adduct studied by time-dependent density functional theory

While most of CO-bound hemes are easily photodissociated with a quantum yield of nearly unity, we occasionally encounter a CO-heme which appears hardly photodissociable under the ordinary measurement conditions of resonance Raman spectra using CW laser excitation and a spinning cell. This study aims to understand such hemes theoretically, that is, the excited-state properties of the five-coordinate heme-CO adduct (5cH) as well as the 6c heme-CO adduct (6cH) with a weak axial ligand. Using a hybrid density functional theory, we scrutinized the properties of the ground and excited spin states of the computational models of a 5cH and a water-ligated 6cH (6cH-H(2)O) and compared these properties with those of a photodissociable imidazole-ligated 6cH (6cH-Im). Jahn-Teller softening for the Fe-C-O bending potential in the a(1)-e excited state was suggested. The excited-state properties of 6cH-Im and 5cH were further studied with time-dependent DFT theory. The reaction products of 6cH-Im and 5cH were assumed to be quintet and triplet states, respectively. According to the time-dependent DFT calculations, the Q excited state of 6cH-Im, which is initially a pure pi-pi state, crosses the Fe-CO dissociative state (2A') without large elongation of the Fe-CO bond. In contrast, the Q state of the 5cH does not cross the Fe-CO dissociative state but results in the formation of the excited spin state with a bent Fe-C-O. Consequently, photoisomerization from linear to bent Fe-C-O in the 5cH is a likely mechanism for apparent nonphotodissociation.